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System-level analyses for the production of 1,6-hexanediol from cellulose

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  • Kim, Hyunwoo
  • Lee, Shinje
  • Won, Wangyun

Abstract

A new strategy for the production of 1,6-hexanediol (1,6-HDO) from biomass is developed in this study. 1,6-HDO is obtained via various continuous catalytic conversions, including dehydration, hydrogenation, and hydrogenolysis. Effective separation blocks are designed to enable the reusing of the solvent and hydrogen as well as for the recovery of 1,6-HDO. Heat integration is performed to reduce energy requirements and a significant amount of energy is recovered by introducing heat pumps into the heat integration network. In our technoeconomic analysis, the minimum selling price of 1,6-HDO is estimated to be $5282/ton. This indicates that the proposed process has the potential to replace conventional petroleum-based methods for producing 1,6-HDO. Moreover, a pioneer plant analysis is carried out to assess the risks and uncertainties of a production plant by estimating performance shortfalls and growth costs. Finally, a sensitivity analysis is performed to investigate the economic feasibility of the proposed process.

Suggested Citation

  • Kim, Hyunwoo & Lee, Shinje & Won, Wangyun, 2021. "System-level analyses for the production of 1,6-hexanediol from cellulose," Energy, Elsevier, vol. 214(C).
    • Handle: RePEc:eee:energy:v:214:y:2021:i:c:s0360544220320818
    DOI: 10.1016/j.energy.2020.118974
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    References listed on IDEAS

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    1. Huang, Kefeng & Won, Wangyun & Barnett, Kevin J. & Brentzel, Zachary J. & Alonso, David M. & Huber, George W. & Dumesic, James A. & Maravelias, Christos T., 2018. "Improving economics of lignocellulosic biofuels: An integrated strategy for coproducing 1,5-pentanediol and ethanol," Applied Energy, Elsevier, vol. 213(C), pages 585-594.
    2. Kiss, Anton A. & Flores Landaeta, Servando J. & Infante Ferreira, Carlos A., 2012. "Towards energy efficient distillation technologies – Making the right choice," Energy, Elsevier, vol. 47(1), pages 531-542.
    3. Jisook Lee & Yongho Son & Kwang Soon Lee & Wangyun Won, 2019. "Economic Analysis and Environmental Impact Assessment of Heat Pump-Assisted Distillation in a Gas Fractionation Unit," Energies, MDPI, vol. 12(5), pages 1-19, March.
    4. Chua, K.J. & Chou, S.K. & Yang, W.M., 2010. "Advances in heat pump systems: A review," Applied Energy, Elsevier, vol. 87(12), pages 3611-3624, December.
    5. Won, Wangyun & Maravelias, Christos T., 2017. "Thermal fractionation and catalytic upgrading of lignocellulosic biomass to biofuels: Process synthesis and analysis," Renewable Energy, Elsevier, vol. 114(PB), pages 357-366.
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    Cited by:

    1. Kim, H. & Baek, S. & Won, W., 2022. "Integrative technical, economic, and environmental sustainability analysis for the development process of biomass-derived 2,5-furandicarboxylic acid," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).

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