IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v218y2021ics0360544220325111.html
   My bibliography  Save this article

Thermal, kinetic and thermodynamic study for co-pyrolysis of pine needles and styrofoam using thermogravimetric analysis

Author

Listed:
  • Varma, Anil Kumar
  • Lal, Navneeta
  • Rathore, Ashwani Kumar
  • Katiyar, Rajesh
  • Thakur, Lokendra Singh
  • Shankar, Ravi
  • Mondal, Prasenjit

Abstract

This study investigate the thermal decomposition behavior of pine needles (PN), styrofoam (SF) as well as their mixture at ratio of 1:1 (w/w), determine the kinetic and thermodynamic parameters for co-pyrolysis of PN and SF using thermogravimetric analysis (TGA) data. The co-pyrolysis experiments were performed in an inert environment (N2) at three variable heating rates of 5, 10 and 20 °C/min in TG analyzer from 35 to 850 °C. TGA outcomes represent that the thermal degradation of PN occurred in three stages, while SF degradation took place in a single stage and degradation of their mixture occurred in three stages. Model-free methods such as Ozawa-Flynn-Wall (OFW) and Kissinger-Akahira-Sunose (KAS) were employed to findout the activation energy (Ea) for co-pyrolysis of PN and SF. Moreover, the thermodynamic parameters (changes in enthalpy, Gibbs free energy and entropy) were also determined by OFW method. The pre-exponential factors were also evaluated by model-fitting (Coats-Redfern) method. The average of Ea for co-pyrolysis of PN and SF determined by KAS and OFW methods was 96.44 and 109.73 kJ/mol, respectively. The results of this study suggest that PN and SF mixture has potential to be used as a pyrolysis feedstocks.

Suggested Citation

  • Varma, Anil Kumar & Lal, Navneeta & Rathore, Ashwani Kumar & Katiyar, Rajesh & Thakur, Lokendra Singh & Shankar, Ravi & Mondal, Prasenjit, 2021. "Thermal, kinetic and thermodynamic study for co-pyrolysis of pine needles and styrofoam using thermogravimetric analysis," Energy, Elsevier, vol. 218(C).
    • Handle: RePEc:eee:energy:v:218:y:2021:i:c:s0360544220325111
    DOI: 10.1016/j.energy.2020.119404
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544220325111
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2020.119404?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Burra, K.G. & Gupta, A.K., 2018. "Kinetics of synergistic effects in co-pyrolysis of biomass with plastic wastes," Applied Energy, Elsevier, vol. 220(C), pages 408-418.
    2. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    3. Xiu, Shuangning & Shahbazi, Abolghasem, 2012. "Bio-oil production and upgrading research: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4406-4414.
    4. Hassan, H. & Hameed, B.H. & Lim, J.K., 2020. "Co-pyrolysis of sugarcane bagasse and waste high-density polyethylene: Synergistic effect and product distributions," Energy, Elsevier, vol. 191(C).
    5. Navarro, M.V. & López, J.M. & Veses, A. & Callén, M.S. & García, T., 2018. "Kinetic study for the co-pyrolysis of lignocellulosic biomass and plastics using the distributed activation energy model," Energy, Elsevier, vol. 165(PA), pages 731-742.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Yuanbo & Zhang, Yutao & Li, Yaqing & Shi, Xueqiang & Che, Bo, 2022. "Determination of ignition temperature and kinetics and thermodynamics analysis of high-volatile coal based on differential derivative thermogravimetry," Energy, Elsevier, vol. 240(C).
    2. El Farissi, Hammadi & Talhaoui, Abdelmonaem & EL Bachiri, Ali, 2023. "Cistus shells used as a sustainable matrix for bioenergy production through slow pyrolysis process: Kinetic and thermodynamic study," Renewable Energy, Elsevier, vol. 218(C).
    3. Luo, Laipeng & Zhang, Zhiyi & Li, Chong & Nishu, & He, Fang & Zhang, Xingguang & Cai, Junmeng, 2021. "Insight into master plots method for kinetic analysis of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 233(C).
    4. Nishu, & Tang, Songbiao & Mei, Wenjie & Yang, Juntao & Wang, Zhongming & Yang, Gaixiu, 2024. "Effect of anaerobic digestion pretreatment on pyrolysis of distillers’ grain: Product distribution, kinetics and thermodynamics analysis," Renewable Energy, Elsevier, vol. 221(C).
    5. Ewa Syguła & Kacper Świechowski & Małgorzata Hejna & Ines Kunaszyk & Andrzej Białowiec, 2021. "Municipal Solid Waste Thermal Analysis—Pyrolysis Kinetics and Decomposition Reactions," Energies, MDPI, vol. 14(15), pages 1-27, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Nawaz, Ahmad & Razzak, Shaikh Abdur, 2024. "Co-pyrolysis of biomass and different plastic waste to reduce hazardous waste and subsequent production of energy products: A review on advancement, synergies, and future prospects," Renewable Energy, Elsevier, vol. 224(C).
    2. Juan Luis Aguirre & Juan Baena & María Teresa Martín & Leonor Nozal & Sergio González & José Luis Manjón & Manuel Peinado, 2020. "Composition, Ageing and Herbicidal Properties of Wood Vinegar Obtained through Fast Biomass Pyrolysis," Energies, MDPI, vol. 13(10), pages 1-17, May.
    3. Li, Chao & Sun, Yifan & Yi, Zijun & Zhang, Lijun & Zhang, Shu & Hu, Xun, 2022. "Co-pyrolysis of coke bottle wastes with cellulose, lignin and sawdust: Impacts of the mixed feedstock on char properties," Renewable Energy, Elsevier, vol. 181(C), pages 1126-1139.
    4. Beims, R.F. & Simonato, C.L. & Wiggers, V.R., 2019. "Technology readiness level assessment of pyrolysis of trygliceride biomass to fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 521-529.
    5. Leng, Lijian & Li, Hui & Yuan, Xingzhong & Zhou, Wenguang & Huang, Huajun, 2018. "Bio-oil upgrading by emulsification/microemulsification: A review," Energy, Elsevier, vol. 161(C), pages 214-232.
    6. Burra, Kiran Raj G. & Liu, Xuan & Wang, Zhiwei & Li, Jinhu & Che, Defu & Gupta, Ashwani K., 2021. "Quantifying the sources of synergistic effects in co-pyrolysis of pinewood and polystyrene," Applied Energy, Elsevier, vol. 302(C).
    7. Kan, Tao & Strezov, Vladimir & Evans, Tim & He, Jing & Kumar, Ravinder & Lu, Qiang, 2020. "Catalytic pyrolysis of lignocellulosic biomass: A review of variations in process factors and system structure," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    8. Li, Qingyin & Lin, Haisheng & Fan, Huailin & Zhang, Shu & Yuan, Xiangzhou & Wang, Yi & Xiang, Jun & Hu, Song & Bkangmo Kontchouo, Félix Mérimé & Hu, Xun, 2021. "Co-pyrolysis of swine manure and pinewood sawdust: Evidence of cross-interaction of the volatiles and profound impacts on product characteristics," Renewable Energy, Elsevier, vol. 179(C), pages 1370-1384.
    9. Luo, Wei & Hu, Qing & Fan, Zhong-yi & Wan, Jun & He, Qian & Huang, Sheng-xiong & Zhou, Nan & Song, Min & Zhang, Jia-chao & Zhou, Zhi, 2020. "The effect of different particle sizes and HCl-modified kaolin on catalytic pyrolysis characteristics of reworked polypropylene plastics," Energy, Elsevier, vol. 213(C).
    10. Ribeiro, Luiz Augusto Badan & Martins, Robson Cristiano & Mesa-Pérez, Juan Miguel & Bizzo, Waldir Antonio, 2019. "Study of bio-oil properties and ageing through fractionation and ternary mixtures with the heavy fraction as the main component," Energy, Elsevier, vol. 169(C), pages 344-355.
    11. Xiao, Ruirui & Yang, Wei & Cong, Xingshun & Dong, Kai & Xu, Jie & Wang, Dengfeng & Yang, Xin, 2020. "Thermogravimetric analysis and reaction kinetics of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 201(C).
    12. Peters, Jens F. & Banks, Scott W. & Bridgwater, Anthony V. & Dufour, Javier, 2017. "A kinetic reaction model for biomass pyrolysis processes in Aspen Plus," Applied Energy, Elsevier, vol. 188(C), pages 595-603.
    13. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    14. Andrew N. Amenaghawon & Chinedu L. Anyalewechi & Charity O. Okieimen & Heri Septya Kusuma, 2021. "Biomass pyrolysis technologies for value-added products: a state-of-the-art review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14324-14378, October.
    15. Aktas, Fatih & Mavukwana, Athi-enkosi & Burra, Kiran Raj Goud & Gupta, Ashwani K., 2024. "Role of spent FCC catalyst in pyrolysis and CO2-assisted gasification of pinewood," Applied Energy, Elsevier, vol. 366(C).
    16. Xie, Teng & Yao, Zonglu & Huo, Lili & Jia, Jixiu & Zhang, Peizhen & Tian, Liwei & Zhao, Lixin, 2023. "Characteristics of biochar derived from the co-pyrolysis of corn stalk and mulch film waste," Energy, Elsevier, vol. 262(PB).
    17. Feng, Qunjie & Lin, Yunqin, 2017. "Integrated processes of anaerobic digestion and pyrolysis for higher bioenergy recovery from lignocellulosic biomass: A brief review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1272-1287.
    18. Douglas Alberto Rocha de Castro & Haroldo Jorge da Silva Ribeiro & Lauro Henrique Hamoy Guerreiro & Lucas Pinto Bernar & Sami Jonatan Bremer & Marcelo Costa Santo & Hélio da Silva Almeida & Sergio Duv, 2021. "Production of Fuel-Like Fractions by Fractional Distillation of Bio-Oil from Açaí ( Euterpe oleracea Mart.) Seeds Pyrolysis," Energies, MDPI, vol. 14(13), pages 1-27, June.
    19. Dmitry Porshnov, 2022. "Evolution of pyrolysis and gasification as waste to energy tools for low carbon economy," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(1), January.
    20. Arabiourrutia, Miriam & Lopez, Gartzen & Artetxe, Maite & Alvarez, Jon & Bilbao, Javier & Olazar, Martin, 2020. "Waste tyre valorization by catalytic pyrolysis – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 129(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:218:y:2021:i:c:s0360544220325111. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.