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Preparation and characterization of proton exchange membranes based on semi-interpenetrating sulfonated poly(imide-siloxane)/epoxy polymer networks

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  • Lee, Chi-Hung
  • Chen, Szu-Hsien
  • Wang, Yen-Zen
  • Lin, Chao-Chien
  • Huang, Chih-Kai
  • Chuang, Ching-Nan
  • Wang, Chih-Kuang
  • Hsieh, Kuo-Huang

Abstract

We prepared and characterized a series of semi-IPN (semi-interpenetrating polymer network) membranes based on SPISX–EP (sulfonated polyimide-siloxane and epoxy) polymers and compared their properties with those of a pure SPISX membrane and a commercially available proton exchange membrane. Overall, the SPISX5–EP (with 5 wt% PDMS (α,ω-diaminopropyl polydimethylsiloxane) in SPISX) membranes can be exhibited desirable mechanical properties and thermal stabilities, with proton conductivities superior to those of Nafion® 117 at 80 °C. The dimensional changes of the membranes and degrees of methanol transport decreased with increasing epoxy content; here, the effect of crosslinking had a greater effect than did the increased number of ionic exchange sites. The proton conductivities and methanol permeabilities of the membranes ranged from 10−3 to 10−2 S/cm and from 10−9 to 10−7 cm2/s, respectively, in the temperature range 25–90 °C. Transmission electron microscopy images indicated that the presence of large, well-connected hydrophilic domains was responsible for the large hydrolytic stability of the SPISX5–EP membranes; infrared spectroscopy confirmed these results. SPISX5–EP membranes featuring epoxy compositions of 30 and 40% exhibited greater hydrolytic stability relative to the corresponding SPISX membranes, suggesting their potential application as proton-conducting membranes in fuel cells.

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  • Lee, Chi-Hung & Chen, Szu-Hsien & Wang, Yen-Zen & Lin, Chao-Chien & Huang, Chih-Kai & Chuang, Ching-Nan & Wang, Chih-Kuang & Hsieh, Kuo-Huang, 2013. "Preparation and characterization of proton exchange membranes based on semi-interpenetrating sulfonated poly(imide-siloxane)/epoxy polymer networks," Energy, Elsevier, vol. 55(C), pages 905-915.
    • Handle: RePEc:eee:energy:v:55:y:2013:i:c:p:905-915
    DOI: 10.1016/j.energy.2013.03.062
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    Cited by:

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    2. Nikouei, Mohammad Ali & Oroujzadeh, Maryam & Mehdipour-Ataei, Shahram, 2017. "The PROMETHEE multiple criteria decision making analysis for selecting the best membrane prepared from sulfonated poly(ether ketone)s and poly(ether sulfone)s for proton exchange membrane fuel cell," Energy, Elsevier, vol. 119(C), pages 77-85.
    3. Colmenar-Santos, Antonio & Alberdi-Jiménez, Lucía & Nasarre-Cortés, Lorenzo & Mora-Larramona, Joaquín, 2014. "Residual heat use generated by a 12 kW fuel cell in an electric vehicle heating system," Energy, Elsevier, vol. 68(C), pages 182-190.
    4. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    5. V., Vijayalekshmi & Khastgir, Dipak, 2018. "Fabrication and comprehensive investigation of physicochemical and electrochemical properties of chitosan-silica supported silicotungstic acid nanocomposite membranes for fuel cell applications," Energy, Elsevier, vol. 142(C), pages 313-330.
    6. Qiu, Diankai & Peng, Linfa & Liang, Peng & Yi, Peiyun & Lai, Xinmin, 2018. "Mechanical degradation of proton exchange membrane along the MEA frame in proton exchange membrane fuel cells," Energy, Elsevier, vol. 165(PB), pages 210-222.

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