IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v83y2015icp483-490.html
   My bibliography  Save this article

Performance analysis of Cu, Sn and Rh impregnated NiO/CGO91 anode for butane internal reforming SOFC at intermediate temperature

Author

Listed:
  • Park, Kwangjin
  • Lee, Sangho
  • Bae, Gyujong
  • Bae, Joongmyeon

Abstract

In this work, the performance of solid oxide fuel cells (SOFC) consisting of Cu, Sn and Rh impregnated NiO/CGO91 anode is investigated for butane internal reforming mode at an intermediate temperature (600 °C). Steam reforming activities of Ni and Ce0.9Gd0.1O2 (CGO91) and Ni and Y0.08Zr0.92O2 (8YSZ) are tested as anode materials of internal reforming SOFC. In butane steam reforming, NiO/CGO91 shows better performance than NiO/8YSZ. However, butane is incomplete converted over NiO/CGO91 even if the gas hourly space velocity is very low. Cu, Sn and Rh are added to the NiO/CGO91 materials to increase the conversion of butane. Among the additives, the Rh is the most effective, resulting in 100% of butane conversion and no carbon deposition. Moreover, Rh added NiO/CGO91 SOFC single cell have a very low degradation rate when the SOFC sing cell is operated in internal reforming mode using butane.

Suggested Citation

  • Park, Kwangjin & Lee, Sangho & Bae, Gyujong & Bae, Joongmyeon, 2015. "Performance analysis of Cu, Sn and Rh impregnated NiO/CGO91 anode for butane internal reforming SOFC at intermediate temperature," Renewable Energy, Elsevier, vol. 83(C), pages 483-490.
    • Handle: RePEc:eee:renene:v:83:y:2015:i:c:p:483-490
    DOI: 10.1016/j.renene.2015.04.070
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148115003596
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2015.04.070?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Seungdoo Park & John M. Vohs & Raymond J. Gorte, 2000. "Direct oxidation of hydrocarbons in a solid-oxide fuel cell," Nature, Nature, vol. 404(6775), pages 265-267, March.
    2. E. Perry Murray & T. Tsai & S. A. Barnett, 1999. "A direct-methane fuel cell with a ceria-based anode," Nature, Nature, vol. 400(6745), pages 649-651, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yu, Fangyong & Xiao, Jie & Zhang, Yapeng & Cai, Weizi & Xie, Yongmin & Yang, Naitao & Liu, Jiang & Liu, Meilin, 2019. "New insights into carbon deposition mechanism of nickel/yttrium-stabilized zirconia cermet from methane by in situ investigation," Applied Energy, Elsevier, vol. 256(C).
    2. Mohamad Fairus Rabuni & Tao Li & Mohd Hafiz Dzarfan Othman & Faidzul Hakim Adnan & Kang Li, 2023. "Progress in Solid Oxide Fuel Cells with Hydrocarbon Fuels," Energies, MDPI, vol. 16(17), pages 1-36, September.
    3. Hu, Boxun & Keane, Michael & Patil, Kailash & Mahapatra, Manoj K. & Pasaogullari, Ugur & Singh, Prabhakar, 2014. "Direct methanol utilization in intermediate temperature liquid-tin anode solid oxide fuel cells," Applied Energy, Elsevier, vol. 134(C), pages 342-348.
    4. Cai, Weizi & Zhou, Qian & Xie, Yongmin & Liu, Jiang & Long, Guohui & Cheng, Shuang & Liu, Meilin, 2016. "A direct carbon solid oxide fuel cell operated on a plant derived biofuel with natural catalyst," Applied Energy, Elsevier, vol. 179(C), pages 1232-1241.
    5. Thieu, Cam-Anh & Ji, Ho-Il & Kim, Hyoungchul & Yoon, Kyung Joong & Lee, Jong-Ho & Son, Ji-Won, 2019. "Palladium incorporation at the anode of thin-film solid oxide fuel cells and its effect on direct utilization of butane fuel at 600 °C," Applied Energy, Elsevier, vol. 243(C), pages 155-164.
    6. Saadabadi, S. Ali & Thallam Thattai, Aditya & Fan, Liyuan & Lindeboom, Ralph E.F. & Spanjers, Henri & Aravind, P.V., 2019. "Solid Oxide Fuel Cells fuelled with biogas: Potential and constraints," Renewable Energy, Elsevier, vol. 134(C), pages 194-214.
    7. Milanese, Marco & Colangelo, Gianpiero & Laforgia, Domenico & de Risi, Arturo, 2017. "Multi-parameter optimization of double-loop fluidized bed solar reactor for thermochemical fuel production," Energy, Elsevier, vol. 134(C), pages 919-932.
    8. Massimiliano Cimenti & Josephine M. Hill, 2009. "Direct Utilization of Liquid Fuels in SOFC for Portable Applications: Challenges for the Selection of Alternative Anodes," Energies, MDPI, vol. 2(2), pages 1-34, June.
    9. Fan, Liyuan & Li, Chao'en & van Biert, Lindert & Zhou, Shou-Han & Tabish, Asif Nadeem & Mokhov, Anatoli & Aravind, Purushothaman Vellayani & Cai, Weiwei, 2022. "Advances on methane reforming in solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    10. Sariboğa, Vedat & Öksüzömer, Faruk, 2012. "The investigation of active Ni/YSZ interlayer for Cu-based direct-methane solid oxide fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 707-721.
    11. Xu, Han & Dang, Zheng, 2016. "Lattice Boltzmann modeling of carbon deposition in porous anode of a solid oxide fuel cell with internal reforming," Applied Energy, Elsevier, vol. 178(C), pages 294-307.
    12. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
    13. Yue Teng & Ho Yeon Lee & Haesu Lee & Yoon Ho Lee, 2022. "Effect of Sputtering Pressure on the Nanostructure and Residual Stress of Thin-Film YSZ Electrolyte," Sustainability, MDPI, vol. 14(15), pages 1-9, August.
    14. Shri Prakash, B. & Senthil Kumar, S. & Aruna, S.T., 2014. "Properties and development of Ni/YSZ as an anode material in solid oxide fuel cell: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 149-179.
    15. Berre Kumuk & Nisa Nur Atak & Battal Dogan & Salih Ozer & Pinar Demircioglu & Ismail Bogrekci, 2024. "Numerical and Thermodynamic Analysis of the Effect of Operating Temperature in Methane-Fueled SOFC," Energies, MDPI, vol. 17(11), pages 1-17, May.
    16. Jiao, Yong & Zhang, Liqin & An, Wenting & Zhou, Wei & Sha, Yujing & Shao, Zongping & Bai, Jianping & Li, Si-Dian, 2016. "Controlled deposition and utilization of carbon on Ni-YSZ anodes of SOFCs operating on dry methane," Energy, Elsevier, vol. 113(C), pages 432-443.
    17. Chen, Xiaohang & Wang, Yuan & Zhao, Yingru & Zhou, Yinghui, 2016. "A study of double functions and load matching of a phosphoric acid fuel cell/heat-driven refrigerator hybrid system," Energy, Elsevier, vol. 101(C), pages 359-365.
    18. Kupecki, Jakub & Papurello, Davide & Lanzini, Andrea & Naumovich, Yevgeniy & Motylinski, Konrad & Blesznowski, Marcin & Santarelli, Massimo, 2018. "Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)," Applied Energy, Elsevier, vol. 230(C), pages 1573-1584.
    19. Xu, Qidong & Xia, Lingchao & He, Qijiao & Guo, Zengjia & Ni, Meng, 2021. "Thermo-electrochemical modelling of high temperature methanol-fuelled solid oxide fuel cells," Applied Energy, Elsevier, vol. 291(C).
    20. Eom, Seongyong & Ahn, Seongyool & Rhie, Younghoon & Kang, Kijoong & Sung, Yonmo & Moon, Cheoreon & Choi, Gyungmin & Kim, Duckjool, 2014. "Influence of devolatilized gases composition from raw coal fuel in the lab scale DCFC (direct carbon fuel cell) system," Energy, Elsevier, vol. 74(C), pages 734-740.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:83:y:2015:i:c:p:483-490. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.