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Enhanced performance of microbial fuel cells by using MnO2/Halloysite nanotubes to modify carbon cloth anodes

Author

Listed:
  • Chen, Yingwen
  • Chen, Liuliu
  • Li, Peiwen
  • Xu, Yuan
  • Fan, Mengjie
  • Zhu, Shemin
  • Shen, Shubao

Abstract

The modification of anode materials is important to enhance the power generation of MFCs (microbial fuel cells). A novel and cost-effective modified anode that is fabricated by dispersing manganese dioxide (MnO2) and HNTs (Halloysite nanotubes) on carbon cloth to improve the MFCs' power production was reported. The results show that the MnO2/HNT anodes acquire more bacteria and provide greater kinetic activity and power density compared to the unmodified anode. Among all modified anodes, 75 wt% MnO2/HNT exhibits the highest electrochemical performance. The maximum power density is 767.3 mWm−2, which 21.6 higher than the unmodified anode (631 mW/m2). Besides, CE (Coulombic efficiency) was improved 20.7, indicating that more chemical energy transformed to electricity. XRD (X-Ray powder diffraction) and FTIR (Fourier transform infrared spectroscopy) are used to characterize the structure and functional groups of the anode. CV (cyclic voltammetry) scans and SEM (scanning electron microscope) images demonstrate that the measured power density is associated with the attachment of bacteria, the microorganism morphology differed between the modified and the original anode. These findings demonstrate that MnO2/HNT nanocomposites can alter the characteristics of carbon cloth anodes to effectively modify the anode for practical MFC applications.

Suggested Citation

  • Chen, Yingwen & Chen, Liuliu & Li, Peiwen & Xu, Yuan & Fan, Mengjie & Zhu, Shemin & Shen, Shubao, 2016. "Enhanced performance of microbial fuel cells by using MnO2/Halloysite nanotubes to modify carbon cloth anodes," Energy, Elsevier, vol. 109(C), pages 620-628.
    • Handle: RePEc:eee:energy:v:109:y:2016:i:c:p:620-628
    DOI: 10.1016/j.energy.2016.05.041
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    Cited by:

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    2. Wang, Yuyang, 2024. "Carbon felt electrode modified with RGO/PANI composite material for enhancing renewable energy storage in microbial fuel cells," Renewable Energy, Elsevier, vol. 232(C).
    3. Wang, Yuyang & Wang, Zhijie & Hu, Guangxu, 2023. "Bifunctional polypyrrole/ferroferric oxide as anode material for enhanced electricity generation and energy storage in microbial fuel cell," Renewable Energy, Elsevier, vol. 219(P1).
    4. Shahid, Kanwal & Ramasamy, Deepika Lakshmi & Haapasaari, Sampo & Sillanpää, Mika & Pihlajamäki, Arto, 2021. "Stainless steel and carbon brushes as high-performance anodes for energy production and nutrient recovery using the microbial nutrient recovery system," Energy, Elsevier, vol. 233(C).
    5. Wang, Yuyang & Chen, Ye & Wen, Qing & Zheng, Hongtao & Xu, Haitao & Qi, Lijuan, 2019. "Electricity generation, energy storage, and microbial-community analysis in microbial fuel cells with multilayer capacitive anodes," Energy, Elsevier, vol. 189(C).
    6. Sekar, Aiswarya Devi & Jayabalan, Tamilmani & Muthukumar, Harshiny & Chandrasekaran, Nivedhini Iswarya & Mohamed, Samsudeen Naina & Matheswaran, Manickam, 2019. "Enhancing power generation and treatment of dairy waste water in microbial fuel cell using Cu-doped iron oxide nanoparticles decorated anode," Energy, Elsevier, vol. 172(C), pages 173-180.
    7. Zinadini, S. & Zinatizadeh, A.A. & Rahimi, M. & Vatanpour, V. & Bahrami, K., 2017. "Energy recovery and hygienic water production from wastewater using an innovative integrated microbial fuel cell–membrane separation process," Energy, Elsevier, vol. 141(C), pages 1350-1362.

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