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Methane Hydrate Pellet Transport Using the Self-Preservation Effect: A Techno-Economic Analysis

Author

Listed:
  • Gregor Rehder

    (Leibniz-Institut für Ostseeforschung Warnemünde (IOW), Sektion Meereschemie/Seestrasse 15, Rostock 18119, Germany)

  • Robert Eckl

    (Linde AG, Engineering Division, Research & Development–Process Development (RDPD)/ Dr.-Carl-von-Linde-Str. 6-14, Pullach 82049, Germany)

  • Markus Elfgen

    (MEYER WERFT GmbH, Industriegebiet Süd, Papenburg 26871, Germany)

  • Andrzej Falenty

    (Leibniz-Institut für Ostseeforschung Warnemünde (IOW), Sektion Meereschemie/Seestrasse 15, Rostock 18119, Germany
    Geowissenschaftliches Zentrum der Universität Göttingen (GZG), Abteilung Kristallographie, Goldschmidtstraße 1, Göttingen 37077, Germany)

  • Rainer Hamann

    (Germanischer Lloyd SE, Department of Strategic Research/Brooktorkai 18, Hamburg 20457, Germany)

  • Nina Kähler

    (Germanischer Lloyd SE, Department of Strategic Research/Brooktorkai 18, Hamburg 20457, Germany)

  • Werner F. Kuhs

    (Geowissenschaftliches Zentrum der Universität Göttingen (GZG), Abteilung Kristallographie, Goldschmidtstraße 1, Göttingen 37077, Germany)

  • Hans Osterkamp

    (MEYER WERFT GmbH, Industriegebiet Süd, Papenburg 26871, Germany)

  • Christoph Windmeier

    (Linde AG, Engineering Division, Research & Development–Process Development (RDPD)/ Dr.-Carl-von-Linde-Str. 6-14, Pullach 82049, Germany)

Abstract

Within the German integrated project SUGAR, aiming for the development of new technologies for the exploration and exploitation of submarine gas hydrates, the option of gas transport by gas hydrate pellets has been comprehensively re-investigated. A series of pVT dissociation experiments, combined with analytical tools such as x-ray diffraction and cryo-SEM, were used to gather an additional level of understanding on effects controlling ice formation. Based on these new findings and the accessible literature, knowns and unknowns of the self-preservation effect important for the technology are summarized. A conceptual process design for methane hydrate production and pelletisation has been developed. For the major steps identified, comprising (i) hydrate formation; (ii) dewatering; (iii) pelletisation; (iv) pellet cooling; and (v) pressure relief, available technologies have been evaluated, and modifications and amendments included where needed. A hydrate carrier has been designed, featuring amongst other technical solutions a pivoted cargo system with the potential to mitigate sintering, an actively cooled containment and cargo distribution system, and a dual fuel engine allowing the use of the boil-off gas. The design was constrained by the properties of gas hydrate pellets, the expected operation on continental slopes in areas with rough seas, a scenario-defined loading capacity of 20,000 m 3 methane hydrate pellets, and safety as well as environmental considerations. A risk analysis for the transport at sea has been carried out in this early stage of development, and the safety level of the new concept was compared to the safety level of other ship types with similar scopes, i.e. , LNG carriers and crude oil tankers. Based on the results of the technological part of this study, and with best knowledge available on the alternative technologies, i.e. , pipeline, LNG and CNG transportation, an evaluation of the economic competitiveness of the methane hydrate transport technology has been performed. The analysis considers capital investment as well as operational costs and comprises a wide set of scenarios with production rates from 20 to 800 10 3 Nm 3 ·h −1 and transport distances from 200 to 10,000 km. In contrast to previous studies, the model calculations in this study reveal no economic benefit of methane hydrate transportation versus competing technologies.

Suggested Citation

  • Gregor Rehder & Robert Eckl & Markus Elfgen & Andrzej Falenty & Rainer Hamann & Nina Kähler & Werner F. Kuhs & Hans Osterkamp & Christoph Windmeier, 2012. "Methane Hydrate Pellet Transport Using the Self-Preservation Effect: A Techno-Economic Analysis," Energies, MDPI, vol. 5(7), pages 1-25, July.
  • Handle: RePEc:gam:jeners:v:5:y:2012:i:7:p:2499-2523:d:18896
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    Citations

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    Cited by:

    1. Zheng, Junjie & Loganathan, Niranjan Kumar & Zhao, Jianzhong & Linga, Praveen, 2019. "Clathrate hydrate formation of CO2/CH4 mixture at room temperature: Application to direct transport of CO2-containing natural gas," Applied Energy, Elsevier, vol. 249(C), pages 190-203.
    2. Olga Gaidukova & Sergey Misyura & Vladimir Morozov & Pavel Strizhak, 2023. "Gas Hydrates: Applications and Advantages," Energies, MDPI, vol. 16(6), pages 1-19, March.
    3. Kipyoung Kim & Hokeun Kang & Youtaek Kim, 2015. "Risk Assessment for Natural Gas Hydrate Carriers: A Hazard Identification (HAZID) Study," Energies, MDPI, vol. 8(4), pages 1-23, April.
    4. Dong, Hongsheng & Wang, Jiaqi & Xie, Zhuoxue & Wang, Bin & Zhang, Lunxiang & Shi, Quan, 2021. "Potential applications based on the formation and dissociation of gas hydrates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    5. Misyura, S.Y., 2019. "Non-stationary combustion of natural and artificial methane hydrate at heterogeneous dissociation," Energy, Elsevier, vol. 181(C), pages 589-602.
    6. Misyura, S.Y., 2020. "Dissociation of various gas hydrates (methane hydrate, double gas hydrates of methane-propane and methane-isopropanol) during combustion: Assessing the combustion efficiency," Energy, Elsevier, vol. 206(C).
    7. Veluswamy, Hari Prakash & Kumar, Asheesh & Kumar, Rajnish & Linga, Praveen, 2019. "Investigation of the kinetics of mixed methane hydrate formation kinetics in saline and seawater," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    8. Chen, Chen & Yuan, Haoyu & Bi, Rongshan & Wang, Na & Li, Yujiao & He, Yan & Wang, Fei, 2022. "A novel conceptual design of LNG-sourced natural gas peak-shaving with gas hydrates as the medium," Energy, Elsevier, vol. 253(C).
    9. Misyura S. Y. & Voytkov I. S. & Morozov V. S. & Manakov A. Y. & Yashutina O. S. & Ildyakov A. V., 2018. "An Experimental Study of Combustion of a Methane Hydrate Layer Using Thermal Imaging and Particle Tracking Velocimetry Methods," Energies, MDPI, vol. 11(12), pages 1-19, December.
    10. Takeya, Satoshi & Mimachi, Hiroko & Murayama, Tetsuro, 2018. "Methane storage in water frameworks: Self-preservation of methane hydrate pellets formed from NaCl solutions," Applied Energy, Elsevier, vol. 230(C), pages 86-93.
    11. Lee, Yohan & Kim, Yunju & Lee, Jaehyoung & Lee, Huen & Seo, Yongwon, 2015. "CH4 recovery and CO2 sequestration using flue gas in natural gas hydrates as revealed by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 150(C), pages 120-127.
    12. Cui, Gan & Wang, Shun & Dong, Zengrui & Xing, Xiao & Shan, Tianxiang & Li, Zili, 2020. "Effects of the diameter and the initial center temperature on the combustion characteristics of methane hydrate spheres," Applied Energy, Elsevier, vol. 257(C).
    13. Misyura, S.Y., 2020. "Comparing the dissociation kinetics of various gas hydrates during combustion: Assessment of key factors to improve combustion efficiency," Applied Energy, Elsevier, vol. 270(C).
    14. Michael T. Kezirian & S. Leigh Phoenix, 2017. "Natural Gas Hydrate as a Storage Mechanism for Safe, Sustainable and Economical Production from Offshore Petroleum Reserves," Energies, MDPI, vol. 10(6), pages 1-8, June.
    15. Omran, Ahmed & Nesterenko, Nikolay & Valtchev, Valentin, 2022. "Zeolitic ice: A route toward net zero emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    16. Sandro Hiller & Christian Hartmann & Babette Hebenstreit & Stefan Arzbacher, 2022. "Solidified-Air Energy Storage: Conceptualization and Thermodynamic Analysis," Energies, MDPI, vol. 15(6), pages 1-14, March.
    17. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.

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