IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v253y2019ic26.html
   My bibliography  Save this article

Investigation of the kinetics of mixed methane hydrate formation kinetics in saline and seawater

Author

Listed:
  • Veluswamy, Hari Prakash
  • Kumar, Asheesh
  • Kumar, Rajnish
  • Linga, Praveen

Abstract

Solidified Natural Gas (SNG) technology for storing methane/natural gas in clathrate hydrates is gaining prominence due to its promising advantages of being extremely safe, relatively greener, more economical and offering a compact mode of long-term reliable storage in comparison to prevalent technologies. Recently, we demonstrated a faster method to store methane in seawater and saline water via mixed sII hydrates in an unstirred reactor configuration. In this study, we investigate in detail the macroscopic kinetics of mixed hydrate formation in presence of saline (3 wt% or 1.1 mol% NaCl) water, artificial and natural seawater. The effect of driving force on the kinetics of mixed hydrate formation was studied by performing hydrate formation experiments at three different pressures of 3.0, 5.0 and 7.2 MPa at 283.2 K. Characteristic difference in the formation kinetics was observed at lower driving force (3.0 MPa and 5.0 MPa) experiments of saline water in comparison to the experiment without salt. Further, effect of amino acids (leucine and arginine) on mixed hydrate formation starting from saline water at moderate pressure of 5.0 MPa have been studied. 200 ppm leucine was found to be enhancing the mixed methane hydrate formation kinetics in saline water under studied experimental conditions. These findings highlight the promise of employing seawater for SNG technology to store methane (natural gas) on a large scale suited for long-term storage.

Suggested Citation

  • Veluswamy, Hari Prakash & Kumar, Asheesh & Kumar, Rajnish & Linga, Praveen, 2019. "Investigation of the kinetics of mixed methane hydrate formation kinetics in saline and seawater," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:253:y:2019:i:c:26
    DOI: 10.1016/j.apenergy.2019.113515
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919311894
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2019.113515?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhong, Dong-Liang & Li, Zheng & Lu, Yi-Yu & Wang, Jia-Le & Yan, Jin, 2015. "Evaluation of CO2 removal from a CO2+CH4 gas mixture using gas hydrate formation in liquid water and THF solutions," Applied Energy, Elsevier, vol. 158(C), pages 133-141.
    2. Chong, Zheng Rong & Koh, Jun Wee & Linga, Praveen, 2017. "Effect of KCl and MgCl2 on the kinetics of methane hydrate formation and dissociation in sandy sediments," Energy, Elsevier, vol. 137(C), pages 518-529.
    3. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    4. Veluswamy, Hari Prakash & Kumar, Asheesh & Kumar, Rajnish & Linga, Praveen, 2017. "An innovative approach to enhance methane hydrate formation kinetics with leucine for energy storage application," Applied Energy, Elsevier, vol. 188(C), pages 190-199.
    5. Gregor Rehder & Robert Eckl & Markus Elfgen & Andrzej Falenty & Rainer Hamann & Nina Kähler & Werner F. Kuhs & Hans Osterkamp & Christoph Windmeier, 2012. "Methane Hydrate Pellet Transport Using the Self-Preservation Effect: A Techno-Economic Analysis," Energies, MDPI, vol. 5(7), pages 1-25, July.
    6. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    7. Kumar, Asheesh & Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2019. "Direct use of seawater for rapid methane storage via clathrate (sII) hydrates," Applied Energy, Elsevier, vol. 235(C), pages 21-30.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Qin, Yue & Shang, Liyan & Lv, Zhenbo & Liu, Zhiming & He, Jianyu & Li, Xu & Binama, Maxime & Yang, Lingyun & Wang, Deyang, 2022. "Rapid formation of methane hydrate in environment-friendly leucine-based complex systems," Energy, Elsevier, vol. 254(PA).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bhattacharjee, Gaurav & Prakash Veluswamy, Hari & Kumar, Rajnish & Linga, Praveen, 2020. "Rapid methane storage via sII hydrates at ambient temperature," Applied Energy, Elsevier, vol. 269(C).
    2. Xiao, Peng & Dong, Bao-Can & Li, Jia & Zhang, Hong-Liang & Chen, Guang-Jin & Sun, Chang-Yu & Huang, Xing, 2022. "An approach to highly efficient filtration of methane hydrate slurry for the continuous hydrate production," Energy, Elsevier, vol. 259(C).
    3. Zheng, Junjie & Loganathan, Niranjan Kumar & Zhao, Jianzhong & Linga, Praveen, 2019. "Clathrate hydrate formation of CO2/CH4 mixture at room temperature: Application to direct transport of CO2-containing natural gas," Applied Energy, Elsevier, vol. 249(C), pages 190-203.
    4. Bhattacharjee, Gaurav & Veluswamy, Hari Prakash & Kumar, Rajnish & Linga, Praveen, 2020. "Seawater based mixed methane-THF hydrate formation at ambient temperature conditions," Applied Energy, Elsevier, vol. 271(C).
    5. Olga Gaidukova & Sergei Misyura & Pavel Strizhak, 2022. "Key Areas of Gas Hydrates Study: Review," Energies, MDPI, vol. 15(5), pages 1-18, February.
    6. Ge, Bin-Bin & Li, Xi-Yue & Zhong, Dong-Liang & Lu, Yi-Yu, 2022. "Investigation of natural gas storage and transportation by gas hydrate formation in the presence of bio-surfactant sulfonated lignin," Energy, Elsevier, vol. 244(PA).
    7. Mu, Liang & Tan, Qiqi & Li, Xianlong & Zhang, Qingyun & Cui, Qingyan, 2023. "A novel method to store methane by forming hydrate in the high water-oil ratio emulsions," Energy, Elsevier, vol. 264(C).
    8. Xu, Jiuping & Tang, Min & Liu, Tingting & Fan, Lurong, 2024. "Technological paradigm-based development strategy towards natural gas hydrate technology," Energy, Elsevier, vol. 289(C).
    9. Qureshi, M Fahed & Khandelwal, Himanshu & Usadi, Adam & Barckholtz, Timothy A. & Mhadeshwar, Ashish B. & Linga, Praveen, 2022. "CO2 hydrate stability in oceanic sediments under brine conditions," Energy, Elsevier, vol. 256(C).
    10. Zhang, Ye & Bhattacharjee, Gaurav & Dharshini Vijayakumar, Mohana & Linga, Praveen, 2022. "Rapid and energy-dense methane hydrate formation at near ambient temperature using 1,3-dioxolane as a dual-function promoter," Applied Energy, Elsevier, vol. 311(C).
    11. Sandro Hiller & Christian Hartmann & Babette Hebenstreit & Stefan Arzbacher, 2022. "Solidified-Air Energy Storage: Conceptualization and Thermodynamic Analysis," Energies, MDPI, vol. 15(6), pages 1-14, March.
    12. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    13. Qin, Yue & Shang, Liyan & Lv, Zhenbo & Liu, Zhiming & He, Jianyu & Li, Xu & Binama, Maxime & Yang, Lingyun & Wang, Deyang, 2022. "Rapid formation of methane hydrate in environment-friendly leucine-based complex systems," Energy, Elsevier, vol. 254(PA).
    14. Sa, Jeong-Hoon & Sum, Amadeu K., 2019. "Promoting gas hydrate formation with ice-nucleating additives for hydrate-based applications," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    15. Chen, Chen & Yuan, Haoyu & Bi, Rongshan & Wang, Na & Li, Yujiao & He, Yan & Wang, Fei, 2022. "A novel conceptual design of LNG-sourced natural gas peak-shaving with gas hydrates as the medium," Energy, Elsevier, vol. 253(C).
    16. Lee, Joonseop & Lee, Dongyoung & Seo, Yongwon, 2021. "Experimental investigation of the exact role of large-molecule guest substances (LMGSs) in determining phase equilibria and structures of natural gas hydrates," Energy, Elsevier, vol. 215(PB).
    17. Shi, Lingli & He, Yong & Lu, Jingsheng & Liang, Deqing, 2020. "Effect of dodecyl dimethyl benzyl ammonium chloride on CH4 hydrate growth and agglomeration in oil-water systems," Energy, Elsevier, vol. 212(C).
    18. Fang, Bin & Lü, Tao & Li, Wei & Moultos, Othonas A. & Vlugt, Thijs J.H. & Ning, Fulong, 2024. "Microscopic insights into poly- and mono-crystalline methane hydrate dissociation in Na-montmorillonite pores at static and dynamic fluid conditions," Energy, Elsevier, vol. 288(C).
    19. Zeng, Siyu & Yin, Zhenyuan & Ren, Junjie & Bhawangirkar, Dnyaneshwar R. & Huang, Li & Linga, Praveen, 2024. "Effect of MgCl2 on CO2 sequestration as hydrates in marine environment: A thermodynamic and kinetic investigation with morphology insights," Energy, Elsevier, vol. 286(C).
    20. Liu, Fa-Ping & Li, Ai-Rong & Wang, Jie & Luo, Ze-Dong, 2021. "Iron-based ionic liquid ([BMIM][FeCl4]) as a promoter of CO2 hydrate nucleation and growth," Energy, Elsevier, vol. 214(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:253:y:2019:i:c:26. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.