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Bioethanol production from mandarin (Citrus unshiu) peel waste using popping pretreatment

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  • Choi, In Seong
  • Kim, Jae-Hoon
  • Wi, Seung Gon
  • Kim, Kyoung Hyoun
  • Bae, Hyeun-Jong

Abstract

In this study, we designed a biomass popping pretreatment, system using a fired burner and a horizontal cylinder rotating on an axis, to produce ethanol from mandarin (Citrus unshiu) peel (MP) waste. Popping pretreatment was performed at 150°C for 10min without chemical treatment. Popping pretreatment reduced the size of particles to less than 1mm and decreased the concentration of d-limonene, a yeast fermentation inhibitor, from 0.21% to 0.01%. Enzymatic hydrolysis of pretreated MP was performed in 50mM sodium acetate buffer (pH 4.8) at 45°C for 6h, and the total saccharification rate was approximately 95.6%. The vacuum evaporation process increased the fermentable sugar concentration to 10% (glucose 7.1% and fructose 2.9%). Subsequent fermentation at 30°C at pH 5.0 for 12h in a laboratory bioreactor increased the ethanol yield to 90.6%, compared to 78% at 36h from raw MP.

Suggested Citation

  • Choi, In Seong & Kim, Jae-Hoon & Wi, Seung Gon & Kim, Kyoung Hyoun & Bae, Hyeun-Jong, 2013. "Bioethanol production from mandarin (Citrus unshiu) peel waste using popping pretreatment," Applied Energy, Elsevier, vol. 102(C), pages 204-210.
    • Handle: RePEc:eee:appene:v:102:y:2013:i:c:p:204-210
    DOI: 10.1016/j.apenergy.2012.03.066
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    3. Peng, Huadong & Chen, Hongzhang & Qu, Yongshui & Li, Hongqiang & Xu, Jian, 2014. "Bioconversion of different sizes of microcrystalline cellulose pretreated by microwave irradiation with/without NaOH," Applied Energy, Elsevier, vol. 117(C), pages 142-148.
    4. Choi, In Seong & Kim, Young Gyu & Jung, Ja Kyun & Bae, Hyeun-Jong, 2015. "Soybean waste (okara) as a valorization biomass for the bioethanol production," Energy, Elsevier, vol. 93(P2), pages 1742-1747.
    5. Taghizadeh-Alisaraei, Ahmad & Motevali, Ali & Ghobadian, Barat, 2019. "Ethanol production from date wastes: Adapted technologies, challenges, and global potential," Renewable Energy, Elsevier, vol. 143(C), pages 1094-1110.
    6. Su, Guandong & Chan, Claire & He, Jianzhong, 2022. "Enhanced biobutanol production from starch waste via orange peel doping," Renewable Energy, Elsevier, vol. 193(C), pages 576-583.
    7. Rossella Vadalà & Giovanna Lo Vecchio & Rossana Rando & Michelangelo Leonardi & Nicola Cicero & Rosaria Costa, 2023. "A Sustainable Strategy for the Conversion of Industrial Citrus Fruit Waste into Bioethanol," Sustainability, MDPI, vol. 15(12), pages 1-11, June.
    8. Thangavelu, Saravana Kannan & Ahmed, Abu Saleh & Ani, Farid Nasir, 2016. "Review on bioethanol as alternative fuel for spark ignition engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 820-835.
    9. Taghizadeh-Alisaraei, Ahmad & Hosseini, Seyyed Hasan & Ghobadian, Barat & Motevali, Ali, 2017. "Biofuel production from citrus wastes: A feasibility study in Iran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 1100-1112.
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