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Reversible carbon dioxide capture by aqueous and non-aqueous amine-based absorbents: A comparative analysis carried out by 13C NMR spectroscopy

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  • Barzagli, Francesco
  • Giorgi, Claudia
  • Mani, Fabrizio
  • Peruzzini, Maurizio

Abstract

The efficiency of CO2 uptake by the amines 2-(2-aminoethoxy)ethanol (DGA), 2-amino-2-methyl-1,3-propanediol (AMPD), 2-amino-2-methyl-1-propanol (AMP), 2,2′-iminodiethanol (DEA) and 2-(butylamino)ethanol (BUMEA) has been investigated either in aqueous and in 2-(2-methoxyethoxy)ethanol (DEGMME) solutions and compared with 30% aqueous 2-aminoethanol (MEA). Batch experiments were carried out to measure the CO2 loading capacity of the different amine solutions and the rate of CO2 absorption. The 13C analysis has been applied to identify and quantify the carbonated species in solution upon CO2 uptake. The efficiency of CO2 (15% in air) capture was measured in continuous cycles of absorption (40 °C) and desorption (110 °C) carried out in packed columns at room pressure. The efficiency of the aqueous absorbents is greater than 90% and overcomes that in 2-(2-methoxyethoxy)ethanol. The CO2 absorption heat of aqueous BUMEA and DGA in DEGMME calculated using Gibbs–Helmholtz equation was found to be lower than that of conventional 30% aqueous MEA: the possible advantages of these systems with respect to aqueous MEA as CO2 absorbents have been discussed.

Suggested Citation

  • Barzagli, Francesco & Giorgi, Claudia & Mani, Fabrizio & Peruzzini, Maurizio, 2018. "Reversible carbon dioxide capture by aqueous and non-aqueous amine-based absorbents: A comparative analysis carried out by 13C NMR spectroscopy," Applied Energy, Elsevier, vol. 220(C), pages 208-219.
    • Handle: RePEc:eee:appene:v:220:y:2018:i:c:p:208-219
    DOI: 10.1016/j.apenergy.2018.03.076
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    1. Mondal, Monoj Kumar & Balsora, Hemant Kumar & Varshney, Prachi, 2012. "Progress and trends in CO2 capture/separation technologies: A review," Energy, Elsevier, vol. 46(1), pages 431-441.
    2. Xiao, Min & Liu, Helei & Idem, Raphael & Tontiwachwuthikul, Paitoon & Liang, Zhiwu, 2016. "A study of structure–activity relationships of commercial tertiary amines for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 184(C), pages 219-229.
    3. El Hadri, Nabil & Quang, Dang Viet & Goetheer, Earl L.V. & Abu Zahra, Mohammad R.M., 2017. "Aqueous amine solution characterization for post-combustion CO2 capture process," Applied Energy, Elsevier, vol. 185(P2), pages 1433-1449.
    4. Manzolini, G. & Sanchez Fernandez, E. & Rezvani, S. & Macchi, E. & Goetheer, E.L.V. & Vlugt, T.J.H., 2015. "Economic assessment of novel amine based CO2 capture technologies integrated in power plants based on European Benchmarking Task Force methodology," Applied Energy, Elsevier, vol. 138(C), pages 546-558.
    5. Oh, Se-Young & Binns, Michael & Cho, Habin & Kim, Jin-Kuk, 2016. "Energy minimization of MEA-based CO2 capture process," Applied Energy, Elsevier, vol. 169(C), pages 353-362.
    6. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    7. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    8. Zhao, Bin & Liu, Fangzheng & Cui, Zheng & Liu, Changjun & Yue, Hairong & Tang, Siyang & Liu, Yingying & Lu, Houfang & Liang, Bin, 2017. "Enhancing the energetic efficiency of MDEA/PZ-based CO2 capture technology for a 650MW power plant: Process improvement," Applied Energy, Elsevier, vol. 185(P1), pages 362-375.
    9. Shakerian, Farid & Kim, Ki-Hyun & Szulejko, Jan E. & Park, Jae-Woo, 2015. "A comparative review between amines and ammonia as sorptive media for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 148(C), pages 10-22.
    10. Zhang, Rui & Zhang, Xiaowen & Yang, Qi & Yu, Hai & Liang, Zhiwu & Luo, Xiao, 2017. "Analysis of the reduction of energy cost by using MEA-MDEA-PZ solvent for post-combustion carbon dioxide capture (PCC)," Applied Energy, Elsevier, vol. 205(C), pages 1002-1011.
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