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Effect of hydrogen peroxide additive on the combustion and emission characteristics of an n-butanol homogeneous charge compression ignition engine

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  • Zhou, Ao
  • Zhang, Chunhua
  • Li, Yangyang
  • Li, Songfeng
  • Yin, Peng

Abstract

The homogeneous charge compression ignition (HCCI) combustion was conducted on a modified engine to investigate the effect of hydrogen peroxide (H2O2) additive on the combustion and emission characteristics, such as the indicated thermal efficiency (ηi), the total hydrocarbon (THC), the carbon monoxide (CO) and the nitrogen oxides (NOx) emissions. A simulation using CHEMKIN software was also performed to analyze the experimental data. The results indicate that the addition of H2O2 facilitates the formation of hydroxyl (OH) radical and hydroperoxyl (HO2) radical in the cylinder under HCCI mode, which greatly affects the combustion and emission characteristics of the n-butanol HCCI engine. By adding H2O2, ηi increases, NOx emission remains at an ultra-low level, but THC and CO emissions reduce at almost all the test conditions. Especially at the low intake temperature (Tin) or low load condition, the improvements are very obvious, which suggests that addition of H2O2 may extend the low Tin and low load limits of HCCI engines.

Suggested Citation

  • Zhou, Ao & Zhang, Chunhua & Li, Yangyang & Li, Songfeng & Yin, Peng, 2019. "Effect of hydrogen peroxide additive on the combustion and emission characteristics of an n-butanol homogeneous charge compression ignition engine," Energy, Elsevier, vol. 169(C), pages 572-579.
  • Handle: RePEc:eee:energy:v:169:y:2019:i:c:p:572-579
    DOI: 10.1016/j.energy.2018.12.076
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    References listed on IDEAS

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    1. Bissoli, M. & Frassoldati, A. & Cuoci, A. & Ranzi, E. & Mehl, M. & Faravelli, T., 2016. "A new predictive multi-zone model for HCCI engine combustion," Applied Energy, Elsevier, vol. 178(C), pages 826-843.
    2. Zhang, Chao & Zhang, Chunhua & Xue, Le & Li, Yangyang, 2017. "Combustion characteristics and operation range of a RCCI combustion engine fueled with direct injection n-heptane and pipe injection n-butanol," Energy, Elsevier, vol. 125(C), pages 439-448.
    3. Qian, Yong & Li, Hua & Han, Dong & Ji, Libin & Huang, Zhen & Lu, Xingcai, 2016. "Octane rating effects of direct injection fuels on dual fuel HCCI-DI stratified combustion mode with port injection of n-heptane," Energy, Elsevier, vol. 111(C), pages 1003-1016.
    4. Han, Xiaoye & Yang, Zhenyi & Wang, Meiping & Tjong, Jimi & Zheng, Ming, 2017. "Clean combustion of n-butanol as a next generation biofuel for diesel engines," Applied Energy, Elsevier, vol. 198(C), pages 347-359.
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