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Reversible photochromic energy storage polyurea microcapsules via in-situ polymerization

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  • Sun, Shaofeng
  • Gao, Yan
  • Han, Na
  • Zhang, XingXiang
  • Li, Wei

Abstract

In this study, reversible photochromic polyurea (PU) microcapsules had been innovatively designed and prepared by in-situ polymerization successfully, which exhibited good latent heat storage and release properties. For the microcapsules, butyl stearate containing photochromic dye (spirooxazine) was used as the core material and PU as the shell material. The surface morphology, melt crystallization, thermal cycling durability, thermal stability and mechanical properties of PU microcapsules were systematically investigated with field emission scanning electron microscope (FE-SEM), different scanning calorimetry (DSC), thermogravimetric (TG) and dynamic mechanical analysis (DMA). And the light-to-thermal conversion performance was studied under sun simulation system. The results showed that the microcapsules synthesized with F2850, a new lipophilic amine, had better morphologies and uniform particle size distribution. When the mass ratio of isophorone diisocyanate (IPDI) to F2850 was 1:2, the surface of the microcapsules was smooth and compact thus resulting in the microcapsules with the highest mechanical strength. In addition, the PU microcapsules exhibited high energy storage efficiency, excellent thermal stability and thermal cyclic durability. Finally, the reversible photochromic microcapsules also presented prominent light-to-thermal conversion properties. What’s more, the temperature of the reversible photochromic microcapsules was nearly 4.9 °C higher than that of microcapsules at the same irradiation time.

Suggested Citation

  • Sun, Shaofeng & Gao, Yan & Han, Na & Zhang, XingXiang & Li, Wei, 2021. "Reversible photochromic energy storage polyurea microcapsules via in-situ polymerization," Energy, Elsevier, vol. 219(C).
    • Handle: RePEc:eee:energy:v:219:y:2021:i:c:s0360544220327377
    DOI: 10.1016/j.energy.2020.119630
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    References listed on IDEAS

    as
    1. Geng, Xiaoye & Li, Wei & Wang, Yu & Lu, Jiangwei & Wang, Jianping & Wang, Ning & Li, Jianjie & Zhang, Xingxiang, 2018. "Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing," Applied Energy, Elsevier, vol. 217(C), pages 281-294.
    2. Cao, Vinh Duy & Bui, Tri Quang & Kjøniksen, Anna-Lena, 2019. "Thermal analysis of multi-layer walls containing geopolymer concrete and phase change materials for building applications," Energy, Elsevier, vol. 186(C).
    3. Kong, Minsuk & Alvarado, Jorge L. & Thies, Curt & Morefield, Sean & Marsh, Charles P., 2017. "Field evaluation of microencapsulated phase change material slurry in ground source heat pump systems," Energy, Elsevier, vol. 122(C), pages 691-700.
    4. Qiu, Zhongzhu & Zhou, Yufei & Yao, Yuan & Liu, Fang & Guo, Ruitang, 2019. "Modification of microencapsulated phase change materials(MPCMs) by synthesizing graphene quantum dots(GQDs) and nano-aluminum for energy storage and heat transfer applications," Energy, Elsevier, vol. 181(C), pages 1331-1338.
    5. Li, Bingmeng & Shu, Dan & Wang, Ruifang & Zhai, Lanlan & Chai, Yuye & Lan, Yunjun & Cao, Hongwei & Zou, Chao, 2020. "Polyethylene glycol/silica (PEG@SiO2) composite inspired by the synthesis of mesoporous materials as shape-stabilized phase change material for energy storage," Renewable Energy, Elsevier, vol. 145(C), pages 84-92.
    6. Li, Dong & Wu, Yangyang & Zhang, Guojun & Arıcı, Müslüm & Liu, Changyu & Wang, Fuqiang, 2018. "Influence of glazed roof containing phase change material on indoor thermal environment and energy consumption," Applied Energy, Elsevier, vol. 222(C), pages 343-350.
    7. Li, Songlin & Dong, Beibei & Wang, Jinghang & Li, Juan & Shen, Tongtong & Peng, Hao & Ling, Xiang, 2019. "Synthesis and characterization of mixed alkanes microcapsules with phase change temperature below ice point for cryogenic thermal energy storage," Energy, Elsevier, vol. 187(C).
    8. Abdolmaleki, L. & Sadrameli, S.M. & Pirvaram, A., 2020. "Application of environmental friendly and eutectic phase change materials for the efficiency enhancement of household freezers," Renewable Energy, Elsevier, vol. 145(C), pages 233-241.
    9. Liu, Huan & Niu, Jinfei & Wang, Xiaodong & Wu, Dezhen, 2019. "Design and construction of mesoporous silica/n-eicosane phase-change nanocomposites for supercooling depression and heat transfer enhancement," Energy, Elsevier, vol. 188(C).
    10. He, Yayue & Li, Wei & Han, Na & Wang, Jianping & Zhang, Xingxiang, 2019. "Facile flexible reversible thermochromic membranes based on micro/nanoencapsulated phase change materials for wearable temperature sensor," Applied Energy, Elsevier, vol. 247(C), pages 615-629.
    11. Geng, Xiaoye & Li, Wei & Yin, Qing & Wang, Yu & Han, Na & Wang, Ning & Bian, Junmin & Wang, Jianping & Zhang, Xingxiang, 2018. "Design and fabrication of reversible thermochromic microencapsulated phase change materials for thermal energy storage and its antibacterial activity," Energy, Elsevier, vol. 159(C), pages 857-869.
    12. Li, Chaoen & Yu, Hang & Song, Yuan & Liang, Hao & Yan, Xun, 2019. "Preparation and characterization of PMMA/TiO2 hybrid shell microencapsulated PCMs for thermal energy storage," Energy, Elsevier, vol. 167(C), pages 1031-1039.
    13. Tahan Latibari, Sara & Mehrali, Mohammad & Mehrali, Mehdi & Afifi, Amalina Binti Muhammad & Mahlia, Teuku Meurah Indra & Akhiani, Amir Reza & Metselaar, Hendrik Simon Cornelis, 2015. "Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol–gel method," Energy, Elsevier, vol. 85(C), pages 635-644.
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