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Development and Characterization of an Electrically Rechargeable Zinc-Air Battery Stack

Author

Listed:
  • Hongyun Ma

    (Department of Chemical Engineering, Tsinghua University, Beijing 100084, China)

  • Baoguo Wang

    (Department of Chemical Engineering, Tsinghua University, Beijing 100084, China)

  • Yongsheng Fan

    (Department of Chemical Engineering, Tsinghua University, Beijing 100084, China)

  • Weichen Hong

    (Department of Chemical Engineering, Tsinghua University, Beijing 100084, China)

Abstract

An electrically rechargeable zinc-air battery stack consisting of three single cells in series was designed using a novel structured bipolar plate with air-breathing holes. Alpha-MnO 2 and LaNiO 3 severed as the catalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). The anodic and cathodic polarization and individual cell voltages were measured at constant charge-discharge (C-D) current densities indicating a uniform voltage profile for each single cell. One hundred C-D cycles were carried out for the stack. The results showed that, over the initial 10 cycles, the average C-D voltage gap was about 0.94 V and the average energy efficiency reached 89.28% with current density charging at 15 mA·cm −2 and discharging at 25 mA·cm −2 . The total increase in charging voltage over the 100 C-D cycles was ~1.56% demonstrating excellent stability performance. The stack performance degradation was analyzed by galvanostatic electrochemical impedance spectroscopy. The charge transfer resistance of ORR increased from 1.57 to 2.21 Ω and that of Zn/Zn 2+ reaction increased from 0.21 to 0.34 Ω after 100 C-D cycles. The quantitative analysis guided the potential for the optimization of both positive and negative electrodes to improve the cycle life of the cell stack.

Suggested Citation

  • Hongyun Ma & Baoguo Wang & Yongsheng Fan & Weichen Hong, 2014. "Development and Characterization of an Electrically Rechargeable Zinc-Air Battery Stack," Energies, MDPI, vol. 7(10), pages 1-9, October.
    • Handle: RePEc:gam:jeners:v:7:y:2014:i:10:p:6549-6557:d:41132
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    References listed on IDEAS

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    1. Yanguang Li & Ming Gong & Yongye Liang & Ju Feng & Ji-Eun Kim & Hailiang Wang & Guosong Hong & Bo Zhang & Hongjie Dai, 2013. "Advanced zinc-air batteries based on high-performance hybrid electrocatalysts," Nature Communications, Nature, vol. 4(1), pages 1-7, June.
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    Cited by:

    1. Arenas, Luis F. & Loh, Adeline & Trudgeon, David P. & Li, Xiaohong & Ponce de León, Carlos & Walsh, Frank C., 2018. "The characteristics and performance of hybrid redox flow batteries with zinc negative electrodes for energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 992-1016.
    2. Wang, Keliang & Pei, Pucheng & Wang, Yichun & Liao, Cheng & Wang, Wei & Huang, Shangwei, 2018. "Advanced rechargeable zinc-air battery with parameter optimization," Applied Energy, Elsevier, vol. 225(C), pages 848-856.
    3. Wenger, Erez & Epstein, Michael & Kribus, Abraham, 2017. "Thermo-electro-chemical storage (TECS) of solar energy," Applied Energy, Elsevier, vol. 190(C), pages 788-799.
    4. Nak Heon Choi & Diego del Olmo & Diego Milian & Nadia El Kissi & Peter Fischer & Karsten Pinkwart & Jens Tübke, 2020. "Use of Carbon Additives towards Rechargeable Zinc Slurry Air Flow Batteries," Energies, MDPI, vol. 13(17), pages 1-12, August.
    5. Koyamparambath, Anish & Santillán-Saldivar, Jair & McLellan, Benjamin & Sonnemann, Guido, 2022. "Supply risk evolution of raw materials for batteries and fossil fuels for selected OECD countries (2000–2018)," Resources Policy, Elsevier, vol. 75(C).

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