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Improving economics of lignocellulosic biofuels: An integrated strategy for coproducing 1,5-pentanediol and ethanol

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  • Huang, Kefeng
  • Won, Wangyun
  • Barnett, Kevin J.
  • Brentzel, Zachary J.
  • Alonso, David M.
  • Huber, George W.
  • Dumesic, James A.
  • Maravelias, Christos T.

Abstract

A biorefinery strategy for the coproduction of ethanol and 1,5-pentanediol (1,5-PDO), which can be used as polyester and polyurethane component, from lignocellulosic biomass is proposed. This strategy integrates biomass fractionation with simultaneous conversion of hemicellulose and cellulose constituents into 1,5-PDO and ethanol, respectively. An experimentally-based process model is developed to determine the economic potential of the integrated strategy. The coproduction strategy becomes competitive with the ethanol-only strategy when 1,5-PDO can be sold at $1140/ton, which is well below the market price of 1,5-PDO. The most important process parameters include biomass loading for biomass fractionation, enzyme loading for enzymatic hydrolysis and fermentation, and overall achievable yields from C5 sugars to 1,5-PDO.

Suggested Citation

  • Huang, Kefeng & Won, Wangyun & Barnett, Kevin J. & Brentzel, Zachary J. & Alonso, David M. & Huber, George W. & Dumesic, James A. & Maravelias, Christos T., 2018. "Improving economics of lignocellulosic biofuels: An integrated strategy for coproducing 1,5-pentanediol and ethanol," Applied Energy, Elsevier, vol. 213(C), pages 585-594.
  • Handle: RePEc:eee:appene:v:213:y:2018:i:c:p:585-594
    DOI: 10.1016/j.apenergy.2017.11.002
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    1. Reyes Valle, C. & Villanueva Perales, A.L. & Vidal-Barrero, F. & Gómez-Barea, A., 2013. "Techno-economic assessment of biomass-to-ethanol by indirect fluidized bed gasification: Impact of reforming technologies and comparison with entrained flow gasification," Applied Energy, Elsevier, vol. 109(C), pages 254-266.
    2. Frankó, Balázs & Galbe, Mats & Wallberg, Ola, 2016. "Bioethanol production from forestry residues: A comparative techno-economic analysis," Applied Energy, Elsevier, vol. 184(C), pages 727-736.
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    1. Ng, Rex T.L. & Fasahati, Peyman & Huang, Kefeng & Maravelias, Christos T., 2019. "Utilizing stillage in the biorefinery: Economic, technological and energetic analysis," Applied Energy, Elsevier, vol. 241(C), pages 491-503.
    2. Wang, Pixiang & Chen, Yong Mei & Wang, Yifen & Lee, Yoon Y. & Zong, Wenming & Taylor, Steven & McDonald, Timothy & Wang, Yi, 2019. "Towards comprehensive lignocellulosic biomass utilization for bioenergy production: Efficient biobutanol production from acetic acid pretreated switchgrass with Clostridium saccharoperbutylacetonicum ," Applied Energy, Elsevier, vol. 236(C), pages 551-559.
    3. Ahn, Byeongchan & Park, Chulhwan & Liu, J. Jay & Ok, Yong Sik & Won, Wangyun, 2023. "Maximizing the utilization of lignocellulosic biomass: Process development and analysis," Renewable Energy, Elsevier, vol. 215(C).
    4. Awasthi, Mukesh Kumar & Sarsaiya, Surendra & Patel, Anil & Juneja, Ankita & Singh, Rajendra Prasad & Yan, Binghua & Awasthi, Sanjeev Kumar & Jain, Archana & Liu, Tao & Duan, Yumin & Pandey, Ashok & Zh, 2020. "Refining biomass residues for sustainable energy and bio-products: An assessment of technology, its importance, and strategic applications in circular bio-economy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
    5. Choe, Bomin & Lee, Shinje & Won, Wangyun, 2021. "Coproduction of butene oligomers and adipic acid from lignocellulosic biomass: Process design and evaluation," Energy, Elsevier, vol. 235(C).
    6. Kim, H. & Baek, S. & Won, W., 2022. "Integrative technical, economic, and environmental sustainability analysis for the development process of biomass-derived 2,5-furandicarboxylic acid," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    7. Kim, Hyunwoo & Lee, Shinje & Won, Wangyun, 2021. "System-level analyses for the production of 1,6-hexanediol from cellulose," Energy, Elsevier, vol. 214(C).
    8. Byun, Jaewon & Han, Jeehoon, 2020. "Economic feasible strategy of cellulosic biofuels: Co-production of pentanediols," Energy, Elsevier, vol. 193(C).
    9. Ghadge, Abhijeet & van der Werf, Sjoerd & Er Kara, Merve & Goswami, Mohit & Kumar, Pankaj & Bourlakis, Michael, 2020. "Modelling the impact of climate change risk on bioethanol supply chains," Technological Forecasting and Social Change, Elsevier, vol. 160(C).
    10. Choe, Bomin & Lee, Shinje & Won, Wangyun, 2020. "Process integration and optimization for economical production of commodity chemicals from lignocellulosic biomass," Renewable Energy, Elsevier, vol. 162(C), pages 242-248.

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