IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v197y2024ics1364032124001497.html
   My bibliography  Save this article

Sustainable production of ammonia and formic acid using three chemical looping reactors and CO2 electroreduction cell

Author

Listed:
  • Ansarinasab, Hojat
  • Fatimah, Manal
  • Khojasteh-Salkuyeh, Yaser

Abstract

Chemical looping reforming (CLR) is emerging as a promising technique with potential to produce useful chemicals while capturing carbon dioxide emissions. This study proposes a novel multigeneration system consisting of three-reactor CLR integrated with CO2 electroreduction cell to produce 13.3 kg/s commercial-grade of ammonia and 0.0113 kg formic acid/kg ammonia. In order to achieve the maximum use of waste heat and cold energy, the system also includes interconnected power generation cycles. The net power generation is 816.54 kJ/kg ammonia, along with 305 kg/s hot water at 80 °C. A technoeconomic analysis is conducted to economically assess the process and the results are compared with other studies. The results of technoeconomic analysis give a comparatively low levelized cost of ammonia equal to 0.48 $/kg. Furthermore, to understand the irreversibilities involved in the integrated process, a thermodynamic analysis is conducted in terms of conventional and advanced exergy analyses along with sensitivity analysis which help determine the practical limitations and opportunities for process improvement of the overall system. According to the results, the overall process exergy efficiency is 74.80% and the overall exergy destruction rate is 116338.53 kW. The results of advanced exergy analysis show strong interdependencies between the components of the system due to major endogenous exergy destruction rates. Additionally, the results are used to propose three distinct strategies for design optimization and process intensification. This work is the first to look at the potential of improving the sustainability index (SI) by using the results of an advanced exergy analysis.

Suggested Citation

  • Ansarinasab, Hojat & Fatimah, Manal & Khojasteh-Salkuyeh, Yaser, 2024. "Sustainable production of ammonia and formic acid using three chemical looping reactors and CO2 electroreduction cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 197(C).
    • Handle: RePEc:eee:rensus:v:197:y:2024:i:c:s1364032124001497
    DOI: 10.1016/j.rser.2024.114426
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032124001497
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2024.114426?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Bahnamiri, Fazele Karimian & Khalili, Masoud & Pakzad, Pouria & Mehrpooya, Mehdi, 2022. "Techno-economic assessment of a novel power-to-liquid system for synthesis of formic acid and ammonia, based on CO2 electroreduction and alkaline water electrolysis cells," Renewable Energy, Elsevier, vol. 187(C), pages 1224-1240.
    2. Milad Sadeghzadeh & Mehdi Mehrpooya & Hojat Ansarinasab, 2021. "A novel exergy-based assessment on a multi-production plant of power, heat and hydrogen: integration of solid oxide fuel cell, solid oxide electrolyzer cell and Rankine steam cycle," International Journal of Low-Carbon Technologies, Oxford University Press, vol. 16(3), pages 798-813.
    3. Penkuhn, Mathias & Tsatsaronis, George, 2017. "Comparison of different ammonia synthesis loop configurations with the aid of advanced exergy analysis," Energy, Elsevier, vol. 137(C), pages 854-864.
    4. Mesfun, Sennai & Sanchez, Daniel L. & Leduc, Sylvain & Wetterlund, Elisabeth & Lundgren, Joakim & Biberacher, Markus & Kraxner, Florian, 2017. "Power-to-gas and power-to-liquid for managing renewable electricity intermittency in the Alpine Region," Renewable Energy, Elsevier, vol. 107(C), pages 361-372.
    5. Rosen, Marc A. & Dincer, Ibrahim & Kanoglu, Mehmet, 2008. "Role of exergy in increasing efficiency and sustainability and reducing environmental impact," Energy Policy, Elsevier, vol. 36(1), pages 128-137, January.
    6. Chein, Rei-Yu & Lu, Cheng-Yang & Chen, Wei-Hsin, 2022. "Syngas production via chemical looping reforming using methane-based feed and NiO/Al2O3 oxygen carrier," Energy, Elsevier, vol. 250(C).
    7. Lu, Chunqiang & Li, Kongzhai & Wang, Hua & Zhu, Xing & Wei, Yonggang & Zheng, Min & Zeng, Chunhua, 2018. "Chemical looping reforming of methane using magnetite as oxygen carrier: Structure evolution and reduction kinetics," Applied Energy, Elsevier, vol. 211(C), pages 1-14.
    8. Lee Pereira, Reinaldo Juan & Argyris, Panagiotis Alexandros & Spallina, Vincenzo, 2020. "A comparative study on clean ammonia production using chemical looping based technology," Applied Energy, Elsevier, vol. 280(C).
    9. Khan, Mohammed N. & Shamim, Tariq, 2016. "Investigation of hydrogen generation in a three reactor chemical looping reforming process," Applied Energy, Elsevier, vol. 162(C), pages 1186-1194.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fang, Jing & Xiong, Chuhao & Feng, Mingqian & Wu, Ye & Liu, Dong, 2022. "Utilization of carbon-based energy as raw material instead of fuel with low CO2 emissions: Energy analyses and process integration of chemical looping ammonia generation," Applied Energy, Elsevier, vol. 312(C).
    2. Xiang, Dong & Zhou, Yunpeng, 2018. "Concept design and techno-economic performance of hydrogen and ammonia co-generation by coke-oven gas-pressure swing adsorption integrated with chemical looping hydrogen process," Applied Energy, Elsevier, vol. 229(C), pages 1024-1034.
    3. Alvin Kiprono Bett & Saeid Jalilinasrabady, 2021. "Optimization of ORC Power Plants for Geothermal Application in Kenya by Combining Exergy and Pinch Point Analysis," Energies, MDPI, vol. 14(20), pages 1-17, October.
    4. L. Hay & A. H. B. Duffy & R. I. Whitfield, 2017. "The S‐Cycle Performance Matrix: Supporting Comprehensive Sustainability Performance Evaluation of Technical Systems," Systems Engineering, John Wiley & Sons, vol. 20(1), pages 45-70, January.
    5. Ding, Haoran & Tong, Sirui & Qi, Zhifu & Liu, Fei & Sun, Shien & Han, Long, 2023. "Syngas production from chemical-looping steam methane reforming: The effect of channel geometry on BaCoO3/CeO2 monolithic oxygen carriers," Energy, Elsevier, vol. 263(PE).
    6. Ziya Sogut, M., 2021. "New approach for assessment of environmental effects based on entropy optimization of jet engine," Energy, Elsevier, vol. 234(C).
    7. van der Kroon, Bianca & Brouwer, Roy & van Beukering, Pieter J.H., 2013. "The energy ladder: Theoretical myth or empirical truth? Results from a meta-analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 20(C), pages 504-513.
    8. Cullen, Jonathan M. & Allwood, Julian M., 2010. "Theoretical efficiency limits for energy conversion devices," Energy, Elsevier, vol. 35(5), pages 2059-2069.
    9. Maia, Cristiana Brasil & Ferreira, André Guimarães & Cabezas-Gómez, Luben & de Oliveira Castro Silva, Janaína & de Morais Hanriot, Sérgio, 2017. "Thermodynamic analysis of the drying process of bananas in a small-scale solar updraft tower in Brazil," Renewable Energy, Elsevier, vol. 114(PB), pages 1005-1012.
    10. Gu, Zhenhua & Zhang, Ling & Lu, Chunqiang & Qing, Shan & Li, Kongzhai, 2020. "Enhanced performance of copper ore oxygen carrier by red mud modification for chemical looping combustion," Applied Energy, Elsevier, vol. 277(C).
    11. Mehrpooya, Mehdi & Ansarinasab, Hojat & Mousavi, Seyed Ali, 2021. "Life cycle assessment and exergoeconomic analysis of the multi-generation system based on fuel cell for methanol, power, and heat production," Renewable Energy, Elsevier, vol. 172(C), pages 1314-1332.
    12. Liu, Chenglin & Zhao, Lei & Zhu, Shun & Shen, Yuefeng & Yu, Jianhua & Yang, Qingchun, 2023. "Advanced exergy analysis and optimization of a coal to ethylene glycol (CtEG) process," Energy, Elsevier, vol. 282(C).
    13. Soltanian, Salman & Kalogirou, Soteris A. & Ranjbari, Meisam & Amiri, Hamid & Mahian, Omid & Khoshnevisan, Benyamin & Jafary, Tahereh & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Aghaei, Siavash & Pe, 2022. "Exergetic sustainability analysis of municipal solid waste treatment systems: A systematic critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    14. Baskut, Omer & Ozgener, Onder & Ozgener, Leyla, 2010. "Effects of meteorological variables on exergetic efficiency of wind turbine power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 3237-3241, December.
    15. Miladi, Rihab & Frikha, Nader & Gabsi, Slimane, 2017. "Exergy analysis of a solar-powered vacuum membrane distillation unit using two models," Energy, Elsevier, vol. 120(C), pages 872-883.
    16. Hepbasli, Arif & Alsuhaibani, Zeyad, 2011. "Exergetic and exergoeconomic aspects of wind energy systems in achieving sustainable development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(6), pages 2810-2825, August.
    17. Ndukwu, M.C. & Bennamoun, L. & Abam, F.I. & Eke, A.B. & Ukoha, D., 2017. "Energy and exergy analysis of a solar dryer integrated with sodium sulfate decahydrate and sodium chloride as thermal storage medium," Renewable Energy, Elsevier, vol. 113(C), pages 1182-1192.
    18. Grubbström, Robert W., 2015. "On the true value of resource consumption when using energy in industrial and other processes," International Journal of Production Economics, Elsevier, vol. 170(PB), pages 377-384.
    19. Ahbabi Saray, Jabraeil & Heyhat, Mohammad Mahdi, 2022. "Modeling of a direct absorption parabolic trough collector based on using nanofluid: 4E assessment and water-energy nexus analysis," Energy, Elsevier, vol. 244(PB).
    20. Jiang, Jianrong & Feng, Xiao, 2019. "Energy optimization of ammonia synthesis processes based on oxygen purity under different purification technologies," Energy, Elsevier, vol. 185(C), pages 819-828.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:197:y:2024:i:c:s1364032124001497. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.