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Comparison of different ammonia synthesis loop configurations with the aid of advanced exergy analysis

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  • Penkuhn, Mathias
  • Tsatsaronis, George

Abstract

An industrial ammonia synthesis loop is a complex interconnected system. With the synthesis reactor operated at high-pressure levels and with synthesis gas made of hydrogen and nitrogen, a highly efficient process design is necessary in order to meet the requirements in terms of cost-efficiency and environmental impact. The evaluation and optimization of different designs in the process synthesis phase are generally done by considering mass and energy balances. However, the conclusions drawn from such an analysis can be misleading and provide, if any, little useful information with respect to system improvement. In order to address these issues, an exergy analysis is used to identify the real thermodynamic inefficiencies of a system and its components. Furthermore, a subsequently conducted advanced exergy analysis provides the means to determine the structural interactions within a system and the thermodynamic improvement potential of its components. In this context, two different ammonia synthesis loop configurations are analyzed. The first concept consists of a three-staged adiabatic reactor with intermediate quench cooling, whereas the second design features a cooled reactor.

Suggested Citation

  • Penkuhn, Mathias & Tsatsaronis, George, 2017. "Comparison of different ammonia synthesis loop configurations with the aid of advanced exergy analysis," Energy, Elsevier, vol. 137(C), pages 854-864.
    • Handle: RePEc:eee:energy:v:137:y:2017:i:c:p:854-864
    DOI: 10.1016/j.energy.2017.02.175
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    References listed on IDEAS

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    1. Kirova-Yordanova, Zornitza, 2004. "Exergy analysis of industrial ammonia synthesis," Energy, Elsevier, vol. 29(12), pages 2373-2384.
    2. Penkuhn, Mathias & Tsatsaronis, George, 2017. "A decomposition method for the evaluation of component interactions in energy conversion systems for application to advanced exergy-based analyses," Energy, Elsevier, vol. 133(C), pages 388-403.
    3. Tsatsaronis, George, 2007. "Definitions and nomenclature in exergy analysis and exergoeconomics," Energy, Elsevier, vol. 32(4), pages 249-253.
    4. Lazzaretto, Andrea & Tsatsaronis, George, 2006. "SPECO: A systematic and general methodology for calculating efficiencies and costs in thermal systems," Energy, Elsevier, vol. 31(8), pages 1257-1289.
    5. Sorin, M.V. & Brodyansky, V.M., 1992. "A method for thermodynamic optimization—I. Theory and application to an ammonia-synthesis plant," Energy, Elsevier, vol. 17(11), pages 1019-1031.
    6. Rafiqul, Islam & Weber, Christoph & Lehmann, Bianca & Voss, Alfred, 2005. "Energy efficiency improvements in ammonia production—perspectives and uncertainties," Energy, Elsevier, vol. 30(13), pages 2487-2504.
    7. Kelly, S. & Tsatsaronis, G. & Morosuk, T., 2009. "Advanced exergetic analysis: Approaches for splitting the exergy destruction into endogenous and exogenous parts," Energy, Elsevier, vol. 34(3), pages 384-391.
    8. Morosuk, Tatiana & Tsatsaronis, George, 2008. "A new approach to the exergy analysis of absorption refrigeration machines," Energy, Elsevier, vol. 33(6), pages 890-907.
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    Cited by:

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