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Thermal conversion of defective coffee beans for energy purposes: Characterization and kinetic modeling

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  • Santos, Carolina Monteiro
  • de Oliveira, Leandro Soares
  • Alves Rocha, Elém Patrícia
  • Franca, Adriana Silva

Abstract

This work aimed to characterize the fuel properties and to evaluate the kinetics of thermal decomposition of defective coffee beans (DCB). Three thermogravimetric-based methods were evaluated: Ozawa-Flynn-Wall (OFW), Kissinger-Akahira-Sunose (KAS) and Friedman. The results showed that DCB presented low activation energy and that the evaluated mathematical models, although satisfactory for describing thermal decomposition in inert atmospheres, did not provide a satisfactory description of the oxidizing process. The enthalpy values indicated that the energy differences between the reagents and the activated complex are related directly to the activation energies. Pre-exponential factors indicated first-order reactions. The immediate analysis and the lignocellulosic contents indicated a biomass with low levels of humidity and ashes, high carbon and volatile concentrations, besides thermal stability. The obtained calorific value was 19.39 MJ/kg. The overall results obtained in the present study indicate that this biomass has the potential to be used as a solid biofuel.

Suggested Citation

  • Santos, Carolina Monteiro & de Oliveira, Leandro Soares & Alves Rocha, Elém Patrícia & Franca, Adriana Silva, 2020. "Thermal conversion of defective coffee beans for energy purposes: Characterization and kinetic modeling," Renewable Energy, Elsevier, vol. 147(P1), pages 1275-1291.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:1275-1291
    DOI: 10.1016/j.renene.2019.09.052
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    1. Lu, Ke-Miao & Lee, Wen-Jhy & Chen, Wei-Hsin & Lin, Ta-Chang, 2013. "Thermogravimetric analysis and kinetics of co-pyrolysis of raw/torrefied wood and coal blends," Applied Energy, Elsevier, vol. 105(C), pages 57-65.
    2. Jayaraman, Kandasamy & Kok, Mustafa Versan & Gokalp, Iskender, 2017. "Thermogravimetric and mass spectrometric (TG-MS) analysis and kinetics of coal-biomass blends," Renewable Energy, Elsevier, vol. 101(C), pages 293-300.
    3. Du, Shan-Wen & Chen, Wei-Hsin & Lucas, John A., 2010. "Pulverized coal burnout in blast furnace simulated by a drop tube furnace," Energy, Elsevier, vol. 35(2), pages 576-581.
    4. Muthuraman, Marisamy & Namioka, Tomoaki & Yoshikawa, Kunio, 2010. "Characteristics of co-combustion and kinetic study on hydrothermally treated municipal solid waste with different rank coals: A thermogravimetric analysis," Applied Energy, Elsevier, vol. 87(1), pages 141-148, January.
    5. Luo, S.Y. & Xiao, B. & Hu, Z.Q. & Liu, S.M. & Guan, Y.W., 2009. "Experimental study on oxygen-enriched combustion of biomass micro fuel," Energy, Elsevier, vol. 34(11), pages 1880-1884.
    6. Slopiecka, Katarzyna & Bartocci, Pietro & Fantozzi, Francesco, 2012. "Thermogravimetric analysis and kinetic study of poplar wood pyrolysis," Applied Energy, Elsevier, vol. 97(C), pages 491-497.
    7. Bonassa, Gabriela & Schneider, Lara Talita & Canever, Victor Bruno & Cremonez, Paulo André & Frigo, Elisandro Pires & Dieter, Jonathan & Teleken, Joel Gustavo, 2018. "Scenarios and prospects of solid biofuel use in Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2365-2378.
    8. Lu, Jau-Jang & Chen, Wei-Hsin, 2015. "Investigation on the ignition and burnout temperatures of bamboo and sugarcane bagasse by thermogravimetric analysis," Applied Energy, Elsevier, vol. 160(C), pages 49-57.
    9. Liu, Zhengang & Quek, Augustine & Balasubramanian, R., 2014. "Preparation and characterization of fuel pellets from woody biomass, agro-residues and their corresponding hydrochars," Applied Energy, Elsevier, vol. 113(C), pages 1315-1322.
    10. Chen, Wei-Hsin & Ye, Song-Ching & Sheen, Herng-Kuang, 2012. "Hydrolysis characteristics of sugarcane bagasse pretreated by dilute acid solution in a microwave irradiation environment," Applied Energy, Elsevier, vol. 93(C), pages 237-244.
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