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Enhancing low-temperature desorption performance toward energy-saving CO2 capture via the multifunctional design of diethylethanolamine-based biphasic solvents

Author

Listed:
  • Zhao, Huajun
  • Liu, Jingyi
  • Cheng, Shuaiqing
  • Wang, Rujie
  • Li, Qiangwei
  • An, Shanlong
  • Zhang, Shihan
  • Wang, Lidong

Abstract

Biphasic solvents with primary/secondary amines as the primary absorbent involve a high heat of reaction and low desorption efficiency, limiting their development. A tertiary amine-based biphasic solvent composed of diethylethanolamine (DEEA), 2-Amino-2-methyl-1-propanol (AMP), ethyl acetoacetate (EAA), and H2O (referred to as DEEA/AMP/EAA/H2O) was proposed, which exhibited superior low-temperature desorption performance and ultra-low regeneration energy. EAA was revealed to facilitate the low-temperature desorption by reducing the activation energy from 6.8 to 2.3 kcal/mol. When regenerated only by heating to 353.15 K, the CO2-rich phase showed a significant desorption efficiency of 88.2 %; the desorption capacity and desorption rate were even 2.23 times and 6.84 times higher than 30 wt% MEA at 393.15 K. Moreover, the desorption heat dominated by the deprotonation of tertiary amine was as low as 0.92 GJ/t CO2; and low-temperature regeneration brought extremely low latent heat below 0.062 GJ/t CO2. Thus, the total regeneration energy was as low as 1.16 GJ/t CO2. In addition, EAA could trigger the phase separation and increase the absorption rate constant from 3.87 E−4 to 1.36 E−3 s−1, even higher than 30 wt% MEA. The addition of AMP further increased the CO2 loading (4.34 mol/L) and CO2 distribution (97.43 %) of the CO2-rich phase.

Suggested Citation

  • Zhao, Huajun & Liu, Jingyi & Cheng, Shuaiqing & Wang, Rujie & Li, Qiangwei & An, Shanlong & Zhang, Shihan & Wang, Lidong, 2024. "Enhancing low-temperature desorption performance toward energy-saving CO2 capture via the multifunctional design of diethylethanolamine-based biphasic solvents," Energy, Elsevier, vol. 307(C).
  • Handle: RePEc:eee:energy:v:307:y:2024:i:c:s0360544224023879
    DOI: 10.1016/j.energy.2024.132613
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    1. Wang, Lidong & Fang, Jie & Ma, Haojun & Wang, Chuhuan & Wang, Rujie & Li, Qiangwei & Zhang, Shihan, 2023. "Super-low energy consuming CO2 capture triggered by weak hydrogen bonds in solid-liquid phase separation," Energy, Elsevier, vol. 272(C).
    2. El Hadri, Nabil & Quang, Dang Viet & Goetheer, Earl L.V. & Abu Zahra, Mohammad R.M., 2017. "Aqueous amine solution characterization for post-combustion CO2 capture process," Applied Energy, Elsevier, vol. 185(P2), pages 1433-1449.
    3. Shen, Yao & Chen, Han & Wang, Junliang & Zhang, Shihan & Jiang, Chenkai & Ye, Jiexu & Wang, Lidong & Chen, Jianmeng, 2020. "Two-stage interaction performance of CO2 absorption into biphasic solvents: Mechanism analysis, quantum calculation and energy consumption," Applied Energy, Elsevier, vol. 260(C).
    4. Zhou, Xiaobin & Liu, Chao & Fan, Yinming & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Yinian & Zhu, Zongqiang, 2022. "Energy-efficient carbon dioxide capture using a novel low-viscous secondary amine-based nonaqueous biphasic solvent: Performance, mechanism, and thermodynamics," Energy, Elsevier, vol. 255(C).
    5. Wang, Rujie & Zhao, Huajun & Qi, Cairao & Yang, Xiaotong & Zhang, Shihan & Li, Ming & Wang, Lidong, 2022. "Novel tertiary amine-based biphasic solvent for energy-efficient CO2 capture with low corrosivity," Energy, Elsevier, vol. 260(C).
    6. Zhou, Xiaobin & Jing, Guohua & Lv, Bihong & Liu, Fan & Zhou, Zuoming, 2019. "Low-viscosity and efficient regeneration of carbon dioxide capture using a biphasic solvent regulated by 2-amino-2-methyl-1-propanol," Applied Energy, Elsevier, vol. 235(C), pages 379-390.
    7. Liu, Fei & Fang, Mengxiang & Dong, Wenfeng & Wang, Tao & Xia, Zhixiang & Wang, Qinhui & Luo, Zhongyang, 2019. "Carbon dioxide absorption in aqueous alkanolamine blends for biphasic solvents screening and evaluation," Applied Energy, Elsevier, vol. 233, pages 468-477.
    8. Shen, Yao & Jiang, Chenkai & Zhang, Shihan & Chen, Jun & Wang, Lidong & Chen, Jianmeng, 2018. "Biphasic solvent for CO2 capture: Amine property-performance and heat duty relationship," Applied Energy, Elsevier, vol. 230(C), pages 726-733.
    9. Wang, Rujie & Zhao, Huajun & Yang, Xiaotong & Qi, Cairao & Zhao, Haonan & Zhang, Shihan & Li, Qiangwei & Li, Ping & Wang, Lidong, 2023. "Energy-efficient non-aqueous biphasic solvent for carbon capture: Absorption mechanism, phase evolution process, and non-corrosiveness," Energy, Elsevier, vol. 281(C).
    10. Wang, Rujie & Liu, Shanshan & Wang, Lidong & Li, Qiangwei & Zhang, Shihan & Chen, Bo & Jiang, Lei & Zhang, Yifeng, 2019. "Superior energy-saving splitter in monoethanolamine-based biphasic solvents for CO2 capture from coal-fired flue gas," Applied Energy, Elsevier, vol. 242(C), pages 302-310.
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