IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v188y2019ics0360544219318043.html
   My bibliography  Save this article

Thermodynamic and kinetic analysis of CuO-CaSO4 oxygen carrier in chemical looping gasification

Author

Listed:
  • Yang, Jie
  • Ma, Liping
  • Yang, Jing
  • Liu, Hongpan
  • Liu, Shengyu
  • Yang, Yingchun
  • Mu, Liusen
  • Wei, Yi
  • Ao, Ran
  • Guo, Zhiying
  • Dai, Quxiu
  • Wang, Huiming

Abstract

Chemical looping gasification (CLG) is an efficient coal gasification method and an emerging technology. In this process, the oxygen is from oxygen carriers such as CuO-CaSO4. The great reactivity characteristic of CuO-CaSO4 compound oxygen carrier has been confirmed by previous work. And, thermodynamics and kinetics are the vital parts of CLG process. To better understand the process of CLG with CuO-CaSO4, the thermodynamics and kinetics of CuO-CaSO4 CLG process has been investigated. In this work. A novel way was proposed to prepare to CuO-CaSO4 oxygen carrier with the industrial wast phosphogypsum (PG). And it showed that the molar ratio of PG to Cu element should be around 2. Activation energy was investigated by isoconversion method. In the CLG process, Activation energy was 86.4556 kJ/mol with CuO-CaSO4, However the activation energy was 145.6092 kJ/mol, when applied PG as oxygen carrier. Deeper studies showed that the mechanism of CLG with CuO-CaSO4 was controlled by product layer diffusion mechanisms of Shrinking Core Model (SCM) model. Therefore, theses phenomena indicate that CuO-CaSO4 is a recommended oxygen carrier in chemical looping technology.

Suggested Citation

  • Yang, Jie & Ma, Liping & Yang, Jing & Liu, Hongpan & Liu, Shengyu & Yang, Yingchun & Mu, Liusen & Wei, Yi & Ao, Ran & Guo, Zhiying & Dai, Quxiu & Wang, Huiming, 2019. "Thermodynamic and kinetic analysis of CuO-CaSO4 oxygen carrier in chemical looping gasification," Energy, Elsevier, vol. 188(C).
    • Handle: RePEc:eee:energy:v:188:y:2019:i:c:s0360544219318043
    DOI: 10.1016/j.energy.2019.116109
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219318043
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.116109?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wang, Lulu & Feng, Xuan & Shen, Laihong & Jiang, Shouxi & Gu, Haiming, 2019. "Carbon and sulfur conversion of petroleum coke in the chemical looping gasification process," Energy, Elsevier, vol. 179(C), pages 1205-1216.
    2. Kim, Ryang-Gyoon & Hwang, Chan-Won & Jeon, Chung-Hwan, 2014. "Kinetics of coal char gasification with CO2: Impact of internal/external diffusion at high temperature and elevated pressure," Applied Energy, Elsevier, vol. 129(C), pages 299-307.
    3. Yang, Jie & Wei, Yi & Yang, Jing & Xiang, Huaping & Ma, Liping & Zhang, Wei & Wang, Lichun & Peng, Yuhui & Liu, Hongpan, 2019. "Syngas production by chemical looping gasification using Fe supported on phosphogypsum compound oxygen carrier," Energy, Elsevier, vol. 168(C), pages 126-135.
    4. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2017. "Kinetic analysis of the interactions between calcium ferrite and coal char for chemical looping gasification applications: Identifying reduction routes and modes of oxygen transfer," Applied Energy, Elsevier, vol. 201(C), pages 94-110.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Du, Wang & Ma, Liping & Pan, Qinghuan & Dai, Quxiu & Zhang, Mi & Yin, Xia & Xiong, Xiong & Zhang, Wei, 2023. "Full-loop CFD simulation of lignite Chemical Looping Gasification with phosphogypsum as oxygen carrier using a circulating fluidized bed," Energy, Elsevier, vol. 262(PA).
    2. Krzywanski, J. & Czakiert, T. & Nowak, W. & Shimizu, T. & Zylka, A. & Idziak, K. & Sosnowski, M. & Grabowska, K., 2022. "Gaseous emissions from advanced CLC and oxyfuel fluidized bed combustion of coal and biomass in a complex geometry facility:A comprehensive model," Energy, Elsevier, vol. 251(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Gang & Lv, Xuewei & Ding, Chengyi & Zhou, Xuangeng & Zhong, Dapeng & Qiu, Guibao, 2020. "Non-isothermal carbothermic reduction kinetics of calcium ferrite and hematite as oxygen carriers for chemical looping gasification applications," Applied Energy, Elsevier, vol. 262(C).
    2. Ben-Mansour, R. & Li, H. & Habib, M.A., 2017. "Effects of oxygen carrier mole fraction, velocity distribution on conversion performance using an experimentally validated mathematical model of a CLC fuel reactor," Applied Energy, Elsevier, vol. 208(C), pages 803-819.
    3. Yang, Jie & Dong, Senlin & Xie, Longgui & Cen, Qihong & Zheng, Dalong & Ma, Liping & Dai, Quxiu, 2023. "Analysis of hydrogen-rich syngas generation in chemical looping gasification of lignite: Application of carbide slag as the oxygen carrier, hydrogen carrier, and in-situ carbon capture agent," Energy, Elsevier, vol. 283(C).
    4. Shah, Vedant & Cheng, Zhuo & Baser, Deven S. & Fan, Jonathan A. & Fan, Liang-Shih, 2021. "Highly Selective Production of Syngas from Chemical Looping Reforming of Methane with CO2 Utilization on MgO-supported Calcium Ferrite Redox Materials," Applied Energy, Elsevier, vol. 282(PA).
    5. Wu, Zhiqiang & Yang, Wangcai & Meng, Haiyu & Zhao, Jun & Chen, Lin & Luo, Zhengyuan & Wang, Shuzhong, 2017. "Physicochemical structure and gasification reactivity of co-pyrolysis char from two kinds of coal blended with lignocellulosic biomass: Effects of the carboxymethylcellulose sodium," Applied Energy, Elsevier, vol. 207(C), pages 96-106.
    6. Siriwardane, Ranjani & Riley, Jarrett & Atallah, Chris, 2022. "CO2 utilization potential of a novel calcium ferrite based looping process fueled with coal: Experimental evaluation of various coal feedstocks and thermodynamic integrated process analysis," Applied Energy, Elsevier, vol. 323(C).
    7. He, Qing & Gong, Yan & Ding, Lu & Guo, Qinghua & Yoshikawa, Kunio & Yu, Guangsuo, 2021. "Reactivity prediction and mechanism analysis of raw and demineralized coal char gasification," Energy, Elsevier, vol. 229(C).
    8. Tang, Genyang & Gu, Jing & Huang, Zhen & Yuan, Haoran & Chen, Yong, 2022. "Cellulose gasification with Ca–Fe oxygen carrier in chemical-looping process," Energy, Elsevier, vol. 239(PD).
    9. Gao, Zhuwei & Li, Chengxin & Qi, Xinyu & Wei, Yaodong & Liu, Zhongxin, 2022. "Flow analysis on carbonaceous deposition of heavy oil droplets and catalyst particles for coking formation process," Energy, Elsevier, vol. 260(C).
    10. Liu, Yacheng & Fan, Weidong & Li, Yu, 2016. "Numerical investigation of air-staged combustion emphasizing char gasification and gas temperature deviation in a large-scale, tangentially fired pulverized-coal boiler," Applied Energy, Elsevier, vol. 177(C), pages 323-334.
    11. Du, Wang & Ma, Liping & Pan, Qinghuan & Dai, Quxiu & Zhang, Mi & Yin, Xia & Xiong, Xiong & Zhang, Wei, 2023. "Full-loop CFD simulation of lignite Chemical Looping Gasification with phosphogypsum as oxygen carrier using a circulating fluidized bed," Energy, Elsevier, vol. 262(PA).
    12. Fredrik Hildor & Henrik Leion & Tobias Mattisson, 2022. "Steel Converter Slag as an Oxygen Carrier—Interaction with Sulfur Dioxide," Energies, MDPI, vol. 15(16), pages 1-29, August.
    13. Zeng, Jimin & Hu, Jiawei & Qiu, Yu & Zhang, Shuai & Zeng, Dewang & Xiao, Rui, 2019. "Multi-function of oxygen carrier for in-situ tar removal in chemical looping gasification: Naphthalene as a model compound," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    14. Li, Zhenwei & Xu, Hongpeng & Yang, Wenming & Wu, Shaohua, 2021. "Numerical study on the effective utilization of high sulfur petroleum coke for syngas production via chemical looping gasification," Energy, Elsevier, vol. 235(C).
    15. Wang, Kun & An, Zewen & Wang, Fengyin & Liang, Wenzheng & Wang, Cuiping & Guo, Qingjie & Liu, Yongzhuo & Yue, Guangxi, 2021. "Effect of ash on the performance of iron-based oxygen carrier in the chemical looping gasification of municipal sludge," Energy, Elsevier, vol. 231(C).
    16. Cheng, Long & Wu, Zhiqiang & Zhang, Zhiguo & Guo, Changqing & Ellis, Naoko & Bi, Xiaotao & Paul Watkinson, A. & Grace, John R., 2020. "Tar elimination from biomass gasification syngas with bauxite residue derived catalysts and gasification char," Applied Energy, Elsevier, vol. 258(C).
    17. Riley, Jarrett & Siriwardane, Ranjani & Tian, Hanjing & Benincosa, William & Poston, James, 2019. "Particle scale modeling of CuFeAlO4 during reduction with CO in chemical looping applications," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    18. Lei, Zhiping & Yan, Jingchong & Fang, Jia & Shui, Hengfu & Ren, Shibiao & Wang, Zhicai & Li, Zhanku & Kong, Ying & Kang, Shigang, 2021. "Catalytic combustion of coke and NO reduction in-situ under the action of Fe, Fe–CaO and Fe–CeO2," Energy, Elsevier, vol. 216(C).
    19. Cerciello, Francesca & Coppola, Antonio & Lacovig, Paolo & Senneca, Osvalda & Salatino, Piero, 2021. "Characterization of surface-oxides on char under periodically changing oxidation/desorption conditions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    20. Li, Fenghai & Zhao, Wei & Li, Junguo & Fan, Hongli & Xu, Meiling & Han, Guopeng & Guo, Mingxi & Wang, Zhiqing & Huang, Jiejie & Fang, Yitian, 2023. "Investigation on influencing mechanisms of phosphogypsum (PG) on the ash fusion behaviors of coal," Energy, Elsevier, vol. 268(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:188:y:2019:i:c:s0360544219318043. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.