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Generation of biofuel from hydrothermal carbonization of cellulose. Kinetics modelling

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  • Álvarez-Murillo, A.
  • Sabio, E.
  • Ledesma, B.
  • Román, S.
  • González-García, C.M.

Abstract

Kinetics of cellulose hydrothermal carbonization was investigated over different reactions times and temperatures, developing a first order-reaction model, where chemical and heat transfer processes were connected and resolved simultaneously. According to the model, mass species evolutions are described by sigmoid curves and the presence of an induction period confirms the importance of taking into account the heat-up time and not only the T-constant period during the experiments. Moreover, the model indicates that temperature plays a main role on cellulose HTC (hydrothermal carbonization) reaction, affecting both pre-exponential and exponential factors of the kinetic constant. Finally, it is interesting to remark, from a practical viewpoint, that the model was able to describe the changes in H/C, O/C and high heating value taking place during cellulose hydrocarbonization, allowing the chemical composition and energy densification to be forecasted.

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  • Álvarez-Murillo, A. & Sabio, E. & Ledesma, B. & Román, S. & González-García, C.M., 2016. "Generation of biofuel from hydrothermal carbonization of cellulose. Kinetics modelling," Energy, Elsevier, vol. 94(C), pages 600-608.
    • Handle: RePEc:eee:energy:v:94:y:2016:i:c:p:600-608
    DOI: 10.1016/j.energy.2015.11.024
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    1. Gao, Ying & Wang, Xian-Hua & Yang, Hai-Ping & Chen, Han-Ping, 2012. "Characterization of products from hydrothermal treatments of cellulose," Energy, Elsevier, vol. 42(1), pages 457-465.
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    9. Mitchell Ubene & Mohammad Heidari & Animesh Dutta, 2022. "Computational Modeling Approaches of Hydrothermal Carbonization: A Critical Review," Energies, MDPI, vol. 15(6), pages 1-28, March.
    10. Michela Lucian & Maurizio Volpe & Luca Fiori, 2019. "Hydrothermal Carbonization Kinetics of Lignocellulosic Agro-Wastes: Experimental Data and Modeling," Energies, MDPI, vol. 12(3), pages 1-20, February.
    11. Kumar, Mayank & Olajire Oyedun, Adetoyese & Kumar, Amit, 2018. "A review on the current status of various hydrothermal technologies on biomass feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1742-1770.
    12. Román, S. & Ledesma, B. & Álvarez, A. & Coronella, C. & Qaramaleki, S.V., 2020. "Suitability of hydrothermal carbonization to convert water hyacinth to added-value products," Renewable Energy, Elsevier, vol. 146(C), pages 1649-1658.
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    14. Silvia Román & Judy Libra & Nicole Berge & Eduardo Sabio & Kyoung Ro & Liang Li & Beatriz Ledesma & Andrés Álvarez & Sunyoung Bae, 2018. "Hydrothermal Carbonization: Modeling, Final Properties Design and Applications: A Review," Energies, MDPI, vol. 11(1), pages 1-28, January.

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