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Iron oxide reduction by graphite and torrefied biomass analyzed by TG-FTIR for mitigating CO2 emissions

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  • Ubando, Aristotle T.
  • Chen, Wei-Hsin
  • Ong, Hwai Chyuan

Abstract

Biomass provides a sustainable source for iron oxide reduction and can replace coal for mitigating CO2 emissions. Torrefied biomass can act as a reducing agent in the iron oxide reduction to metallic iron which is important in chemical-looping combustion for lessening CO2 emissions. This study performs iron oxide reduction by graphite and torrefied biomass via thermogravimetric analysis (TGA), while the evolved gases from the reduction processes are analyzed using a Fourier transform infrared (FTIR) spectrometer. Iron ore reduction by graphite occurs at higher temperatures (>950 °C), whereas iron oxide reduction using the torrefied biomass is more significant for low-to medium-range temperatures with an onset temperature of 300 °C. The reduction extent is recognized from the comparison between theoretical and experimental TGA curves, and validated by the evolved gases. The reduction extent of the 2:1 ratio of hematite-to-torrefied biomass shows a lower onset reduction temperature compared to the 1:1 ratio. The TG-FTIR results confirm the direct reduction of iron oxides by carbon in graphite and torrefied biomass and the release of evolved CO2 instead of CO. A step-wise reduction procedure is observed which is triggered by the evolved gases released from torrefied biomass devolatilization at 370 °C.

Suggested Citation

  • Ubando, Aristotle T. & Chen, Wei-Hsin & Ong, Hwai Chyuan, 2019. "Iron oxide reduction by graphite and torrefied biomass analyzed by TG-FTIR for mitigating CO2 emissions," Energy, Elsevier, vol. 180(C), pages 968-977.
    • Handle: RePEc:eee:energy:v:180:y:2019:i:c:p:968-977
    DOI: 10.1016/j.energy.2019.05.149
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    1. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    2. Du, Shan-Wen & Chen, Wei-Hsin & Lucas, John A., 2010. "Pulverized coal burnout in blast furnace simulated by a drop tube furnace," Energy, Elsevier, vol. 35(2), pages 576-581.
    3. Irfan, Muhammad F. & Usman, Muhammad R. & Kusakabe, K., 2011. "Coal gasification in CO2 atmosphere and its kinetics since 1948: A brief review," Energy, Elsevier, vol. 36(1), pages 12-40.
    4. Suopajärvi, Hannu & Umeki, Kentaro & Mousa, Elsayed & Hedayati, Ali & Romar, Henrik & Kemppainen, Antti & Wang, Chuan & Phounglamcheik, Aekjuthon & Tuomikoski, Sari & Norberg, Nicklas & Andefors, Alf , 2018. "Use of biomass in integrated steelmaking – Status quo, future needs and comparison to other low-CO2 steel production technologies," Applied Energy, Elsevier, vol. 213(C), pages 384-407.
    5. Chen, Wei-Hsin & Huang, Shih-Rong & Wang, Xiao-Dong & Wu, Po-Hua & Lin, Yu-Li, 2017. "Performance of a thermoelectric generator intensified by temperature oscillation," Energy, Elsevier, vol. 133(C), pages 257-269.
    6. Karali, Nihan & Xu, Tengfang & Sathaye, Jayant, 2014. "Reducing energy consumption and CO2 emissions by energy efficiency measures and international trading: A bottom-up modeling for the U.S. iron and steel sector," Applied Energy, Elsevier, vol. 120(C), pages 133-146.
    7. Tran, Khanh-Quang & Luo, Xun & Seisenbaeva, Gulaim & Jirjis, Raida, 2013. "Stump torrefaction for bioenergy application," Applied Energy, Elsevier, vol. 112(C), pages 539-546.
    8. Mousa, Elsayed & Wang, Chuan & Riesbeck, Johan & Larsson, Mikael, 2016. "Biomass applications in iron and steel industry: An overview of challenges and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 1247-1266.
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