IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v169y2019icp914-923.html
   My bibliography  Save this article

Experimental investigation and assessment of direct ammonia fuel cells utilizing alkaline molten and solid electrolytes

Author

Listed:
  • Siddiqui, O.
  • Dincer, I.

Abstract

In the present study, the solid anion exchange membrane and molten electrolyte entailing direct type ammonia fuel cells are uniquely developed, and their performances are investigated through energy and exergy efficiencies at varying operating conditions and state properties, based on the presently conducted experiments and datasets obtained. Both energy and exergy efficiencies are determined to be 12.1 ± 0.4% and 13.8 ± 0.4% respectively at the maximum power density value of 6.4 ± 0.2 W m−2 for the membrane based cell. Higher humidifier temperatures are observed to improve the performance of the fuel cell. The energy and exergy efficiencies of the molten alkaline electrolyte based cell are found to be 20.6 ± 0.6% and 23.3 ± 0.7% respectively at a temperature of 220 °C. The open circuit voltages are found as 278 ± 8 mV and 520 ± 16 mV for the anion exchange membrane and molten alkaline electrolyte based cells respectively. The open circuit voltage decreases and the short circuit current density increases with increasing electrolyte temperatures.

Suggested Citation

  • Siddiqui, O. & Dincer, I., 2019. "Experimental investigation and assessment of direct ammonia fuel cells utilizing alkaline molten and solid electrolytes," Energy, Elsevier, vol. 169(C), pages 914-923.
    • Handle: RePEc:eee:energy:v:169:y:2019:i:c:p:914-923
    DOI: 10.1016/j.energy.2018.12.096
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218324629
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.12.096?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Khani, Leyla & Mahmoudi, S. Mohammad S. & Chitsaz, Ata & Rosen, Marc A., 2016. "Energy and exergoeconomic evaluation of a new power/cooling cogeneration system based on a solid oxide fuel cell," Energy, Elsevier, vol. 94(C), pages 64-77.
    2. Miura, Daisuke & Tezuka, Tetsuo, 2014. "A comparative study of ammonia energy systems as a future energy carrier, with particular reference to vehicle use in Japan," Energy, Elsevier, vol. 68(C), pages 428-436.
    3. Li, Yanchao & Bi, Mingshu & Li, Bei & Zhou, Yonghao & Huang, Lei & Gao, Wei, 2018. "Explosion hazard evaluation of renewable hydrogen/ammonia/air fuels," Energy, Elsevier, vol. 159(C), pages 252-263.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Marco Osvaldo Vigueras-Zúñiga & Maria Elena Tejeda-del-Cueto & Syed Mashruk & Marina Kovaleva & Cesar Leonardo Ordóñez-Romero & Agustin Valera-Medina, 2021. "Methane/Ammonia Radical Formation during High Temperature Reactions in Swirl Burners," Energies, MDPI, vol. 14(20), pages 1-13, October.
    2. Blanco, Elena C. & Sánchez, Antonio & Martín, Mariano & Vega, Pastora, 2023. "Methanol and ammonia as emerging green fuels: Evaluation of a new power generation paradigm," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    3. Al-Hamed, K.H.M. & Dincer, Ibrahim, 2020. "A novel ammonia molten alkaline fuel cell based integrated powering system for clean rail transportation," Energy, Elsevier, vol. 201(C).
    4. Al-Hamed, Khaled H.M. & Dincer, Ibrahim, 2021. "A novel ammonia solid oxide fuel cell-based powering system with on-board hydrogen production for clean locomotives," Energy, Elsevier, vol. 220(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Perna, A. & Minutillo, M. & Jannelli, E. & Cigolotti, V. & Nam, S.W. & Han, J., 2018. "Design and performance assessment of a combined heat, hydrogen and power (CHHP) system based on ammonia-fueled SOFC," Applied Energy, Elsevier, vol. 231(C), pages 1216-1229.
    2. Huadao Xing & Runze Yu & Guangan Xu & Xiaodong Li & Yanyu Qiu & Derong Wang & Bin Li & Lifeng Xie, 2022. "Theoretical and Experimental Investigation of Explosion Characteristics of Hydrogen Explosion in a Closed Vessel," Energies, MDPI, vol. 15(22), pages 1-14, November.
    3. Xu, Haoran & Chen, Bin & Tan, Peng & Zhang, Houcheng & Yuan, Jinliang & Liu, Jiang & Ni, Meng, 2017. "Performance improvement of a direct carbon solid oxide fuel cell system by combining with a Stirling cycle," Energy, Elsevier, vol. 140(P1), pages 979-987.
    4. Esmaeil Jadidi & Mohammad Hasan Khoshgoftar Manesh & Mostafa Delpisheh & Viviani Caroline Onishi, 2021. "Advanced Exergy, Exergoeconomic, and Exergoenvironmental Analyses of Integrated Solar-Assisted Gasification Cycle for Producing Power and Steam from Heavy Refinery Fuels," Energies, MDPI, vol. 14(24), pages 1-29, December.
    5. Soleymani, Elahe & Ghavami Gargari, Saeed & Ghaebi, Hadi, 2021. "Thermodynamic and thermoeconomic analysis of a novel power and hydrogen cogeneration cycle based on solid SOFC," Renewable Energy, Elsevier, vol. 177(C), pages 495-518.
    6. Tian, Zhen & Zhou, Yihang & Zhang, Yuan & Gao, Wenzhong, 2024. "Design principle, 4E analyses and optimization for onboard CCS system under EEDI framework: A case study of an LNG-fueled bulk carrier," Energy, Elsevier, vol. 295(C).
    7. Zhang, Shaozhi & Luo, Jielin & Xu, Yiyang & Chen, Guangming & Wang, Qin, 2021. "Thermodynamic analysis of a combined cycle of ammonia-based battery and absorption refrigerator," Energy, Elsevier, vol. 220(C).
    8. Amirfazli, Amir & Asghari, Saeed & Sarraf, Mohammad, 2018. "An investigation into the effect of manifold geometry on uniformity of temperature distribution in a PEMFC stack," Energy, Elsevier, vol. 145(C), pages 141-151.
    9. Liu, Yang & Han, Jitian & You, Huailiang, 2020. "Exergoeconomic analysis and multi-objective optimization of a CCHP system based on LNG cold energy utilization and flue gas waste heat recovery with CO2 capture," Energy, Elsevier, vol. 190(C).
    10. Shamoushaki, Moein & Ehyaei, M.A. & Ghanatir, Farrokh, 2017. "Exergy, economic and environmental analysis and multi-objective optimization of a SOFC-GT power plant," Energy, Elsevier, vol. 134(C), pages 515-531.
    11. Liu, Lijuan & Zhang, Qi, 2019. "Flame range and energy output in two-phase propylene oxide/air mixtures beyond the original premixed zone," Energy, Elsevier, vol. 171(C), pages 666-677.
    12. Lu, Yawei & Fan, Rujia & Wang, Zhirong & Cao, Xingyan & Guo, Wenjie, 2024. "The influence of hydrogen concentration on the characteristic of explosion venting: Explosion pressure, venting flame and flow field microstructure," Energy, Elsevier, vol. 293(C).
    13. Ding, Xiaoyi & Sun, Wei & Harrison, Gareth P. & Lv, Xiaojing & Weng, Yiwu, 2020. "Multi-objective optimization for an integrated renewable, power-to-gas and solid oxide fuel cell/gas turbine hybrid system in microgrid," Energy, Elsevier, vol. 213(C).
    14. Lu, Hongfang & Lin, Bin-Le & Campbell, Daniel E. & Wang, Yanjia & Duan, Wenqi & Han, Taotao & Wang, Jun & Ren, Hai, 2022. "Australia-Japan telecoupling of wind power-based green ammonia for passenger transportation: Efficiency, impacts, and sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    15. Isa, Normazlina Mat & Tan, Chee Wei & Yatim, A.H.M., 2018. "A comprehensive review of cogeneration system in a microgrid: A perspective from architecture and operating system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 2236-2263.
    16. Fang, Zhenhua & Pan, Zhen & Ma, Guiyang & Yu, Jingxian & Shang, Liyan & Zhang, Zhien, 2023. "Exergoeconomic, exergoenvironmental analysis and multi-objective optimization of a novel combined cooling, heating and power system for liquefied natural gas cold energy recovery," Energy, Elsevier, vol. 269(C).
    17. Obara, Shin'ya, 2019. "Energy and exergy flows of a hydrogen supply chain with truck transportation of ammonia or methyl cyclohexane," Energy, Elsevier, vol. 174(C), pages 848-860.
    18. Hosseinpour, Javad & Chitsaz, Ata & Eisavi, Beneta & Yari, Mortaza, 2018. "Investigation on performance of an integrated SOFC-Goswami system using wood gasification," Energy, Elsevier, vol. 148(C), pages 614-628.
    19. Yukio Watanabe & Wataru Aoki & Mitsuyoshi Ueda, 2021. "Sustainable Biological Ammonia Production towards a Carbon-Free Society," Sustainability, MDPI, vol. 13(17), pages 1-13, August.
    20. Liu, Xing & Wang, Ying & Bai, Yuanqi & Yang, Wenxu, 2023. "Development of reduced and optimized mechanism for ammonia/ hydrogen mixture based on genetic algorithm," Energy, Elsevier, vol. 270(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:169:y:2019:i:c:p:914-923. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.