IDEAS home Printed from https://ideas.repec.org/a/wly/greenh/v8y2018i3p542-556.html
   My bibliography  Save this article

Performance of a Cu–Fe‐based oxygen carrier combined with a Ni‐based oxygen carrier in a chemical‐looping combustion process based on fixed‐bed reactors

Author

Listed:
  • Qiang Tian
  • Lixin Che
  • Bin Ding
  • Qianwei Wang
  • Qingquan Su

Abstract

The application of chemical‐looping combustion (CLC) based on fixed‐bed reactors for distributed medium‐ and small‐scale hot‐water and steam gas‐fuelled boilers is promising due to its low NOx emission, high energy efficiency and nearly zero energy consumption in carbon capture. For fixed‐bed reactors, a wide operating temperature window (Tw) for the oxygen carrier (OC) is crucial to ensure the performance and cycle life of the OC. The performance of Cu30–Fe50/Al20‐M combined with different Ni‐based OCs was investigated to extend the Tw(L) of 600°C for Cu30–Fe50/Al20‐M to a lower temperature, which was developed previously. The different Ni‐based OCs would work as CH4 steam reforming catalysts if their required reduction temperatures were significantly lower than the Tw(L) of Cu30–Fe50/Al20‐M. Results showed that a Ni‐based OC of Ni60/Al40‐M could be reduced with CH4/H2O with an S/C of 1.0 at a temperature of 450°C. The combination of Cu30–Fe50/Al20 and Ni25/Al75‐I, which was packed in the bed by a mixing method, exhibited a low‐temperature reactivity and Tw(L) was lowered from 600°C to 490°C. Moreover, carbon deposition and an intermediate compound, NiFe2O4, which was found in a composite OC of Ni–Cu–Fe–/Al, were not detected during the reduction step. Based on the results, a new CLC process, which was characterised by an integrated methane steam reforming in the reduction step, was proposed. © 2018 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • Qiang Tian & Lixin Che & Bin Ding & Qianwei Wang & Qingquan Su, 2018. "Performance of a Cu–Fe‐based oxygen carrier combined with a Ni‐based oxygen carrier in a chemical‐looping combustion process based on fixed‐bed reactors," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(3), pages 542-556, June.
    • Handle: RePEc:wly:greenh:v:8:y:2018:i:3:p:542-556
    DOI: 10.1002/ghg.1763
    as

    Download full text from publisher

    File URL: https://doi.org/10.1002/ghg.1763
    Download Restriction: no
    File URL: https://libkey.io/10.1002/ghg.1763?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhang, Shuai & Xiao, Rui & Zheng, Wenguang, 2014. "Comparative study between fluidized-bed and fixed-bed operation modes in pressurized chemical looping combustion of coal," Applied Energy, Elsevier, vol. 130(C), pages 181-189.
    2. Han, Lu & Bollas, George M., 2016. "Chemical-looping combustion in a reverse-flow fixed bed reactor," Energy, Elsevier, vol. 102(C), pages 669-681.
    3. Qiang Tian & Lixin Che & Bin Ding & Qianwei Wang & Qingquan Su, 2017. "Performance of Cu‐Fe‐based oxygen carrier in a CLC process based on fixed bed reactors," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(4), pages 731-744, August.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Qiang Tian & Lixin Che & Bin Ding & Qianwei Wang & Qingquan Su, 2017. "Performance of Cu‐Fe‐based oxygen carrier in a CLC process based on fixed bed reactors," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(4), pages 731-744, August.
    2. Zhang, Hao & Hong, Hui & Jiang, Qiongqiong & Deng, Ya'nan & Jin, Hongguang & Kang, Qilan, 2018. "Development of a chemical-looping combustion reactor having porous honeycomb chamber and experimental validation by using NiO/NiAl2O4," Applied Energy, Elsevier, vol. 211(C), pages 259-268.
    3. Tomasz Czakiert & Jaroslaw Krzywanski & Anna Zylka & Wojciech Nowak, 2022. "Chemical Looping Combustion: A Brief Overview," Energies, MDPI, vol. 15(4), pages 1-19, February.
    4. Gao, Zixiang & Wu, Di & Yin, Fan & Sun, Liyan & Zeng, Dewang & Xiao, Rui, 2024. "Thermodynamic and kinetic analysis on the biomass syngas fueled chemical looping hydrogen generation process in fixed bed reactor," Energy, Elsevier, vol. 298(C).
    5. Voitic, Gernot & Nestl, Stephan & Lammer, Michael & Wagner, Julian & Hacker, Viktor, 2015. "Pressurized hydrogen production by fixed-bed chemical looping," Applied Energy, Elsevier, vol. 157(C), pages 399-407.
    6. Xing Chen & Shuai Zhang & Rui Xiao & Peng Li, 2017. "Modification of traditionally impregnated Fe 2 O 3 /Al 2 O 3 oxygen carriers by ultrasonic method and their performance in chemical looping combustion," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(1), pages 65-77, February.
    7. Zhao, Ying-jie & Zhang, Yu-ke & Cui, Yang & Duan, Yuan-yuan & Huang, Yi & Wei, Guo-qiang & Mohamed, Usama & Shi, Li-juan & Yi, Qun & Nimmo, William, 2022. "Pinch combined with exergy analysis for heat exchange network and techno-economic evaluation of coal chemical looping combustion power plant with CO2 capture," Energy, Elsevier, vol. 238(PA).
    8. Nandy, Anirban & Loha, Chanchal & Gu, Sai & Sarkar, Pinaki & Karmakar, Malay K. & Chatterjee, Pradip K., 2016. "Present status and overview of Chemical Looping Combustion technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 597-619.
    9. Penthor, Stefan & Zerobin, Florian & Mayer, Karl & Pröll, Tobias & Hofbauer, Hermann, 2015. "Investigation of the performance of a copper based oxygen carrier for chemical looping combustion in a 120kW pilot plant for gaseous fuels," Applied Energy, Elsevier, vol. 145(C), pages 52-59.
    10. Gu, Zhenhua & Li, Kongzhai & Wang, Hua & Qing, Shan & Zhu, Xing & Wei, Yonggang & Cheng, Xianming & Yu, He & Cao, Yan, 2016. "Bulk monolithic Ce–Zr–Fe–O/Al2O3 oxygen carriers for a fixed bed scheme of the chemical looping combustion: Reactivity of oxygen carrier," Applied Energy, Elsevier, vol. 163(C), pages 19-31.
    11. Zeng, Jimin & Xiao, Rui & Yuan, Jun, 2021. "High-quality syngas production from biomass driven by chemical looping on a PY-GA coupled reactor," Energy, Elsevier, vol. 214(C).
    12. Bartocci, Pietro & Abad, Alberto & Mattisson, Tobias & Cabello, Arturo & Loscertales, Margarita de las Obras & Negredo, Teresa Mendiara & Zampilli, Mauro & Taiana, Andrea & Serra, Angela & Arauzo, Inm, 2022. "Bioenergy with Carbon Capture and Storage (BECCS) developed by coupling a Pressurised Chemical Looping combustor with a turbo expander: How to optimize plant efficiency," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    13. Pietro Bartocci & Alberto Abad & Aldo Bischi & Lu Wang & Arturo Cabello & Margarita de Las Obras Loscertales & Mauro Zampilli & Haiping Yang & Francesco Fantozzi, 2023. "Dimensioning Air Reactor and Fuel Reactor of a Pressurized Chemical Looping Combustor to Be Coupled to a Gas Turbine: Part 1, the Air Reactor," Energies, MDPI, vol. 16(5), pages 1-20, February.
    14. Mayer, Karl & Penthor, Stefan & Pröll, Tobias & Hofbauer, Hermann, 2015. "The different demands of oxygen carriers on the reactor system of a CLC plant – Results of oxygen carrier testing in a 120kWth pilot plant," Applied Energy, Elsevier, vol. 157(C), pages 323-329.
    15. Lu, Xuao & Rahman, Ryad A. & Lu, Dennis Y. & Ridha, Firas N. & Duchesne, Marc A. & Tan, Yewen & Hughes, Robin W., 2016. "Pressurized chemical looping combustion with CO: Reduction reactivity and oxygen-transport capacity of ilmenite ore," Applied Energy, Elsevier, vol. 184(C), pages 132-139.
    16. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    17. Sreenivasulu, B. & Gayatri, D.V. & Sreedhar, I. & Raghavan, K.V., 2015. "A journey into the process and engineering aspects of carbon capture technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1324-1350.
    18. Jacobs, M. & Van Noyen, J. & Larring, Y. & Mccann, M. & Pishahang, M. & Amini, S. & Ortiz, M. & Galluci, F. & Sint-Annaland, M.V. & Tournigant, D. & Louradour, E. & Snijkers, F., 2015. "Thermal and mechanical behaviour of oxygen carrier materials for chemical looping combustion in a packed bed reactor," Applied Energy, Elsevier, vol. 157(C), pages 374-381.
    19. Güleç, Fatih & Meredith, Will & Sun, Cheng-Gong & Snape, Colin E., 2019. "Selective low temperature chemical looping combustion of higher alkanes with Cu- and Mn- oxides," Energy, Elsevier, vol. 173(C), pages 658-666.
    20. Han, Lu & Bollas, George M., 2016. "Dynamic optimization of fixed bed chemical-looping combustion processes," Energy, Elsevier, vol. 112(C), pages 1107-1119.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wly:greenh:v:8:y:2018:i:3:p:542-556. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Wiley Content Delivery (email available below). General contact details of provider: https://doi.org/10.1002/(ISSN)2152-3878 .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.