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Effect of KCl and MgCl2 on the kinetics of methane hydrate formation and dissociation in sandy sediments

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  • Chong, Zheng Rong
  • Koh, Jun Wee
  • Linga, Praveen

Abstract

Natural gas hydrate is one of the potential energy resources in the future. However, the extraction of energy from hydrates remains uncertain due to limited understanding on how hydrates are formed and dissociated under different perturbations. More than 90% of NGH resource exists within marine location where salts are present. In this study, we investigated the formation and dissociation behavior of methane hydrate in the presence of magnesium chloride (MgCl2) and potassium chloride (KCl), two salts found in seawater, at 1.5 wt% and 3.0 wt%; and compared it with the cases of water and NaCl from our previous work. We found that on top of thermodynamic inhibition, both MgCl2 and KCl act as kinetic inhibitors on hydrate formation, retarding the rate of formation – with KCl exhibiting a weaker inhibition compared to MgCl2. For hydrate dissociation via thermal stimulation, we demonstrated that hydrate dissociates more rapidly in the presence of salts as compared to water despite a comparable temperature driving force (ΔT = 5.3 K) applied. Our results indicated that the weaker thermodynamic inhibitor, KCl, has a milder kinetic inhibition effect on hydrate formation and a weaker promoting effect on hydrate dissociation as compared to MgCl2 and NaCl.

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  • Chong, Zheng Rong & Koh, Jun Wee & Linga, Praveen, 2017. "Effect of KCl and MgCl2 on the kinetics of methane hydrate formation and dissociation in sandy sediments," Energy, Elsevier, vol. 137(C), pages 518-529.
    • Handle: RePEc:eee:energy:v:137:y:2017:i:c:p:518-529
    DOI: 10.1016/j.energy.2017.01.154
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    1. Prasad B. Kerkar & Kristine Horvat & Devinder Mahajan & Keith W. Jones, 2013. "Formation and Dissociation of Methane Hydrates from Seawater in Consolidated Sand: Mimicking Methane Hydrate Dynamics beneath the Seafloor," Energies, MDPI, vol. 6(12), pages 1-17, November.
    2. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    3. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    4. Yang, She Hern Bryan & Babu, Ponnivalavan & Chua, Sam Fu Sheng & Linga, Praveen, 2016. "Carbon dioxide hydrate kinetics in porous media with and without salts," Applied Energy, Elsevier, vol. 162(C), pages 1131-1140.
    5. Chong, Zheng Rong & Pujar, Girish Anand & Yang, Mingjun & Linga, Praveen, 2016. "Methane hydrate formation in excess water simulating marine locations and the impact of thermal stimulation on energy recovery," Applied Energy, Elsevier, vol. 177(C), pages 409-421.
    6. Li, Xiao-Sen & Xu, Chun-Gang & Zhang, Yu & Ruan, Xu-Ke & Li, Gang & Wang, Yi, 2016. "Investigation into gas production from natural gas hydrate: A review," Applied Energy, Elsevier, vol. 172(C), pages 286-322.
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