IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v239y2022ipas0360544221021885.html
   My bibliography  Save this article

Improvement of proton conductivity of magnetically aligned phosphotungstic acid-decorated cobalt oxide embedded Nafion membrane

Author

Listed:
  • Pourzare, K.
  • Mansourpanah, Y.
  • Farhadi, S.
  • Sadrabadi, M.M. Hasani
  • Ulbricht, M.

Abstract

The fabrication of proton exchange membranes with a short conduction pathway in the direction of membrane thickness is desirable for fuel cell applications. In this study, a new nanohybrid additive (Co3O4-NH2/H3PW12O40; CAW) is synthesized, by anchoring phosphotungstic acid (H3PW12O40; HPW) on aminopropylsiloxane-functionalized cobalt oxide, and then it is incorporated into the Nafion (NF) matrix to prepare nanocomposite membranes by film casting from CAW dispersions in NF solutions. To obtain short-pathway proton-conducting channels, through the nanocomposite membranes drying process, a magnetic field is employed to align the nanohybrid particles in transversal (thickness) direction of the NF matrix. Furthermore, the alignment of nanohybrids is observed directly by scanning electron microscopy, and estimated indirectly by proton conductivity and methanol permeability values. It is found that alignment of nanohybrids in the NF matrix elevates the conductivity of proton as well as the permeability of methanol. The aligned NF/CAW nanocomposite membrane with 1 wt% of CAW reveals the highest proton conductivity of 211 mS cm−1 at 90 °C and 95% relative humidity, which is 39% higher than that of pure NF (152 mS cm−1). Interestingly, through the orientation of CAW, 76% improvement in the selectivity of the membranes is observed.

Suggested Citation

  • Pourzare, K. & Mansourpanah, Y. & Farhadi, S. & Sadrabadi, M.M. Hasani & Ulbricht, M., 2022. "Improvement of proton conductivity of magnetically aligned phosphotungstic acid-decorated cobalt oxide embedded Nafion membrane," Energy, Elsevier, vol. 239(PA).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221021885
    DOI: 10.1016/j.energy.2021.121940
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221021885
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.121940?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Xin Liu & Yi Li & Jiandang Xue & Weikang Zhu & Junfeng Zhang & Yan Yin & Yanzhou Qin & Kui Jiao & Qing Du & Bowen Cheng & Xupin Zhuang & Jianxin Li & Michael D. Guiver, 2019. "Magnetic field alignment of stable proton-conducting channels in an electrolyte membrane," Nature Communications, Nature, vol. 10(1), pages 1-13, December.
    2. Ogungbemi, Emmanuel & Ijaodola, Oluwatosin & Khatib, F.N. & Wilberforce, Tabbi & El Hassan, Zaki & Thompson, James & Ramadan, Mohamad & Olabi, A.G., 2019. "Fuel cell membranes – Pros and cons," Energy, Elsevier, vol. 172(C), pages 155-172.
    3. Ayyaru, Sivasankaran & Dharmalingam, Sangeetha, 2015. "A study of influence on nanocomposite membrane of sulfonated TiO2 and sulfonated polystyrene-ethylene-butylene-polystyrene for microbial fuel cell application," Energy, Elsevier, vol. 88(C), pages 202-208.
    4. Nagar, Harsha & Sahu, Nivedita & Basava Rao, V.V. & Sridhar, S., 2020. "Surface modification of sulfonated polyethersulfone membrane with polyaniline nanoparticles for application in direct methanol fuel cell," Renewable Energy, Elsevier, vol. 146(C), pages 1262-1277.
    5. Prapainainar, Paweena & Du, Zehui & Theampetch, Apichaya & Prapainainar, Chaiwat & Kongkachuichay, Paisan & Holmes, Stuart M., 2020. "Properties and DMFC performance of nafion/mordenite composite membrane fabricated by solution-casting method with different solvent ratio," Energy, Elsevier, vol. 190(C).
    6. V., Vijayalekshmi & Khastgir, Dipak, 2018. "Fabrication and comprehensive investigation of physicochemical and electrochemical properties of chitosan-silica supported silicotungstic acid nanocomposite membranes for fuel cell applications," Energy, Elsevier, vol. 142(C), pages 313-330.
    7. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Chenfang & Li, Qingshan & Wang, Chunmei & Zhang, Yangjun & Zhuge, Weilin, 2021. "Thermodynamic analysis of a hydrogen fuel cell waste heat recovery system based on a zeotropic organic Rankine cycle," Energy, Elsevier, vol. 232(C).
    2. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.
    3. Abed Alaswad & Abdelnasir Omran & Jose Ricardo Sodre & Tabbi Wilberforce & Gianmichelle Pignatelli & Michele Dassisti & Ahmad Baroutaji & Abdul Ghani Olabi, 2020. "Technical and Commercial Challenges of Proton-Exchange Membrane (PEM) Fuel Cells," Energies, MDPI, vol. 14(1), pages 1-21, December.
    4. A. G. Olabi & Tabbi Wilberforce & Khaled Elsaid & Tareq Salameh & Enas Taha Sayed & Khaled Saleh Husain & Mohammad Ali Abdelkareem, 2021. "Selection Guidelines for Wind Energy Technologies," Energies, MDPI, vol. 14(11), pages 1-34, June.
    5. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    6. Cha, Dowon & Yang, Wonseok & Kim, Yongchan, 2019. "Performance improvement of self-humidifying PEM fuel cells using water injection at various start-up conditions," Energy, Elsevier, vol. 183(C), pages 514-524.
    7. Zhang, Xiaoqing & Yang, Jiapei & Ma, Xiao & Zhuge, Weilin & Shuai, Shijin, 2022. "Modelling and analysis on effects of penetration of microporous layer into gas diffusion layer in PEM fuel cells: Focusing on mass transport," Energy, Elsevier, vol. 254(PA).
    8. Najmi, Aezid-Ul-Hassan & Anyanwu, Ikechukwu S. & Xie, Xu & Liu, Zhi & Jiao, Kui, 2021. "Experimental investigation and optimization of proton exchange membrane fuel cell using different flow fields," Energy, Elsevier, vol. 217(C).
    9. Ahmed M. Nassef & Ahmed Handam, 2022. "Parameter Estimation-Based Slime Mold Algorithm of Photocatalytic Methane Reforming Process for Hydrogen Production," Sustainability, MDPI, vol. 14(5), pages 1-12, March.
    10. K. Arunprasath & S. Bathrinath & R. K. A. Bhalaji & Koppiahraj Karuppiah & Anish Nair, 2023. "An integrated approach to modelling of barriers in implementation of cellular manufacturing systems in production industries," International Journal of System Assurance Engineering and Management, Springer;The Society for Reliability, Engineering Quality and Operations Management (SREQOM),India, and Division of Operation and Maintenance, Lulea University of Technology, Sweden, vol. 14(4), pages 1370-1378, August.
    11. Ahmed Mohmed Dafalla & Lin Wei & Bereket Tsegai Habte & Jian Guo & Fangming Jiang, 2022. "Membrane Electrode Assembly Degradation Modeling of Proton Exchange Membrane Fuel Cells: A Review," Energies, MDPI, vol. 15(23), pages 1-26, December.
    12. Venkatesan, Suriya & Mitzel, Jens & Wegner, Karsten & Costa, Remi & Gazdzicki, Pawel & Friedrich, Kaspar Andreas, 2022. "Nanomaterials and films for polymer electrolyte membrane fuel cells and solid oxide cells by flame spray pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    13. Thowayeb H. Hassan & Abu Elnasr E. Sobaih & Amany E. Salem, 2021. "Factors Affecting the Rate of Fuel Consumption in Aircrafts," Sustainability, MDPI, vol. 13(14), pages 1-16, July.
    14. Zhiming Zhang & Jun Zhang & Tong Zhang, 2022. "Endplate Design and Topology Optimization of Fuel Cell Stack Clamped with Bolts," Sustainability, MDPI, vol. 14(8), pages 1-13, April.
    15. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
    16. Abdul Ghani Olabi & Tabbi Wilberforce & Mohammad Ali Abdelkareem & Mohamad Ramadan, 2021. "Critical Review of Flywheel Energy Storage System," Energies, MDPI, vol. 14(8), pages 1-33, April.
    17. Li, Yanju & Li, Dongxu & Ma, Zheshu & Zheng, Meng & Lu, Zhanghao & Song, Hanlin & Guo, Xinjia & Shao, Wei, 2022. "Performance analysis and optimization of a novel vehicular power system based on HT-PEMFC integrated methanol steam reforming and ORC," Energy, Elsevier, vol. 257(C).
    18. Kusworo, Tutuk Djoko & Widayat, Widayat & Utomo, Dani Puji & Pratama, Yulius Harmawan Setya & Arianti, Riska Anindisa Vira, 2020. "Performance evaluation of modified nanohybrid membrane polyethersulfone-nano ZnO (PES-nano ZnO) using three combination effect of PVP, irradiation of ultraviolet and thermal for biodiesel purification," Renewable Energy, Elsevier, vol. 148(C), pages 935-945.
    19. Li, Jing & Zuo, Wei & E, Jiaqiang & Zhang, Yuntian & Li, Qingqing & Sun, Ke & Zhou, Kun & Zhang, Guangde, 2022. "Multi-objective optimization of mini U-channel cold plate with SiO2 nanofluid by RSM and NSGA-II," Energy, Elsevier, vol. 242(C).
    20. Sven Gruber & Klemen Rola & Danijela Urbancl & Darko Goričanec, 2023. "Carbon-Free Heat Production for High-Temperature Heating Systems," Sustainability, MDPI, vol. 15(20), pages 1-18, October.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221021885. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.