IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v119y2020ics1364032119308081.html
   My bibliography  Save this article

Coke formation and deactivation during catalytic reforming of biomass and waste pyrolysis products: A review

Author

Listed:
  • Ochoa, Aitor
  • Bilbao, Javier
  • Gayubo, Ana G.
  • Castaño, Pedro

Abstract

Undoubtedly, hydrogen (H2) is a clean feedstock and energy carrier whose sustainable production should be anticipated. The pyrolysis of biomass or waste plastics and the subsequent reforming over base (transition) or noble metals supported catalysts allows reaching elevated H2 yields. However, the catalyst used in the reforming step undergoes a rapid and severe deactivation by means of a series of physicochemical phenomena, including metal sintering, metallic phase oxidation, thermal degradation of the support and, more notoriously, coke deposition. This review deals with the currently existing alternatives at the catalyst and reactor level to cope with catalyst deactivation and increase process stability, and then delves with the fundamental phenomena occurring during this catalyst deactivation. An emphasis is placed on coke deposition and its influence on deactivation, which depends on its location, chemical nature, morphology, precursors or formation mechanism, among others. We also discuss the challenges for increasing the value of the carbon materials formed and therefore, enhance process viability.

Suggested Citation

  • Ochoa, Aitor & Bilbao, Javier & Gayubo, Ana G. & Castaño, Pedro, 2020. "Coke formation and deactivation during catalytic reforming of biomass and waste pyrolysis products: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    • Handle: RePEc:eee:rensus:v:119:y:2020:i:c:s1364032119308081
    DOI: 10.1016/j.rser.2019.109600
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032119308081
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2019.109600?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ayalur Chattanathan, Shyamsundar & Adhikari, Sushil & Abdoulmoumine, Nourredine, 2012. "A review on current status of hydrogen production from bio-oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2366-2372.
    2. Iulianelli, A. & Ribeirinha, P. & Mendes, A. & Basile, A., 2014. "Methanol steam reforming for hydrogen generation via conventional and membrane reactors: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 355-368.
    3. Luo, Ming & Yi, Yang & Wang, Shuzhong & Wang, Zhuliang & Du, Min & Pan, Jianfeng & Wang, Qian, 2018. "Review of hydrogen production using chemical-looping technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 3186-3214.
    4. Hou, Tengfei & Zhang, Shaoyin & Chen, Yongdong & Wang, Dazhi & Cai, Weijie, 2015. "Hydrogen production from ethanol reforming: Catalysts and reaction mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 132-148.
    5. Sharma, Sunita & Ghoshal, Sib Krishna, 2015. "Hydrogen the future transportation fuel: From production to applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1151-1158.
    6. Kirubakaran, V. & Sivaramakrishnan, V. & Nalini, R. & Sekar, T. & Premalatha, M. & Subramanian, P., 2009. "A review on gasification of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(1), pages 179-186, January.
    7. Hedayati, Ali & Le Corre, Olivier & Lacarrière, Bruno & Llorca, Jordi, 2016. "Dynamic simulation of pure hydrogen production via ethanol steam reforming in a catalytic membrane reactor," Energy, Elsevier, vol. 117(P2), pages 316-324.
    8. Wang, Jianlong & Yin, Yanan, 2018. "Fermentative hydrogen production using various biomass-based materials as feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 92(C), pages 284-306.
    9. Kunwar, Bidhya & Cheng, H.N. & Chandrashekaran, Sriram R & Sharma, Brajendra K, 2016. "Plastics to fuel: a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 421-428.
    10. Nikolaidis, Pavlos & Poullikkas, Andreas, 2017. "A comparative overview of hydrogen production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 597-611.
    11. Chaubey, Rashmi & Sahu, Satanand & James, Olusola O. & Maity, Sudip, 2013. "A review on development of industrial processes and emerging techniques for production of hydrogen from renewable and sustainable sources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 443-462.
    12. Stig Helveg & Carlos López-Cartes & Jens Sehested & Poul L. Hansen & Bjerne S. Clausen & Jens R. Rostrup-Nielsen & Frank Abild-Pedersen & Jens K. Nørskov, 2004. "Atomic-scale imaging of carbon nanofibre growth," Nature, Nature, vol. 427(6973), pages 426-429, January.
    13. Medrano, J.A. & Oliva, M. & Ruiz, J. & García, L. & Arauzo, J., 2011. "Hydrogen from aqueous fraction of biomass pyrolysis liquids by catalytic steam reforming in fluidized bed," Energy, Elsevier, vol. 36(4), pages 2215-2224.
    14. Nabgan, Walid & Tuan Abdullah, Tuan Amran & Mat, Ramli & Nabgan, Bahador & Gambo, Yahya & Ibrahim, Maryam & Ahmad, Arshad & Jalil, Aishah Abdul & Triwahyono, Sugeng & Saeh, Ibrahim, 2017. "Renewable hydrogen production from bio-oil derivative via catalytic steam reforming: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 347-357.
    15. Kong, Lingjun & Tian, ShuangHong & Li, Zhaohui & Luo, Rongshu & Chen, Dingsheng & Tu, YuTing & Xiong, Ya, 2013. "Conversion of recycled sawdust into high HHV and low NOx emission bio-char pellets using lignin and calcium hydroxide blended binders," Renewable Energy, Elsevier, vol. 60(C), pages 559-565.
    16. Aramouni, Nicolas Abdel Karim & Touma, Jad G. & Tarboush, Belal Abu & Zeaiter, Joseph & Ahmad, Mohammad N., 2018. "Catalyst design for dry reforming of methane: Analysis review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2570-2585.
    17. Villafán-Vidales, H.I. & Arancibia-Bulnes, C.A. & Riveros-Rosas, D. & Romero-Paredes, H. & Estrada, C.A., 2017. "An overview of the solar thermochemical processes for hydrogen and syngas production: Reactors, and facilities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 894-908.
    18. Kim, Taegyu & Jo, Sungkwon & Song, Young-Hoon & Lee, Dae Hoon, 2014. "Synergetic mechanism of methanol–steam reforming reaction in a catalytic reactor with electric discharges," Applied Energy, Elsevier, vol. 113(C), pages 1692-1699.
    19. Namioka, Tomoaki & Saito, Atsushi & Inoue, Yukiharu & Park, Yeongsu & Min, Tai-jin & Roh, Seon-ah & Yoshikawa, Kunio, 2011. "Hydrogen-rich gas production from waste plastics by pyrolysis and low-temperature steam reforming over a ruthenium catalyst," Applied Energy, Elsevier, vol. 88(6), pages 2019-2026, June.
    20. Resende, K.A. & Ávila-Neto, C.N. & Rabelo-Neto, R.C. & Noronha, F.B. & Hori, C.E., 2015. "Thermodynamic analysis and reaction routes of steam reforming of bio-oil aqueous fraction," Renewable Energy, Elsevier, vol. 80(C), pages 166-176.
    21. Li, Hongyu & Xu, Qingli & Xue, Hanshen & Yan, Yongjie, 2009. "Catalytic reforming of the aqueous phase derived from fast-pyrolysis of biomass," Renewable Energy, Elsevier, vol. 34(12), pages 2872-2877.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Du, Jinlong & Zhang, Fengxia & Hu, Jianhang & Yang, Shiliang & Liu, Huili & Wang, Hua, 2022. "Pyrolysis of rubber seed oil over high-temperature copper slag: Gas and mechanism of coke formation," Renewable Energy, Elsevier, vol. 185(C), pages 1209-1220.
    2. Lee, Seong Chan & Choi, Jae Hyung & Lee, Chul Woo & Woo, Seung Han & Lee, Jaekyoung & Woo, Hee Chul, 2022. "H2 production by steam reforming of Saccharina japonica-derived liquefied oils on NixCuy hydrotalcite-derived catalysts," Renewable Energy, Elsevier, vol. 191(C), pages 418-427.
    3. Wang, Chunsheng & Wang, Yishuang & Chen, Mingqiang & Liang, Defang & Cheng, Wen & Li, Chang & Yang, Zhonglian & Wang, Jun, 2022. "Understanding relationship of sepiolite structure tailoring and the catalytic behaviors in glycerol steam reforming over Co/sepiolite derived Co-phyllosilicate catalyst," Renewable Energy, Elsevier, vol. 183(C), pages 304-320.
    4. Yang, Yaojun & Diao, Rui & Luo, Zejun & Zhu, Xifeng, 2023. "Co-combustion performances of biomass pyrolysis semi-coke and rapeseed cake: PCA, 2D-COS and full range prediction of M-DAEM via machine learning," Renewable Energy, Elsevier, vol. 219(P1).
    5. Chen, Cheng & Volpe, Roberto & Jiang, Xi, 2021. "A molecular investigation on lignin thermochemical conversion and carbonaceous organics deposition induced catalyst deactivation," Applied Energy, Elsevier, vol. 302(C).
    6. Zhao, Liwen & Liu, Guilian, 2022. "Dynamic coupling of reactor and heat exchanger network considering catalyst deactivation," Energy, Elsevier, vol. 260(C).
    7. Gao, Zhuwei & Li, Chengxin & Qi, Xinyu & Wei, Yaodong & Liu, Zhongxin, 2022. "Flow analysis on carbonaceous deposition of heavy oil droplets and catalyst particles for coking formation process," Energy, Elsevier, vol. 260(C).
    8. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    9. Lin, Qunqing & Zhang, Shuping & Wang, Jiaxing & Yin, Haoxin, 2021. "Synthesis of modified char-supported Ni–Fe catalyst with hierarchical structure for catalytic cracking of biomass tar," Renewable Energy, Elsevier, vol. 174(C), pages 188-198.
    10. Wang, Chunsheng & Wang, Yishuang & Chen, Mingqiang & Hu, Jiaxin & Liang, Defang & Tang, Zhiyuan & Yang, Zhonglian & Wang, Jun & Zhang, Han, 2021. "Comparison of the regenerability of Co/sepiolite and Co/Al2O3 catalysts containing the spinel phase in simulated bio-oil steam reforming," Energy, Elsevier, vol. 214(C).
    11. Zou, Jiecheng & Zhao, Lanxun & Hu, Qiang & Yao, Dingding & Yang, Haiping, 2024. "Pyrolysis and catalytic reforming of disposable plastic waste for syngas production with adjustable H2/CO ratio," Applied Energy, Elsevier, vol. 362(C).
    12. Yang, Hanmin & Cui, Yuxiao & Han, Tong & Sandström, Linda & Jönsson, Pär & Yang, Weihong, 2022. "High-purity syngas production by cascaded catalytic reforming of biomass pyrolysis vapors," Applied Energy, Elsevier, vol. 322(C).
    13. Feng, Dongdong & Wang, Shizhang & Dong, Heming & Wang, Junjie & Wang, Fuhua & Shang, Qi & Zhao, Yijun & Sun, Shaozeng, 2024. "Mechanism on CMD reaction regulated by supports and promoters of Fe-based catalysts," Energy, Elsevier, vol. 298(C).
    14. Hao, Jingyuan & Qi, Baojin & Li, Dong & Zeng, Feiya, 2021. "Catalytic co-pyrolysis of rice straw and ulva prolifera macroalgae: Effects of process parameter on bio-oil up-gradation," Renewable Energy, Elsevier, vol. 164(C), pages 460-471.
    15. Wang, Xin & Jin, Xiaodong & Wang, Hui & Wang, Yi & Zuo, Lu & Shen, Boxiong & Yang, Jiancheng, 2023. "Catalytic pyrolysis of microalgal lipids to liquid biofuels: Metal oxide doped catalysts with hierarchically porous structure and their performance," Renewable Energy, Elsevier, vol. 212(C), pages 887-896.
    16. Gao, Ningbo & Salisu, Jamilu & Quan, Cui & Williams, Paul, 2021. "Modified nickel-based catalysts for improved steam reforming of biomass tar: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    17. Tang, Shouhang & Zhou, Sicheng & Li, Ge & Xin, Shanzhi & Huang, Fang & Liu, Xiaoye & Huang, Kai & Zeng, Lixi & Mi, Tie, 2023. "Combination of torrefaction and catalytic fast pyrolysis for aromatic hydrocarbon production from herbaceous medicine waste," Energy, Elsevier, vol. 270(C).
    18. Liu, Xu & Guo, Yang & Dasgupta, Anish & He, Haoran & Xu, Donghai & Guan, Qingqing, 2022. "Algal bio-oil refinery: A review of heterogeneously catalyzed denitrogenation and demetallization reactions for renewable process," Renewable Energy, Elsevier, vol. 183(C), pages 627-650.
    19. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.
    20. Du, Jinlong & Shen, Tianhao & Hu, Jianhang & Zhang, Fengxia & Yang, Shiliang & Liu, Huili & Wang, Hua, 2023. "Study on thermochemical conversion of triglyceride biomass catalyzed by biochar catalyst," Energy, Elsevier, vol. 277(C).
    21. Guo, Feiqiang & Qiao, Qixia & Mao, Songbo & Bai, Jiaming & Dong, Kaiming & Shu, Rui & Xu, Liya & Wei, Haixiao & Qian, Lin & Wang, Yunpu, 2023. "A comprehensive study on the pyrolysis behavior of pine sawdust catalyzed by different metal ions under conventional and microwave heating conditions," Energy, Elsevier, vol. 272(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Guanyi & Tao, Junyu & Liu, Caixia & Yan, Beibei & Li, Wanqing & Li, Xiangping, 2017. "Hydrogen production via acetic acid steam reforming: A critical review on catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1091-1098.
    2. Marino, C. & Nucara, A. & Panzera, M.F. & Pietrafesa, M. & Varano, V., 2019. "Energetic and economic analysis of a stand alone photovoltaic system with hydrogen storage," Renewable Energy, Elsevier, vol. 142(C), pages 316-329.
    3. Shashi Sharma & Shivani Agarwal & Ankur Jain, 2021. "Significance of Hydrogen as Economic and Environmentally Friendly Fuel," Energies, MDPI, vol. 14(21), pages 1-28, November.
    4. Hou, Tengfei & Zhang, Shaoyin & Chen, Yongdong & Wang, Dazhi & Cai, Weijie, 2015. "Hydrogen production from ethanol reforming: Catalysts and reaction mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 132-148.
    5. Li, Kaiyu & Gao, Yitong & Zhang, Shengan & Liu, Guilian, 2022. "Study on the energy efficiency of bioethanol-based liquid hydrogen production process," Energy, Elsevier, vol. 238(PC).
    6. Almaktar, Mohamed & Shaaban, Mohamed, 2021. "Prospects of renewable energy as a non-rivalry energy alternative in Libya," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    7. Nasir Uddin, Md. & Daud, W.M.A. Wan & Abbas, Hazim F., 2013. "Potential hydrogen and non-condensable gases production from biomass pyrolysis: Insights into the process variables," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 204-224.
    8. Huang, Jijiang & Veksha, Andrei & Chan, Wei Ping & Giannis, Apostolos & Lisak, Grzegorz, 2022. "Chemical recycling of plastic waste for sustainable material management: A prospective review on catalysts and processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    9. Wenran Gao & Hui Li & Karnowo & Bing Song & Shu Zhang, 2020. "Integrated Leaching and Thermochemical Technologies for Producing High-Value Products from Rice Husk: Leaching of Rice Husk with the Aqueous Phases of Bioliquids," Energies, MDPI, vol. 13(22), pages 1-15, November.
    10. Dega, Frank Blondel & Chamoumi, Mostafa & Braidy, Nadi & Abatzoglou, Nicolas, 2019. "Autothermal dry reforming of methane with a nickel spinellized catalyst prepared from a negative value metallurgical residue," Renewable Energy, Elsevier, vol. 138(C), pages 1239-1249.
    11. Spallina, V. & Matturro, G. & Ruocco, C. & Meloni, E. & Palma, V. & Fernandez, E. & Melendez, J. & Pacheco Tanaka, A.D. & Viviente Sole, J.L. & van Sint Annaland, M. & Gallucci, F., 2018. "Direct route from ethanol to pure hydrogen through autothermal reforming in a membrane reactor: Experimental demonstration, reactor modelling and design," Energy, Elsevier, vol. 143(C), pages 666-681.
    12. Chen, Guanyi & Yao, Jingang & Liu, Jing & Yan, Beibei & Shan, Rui, 2016. "Biomass to hydrogen-rich syngas via catalytic steam reforming of bio-oil," Renewable Energy, Elsevier, vol. 91(C), pages 315-322.
    13. Garcia, Gabriel & Arriola, Emmanuel & Chen, Wei-Hsin & De Luna, Mark Daniel, 2021. "A comprehensive review of hydrogen production from methanol thermochemical conversion for sustainability," Energy, Elsevier, vol. 217(C).
    14. Aasadnia, Majid & Mehrpooya, Mehdi, 2018. "Large-scale liquid hydrogen production methods and approaches: A review," Applied Energy, Elsevier, vol. 212(C), pages 57-83.
    15. Mostafa Rezaei & Ali Mostafaeipour & Mojtaba Qolipour & Hamid-Reza Arabnia, 2018. "Hydrogen production using wind energy from sea water: A case study on Southern and Northern coasts of Iran," Energy & Environment, , vol. 29(3), pages 333-357, May.
    16. Hajizadeh, Abdollah & Mohamadi-Baghmolaei, Mohamad & Cata Saady, Noori M. & Zendehboudi, Sohrab, 2022. "Hydrogen production from biomass through integration of anaerobic digestion and biogas dry reforming," Applied Energy, Elsevier, vol. 309(C).
    17. Alviani, Vani Novita & Hirano, Nobuo & Watanabe, Noriaki & Oba, Masahiro & Uno, Masaoki & Tsuchiya, Noriyoshi, 2021. "Local initiative hydrogen production by utilization of aluminum waste materials and natural acidic hot-spring water," Applied Energy, Elsevier, vol. 293(C).
    18. Sun, Zhao & Hu, Chenfeng & Zhang, Rongjun & Li, Hongwei & Wu, Yu & Sun, Zhiqiang, 2023. "Simulation of the deoxygenated and decarburized biomass cascade utilization system for comprehensive upgrading of green hydrogen generation," Renewable Energy, Elsevier, vol. 219(P2).
    19. Resende, K.A. & Ávila-Neto, C.N. & Rabelo-Neto, R.C. & Noronha, F.B. & Hori, C.E., 2015. "Thermodynamic analysis and reaction routes of steam reforming of bio-oil aqueous fraction," Renewable Energy, Elsevier, vol. 80(C), pages 166-176.
    20. Yang, F. & Meerman, J.C. & Faaij, A.P.C., 2021. "Carbon capture and biomass in industry: A techno-economic analysis and comparison of negative emission options," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:119:y:2020:i:c:s1364032119308081. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.