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In-situ catalytic upgrading of bio-oils from rapid pyrolysis of torrefied giant miscanthus (Miscanthus x giganteus) over copper‑magnesium bimetal modified HZSM-5

Author

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  • Chaerusani, Virdi
  • Ramli, Yusrin
  • Zahra, Aghietyas Choirun Az
  • Zhang, Pan
  • Rizkiana, Jenny
  • Kongparakul, Suwadee
  • Samart, Chanatip
  • Karnjanakom, Surachai
  • Kang, Dong-Jin
  • Abudula, Abuliti
  • Guan, Guoqing

Abstract

In this study, fast pyrolysis of both raw and torrefied giant miscanthus (GM) is investigated in detail. It is found that the pyrolysis of torrefied GM results in higher distribution of phenols and aliphatic compounds in bio-oil with lower moisture content. To further improve the bio-oil quality, catalytic upgrading process of the bio-oil from the torrefied GM over copper‑magnesium (CuMg) bimetal doped zeolites is also investigated. As a result, a highest yield of aromatic hydrocarbons of 63.1% favoring in higher monoaromatic hydrocarbons such as benzene, toluene and xylene in the upgraded bio-oil is obtained as GM-300 is used as feedstock and HSZ-Cu 2:1 Mg as the catalyst. It is found that CuMg doping can not only enhance catalytic activity of zeolite but also maintain relatively low coke deposition and improve the catalyst reusability. Besides, the spent catalysts are easily regenerated only by a facile calcination way, and the regenerated catalyst shows almost the same activity as the initial one.

Suggested Citation

  • Chaerusani, Virdi & Ramli, Yusrin & Zahra, Aghietyas Choirun Az & Zhang, Pan & Rizkiana, Jenny & Kongparakul, Suwadee & Samart, Chanatip & Karnjanakom, Surachai & Kang, Dong-Jin & Abudula, Abuliti & G, 2024. "In-situ catalytic upgrading of bio-oils from rapid pyrolysis of torrefied giant miscanthus (Miscanthus x giganteus) over copper‑magnesium bimetal modified HZSM-5," Applied Energy, Elsevier, vol. 353(PA).
    • Handle: RePEc:eee:appene:v:353:y:2024:i:pa:s0306261923014745
    DOI: 10.1016/j.apenergy.2023.122110
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    1. Karasu, Seçkin & Altan, Aytaç & Bekiros, Stelios & Ahmad, Wasim, 2020. "A new forecasting model with wrapper-based feature selection approach using multi-objective optimization technique for chaotic crude oil time series," Energy, Elsevier, vol. 212(C).
    2. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    3. Kallis, Kyriakos X. & Pellegrini Susini, Giacomo A. & Oakey, John E., 2013. "A comparison between Miscanthus and bioethanol waste pellets and their performance in a downdraft gasifier," Applied Energy, Elsevier, vol. 101(C), pages 333-340.
    4. Lehto, Jani & Oasmaa, Anja & Solantausta, Yrjö & Kytö, Matti & Chiaramonti, David, 2014. "Review of fuel oil quality and combustion of fast pyrolysis bio-oils from lignocellulosic biomass," Applied Energy, Elsevier, vol. 116(C), pages 178-190.
    5. Zhang, Congyu & Yang, Wu & Chen, Wei-Hsin & Ho, Shih-Hsin & Pétrissans, Anelie & Pétrissans, Mathieu, 2022. "Effect of torrefaction on the structure and reactivity of rice straw as well as life cycle assessment of torrefaction process," Energy, Elsevier, vol. 240(C).
    6. Xu, Hao & Cheng, Shuo & Hungwe, Douglas & Yoshikawa, Kunio & Takahashi, Fumitake, 2022. "Co-pyrolysis coupled with torrefaction enhances hydrocarbons production from rice straw and oil sludge: The effect of torrefaction on co-pyrolysis synergistic behaviors," Applied Energy, Elsevier, vol. 327(C).
    7. Karasu, Seçkin & Altan, Aytaç, 2022. "Crude oil time series prediction model based on LSTM network with chaotic Henry gas solubility optimization," Energy, Elsevier, vol. 242(C).
    8. Yang, Fan & Zhong, Jie & Liu, Xiaohui & Zhu, Xuedong, 2018. "A novel catalytic alkylation process of syngas with benzene over the cerium modified platinum supported on HZSM-5 zeolite," Applied Energy, Elsevier, vol. 226(C), pages 22-30.
    9. Wilk, Małgorzata & Magdziarz, Aneta, 2017. "Hydrothermal carbonization, torrefaction and slow pyrolysis of Miscanthus giganteus," Energy, Elsevier, vol. 140(P1), pages 1292-1304.
    10. Zhang, Congyu & Ho, Shih-Hsin & Chen, Wei-Hsin & Fu, Yujie & Chang, Jo-Shu & Bi, Xiaotao, 2019. "Oxidative torrefaction of biomass nutshells: Evaluations of energy efficiency as well as biochar transportation and storage," Applied Energy, Elsevier, vol. 235(C), pages 428-441.
    11. Chaihad, Nichaboon & Situmorang, Yohanes Andre & Anniwaer, Aisikaer & Kurnia, Irwan & Karnjanakom, Surachai & Kasai, Yutaka & Abudula, Abuliti & Reubroycharoen, Prasert & Guan, Guoqing, 2021. "Preparation of various hierarchical HZSM-5 based catalysts for in-situ fast upgrading of bio-oil," Renewable Energy, Elsevier, vol. 169(C), pages 283-292.
    12. da Silva, Carlos Miguel Simões & Carneiro, Angélica de Cássia Oliveira & Vital, Benedito Rocha & Figueiró, Clarissa Gusmão & Fialho, Lucas de Freitas & de Magalhães, Mateus Alves & Carvalho, Amélia Gu, 2018. "Biomass torrefaction for energy purposes – Definitions and an overview of challenges and opportunities in Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2426-2432.
    13. Chen, Yun-Chun & Chen, Wei-Hsin & Lin, Bo-Jhih & Chang, Jo-Shu & Ong, Hwai Chyuan, 2016. "Impact of torrefaction on the composition, structure and reactivity of a microalga residue," Applied Energy, Elsevier, vol. 181(C), pages 110-119.
    14. Dai, Leilei & Wang, Yunpu & Liu, Yuhuan & Ruan, Roger & He, Chao & Yu, Zhenting & Jiang, Lin & Zeng, Zihong & Tian, Xiaojie, 2019. "Integrated process of lignocellulosic biomass torrefaction and pyrolysis for upgrading bio-oil production: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 20-36.
    15. Palizdar, A. & Sadrameli, S.M., 2020. "Catalytic upgrading of biomass pyrolysis oil over tailored hierarchical MFI zeolite: Effect of porosity enhancement and porosity-acidity interaction on deoxygenation reactions," Renewable Energy, Elsevier, vol. 148(C), pages 674-688.
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