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An integrated device to convert carbon dioxide to energy

Author

Listed:
  • Saric, Steven
  • Biggs, Brenna
  • Janbahan, Mika
  • Hamilton, Ryan
  • Do, Huy K.
  • Mayoral, Salvador
  • Haan, John L.

Abstract

A device was constructed that converts dissolved carbon dioxide to power. In a central reservoir this device wholly contains the electrochemical conversion cycle of carbonate to formate and formate to carbonate. At one end of the reservoir is a cation exchange membrane containing Sn and Pt catalysts to reduce carbonate and oxidize water, respectively. At the other end is an anion exchange membrane containing Pd and Pt catalysts to oxidize formate and reduce oxygen, respectively (the direct formate fuel cell). The electrochemical reduction of carbonate produced 54mM formate after 15min. The formate produced within this device produced a power density of 2mWcm−2. The overall efficiency of a 15min run of this device was 40%. This device represents a two order of magnitude increase in the time efficiency with which carbonate is reduced to formate compared with the first reported device that converts carbon dioxide to power.

Suggested Citation

  • Saric, Steven & Biggs, Brenna & Janbahan, Mika & Hamilton, Ryan & Do, Huy K. & Mayoral, Salvador & Haan, John L., 2016. "An integrated device to convert carbon dioxide to energy," Applied Energy, Elsevier, vol. 183(C), pages 1346-1350.
    • Handle: RePEc:eee:appene:v:183:y:2016:i:c:p:1346-1350
    DOI: 10.1016/j.apenergy.2016.09.080
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    References listed on IDEAS

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    1. Zeng, L. & Tang, Z.K. & Zhao, T.S., 2014. "A high-performance alkaline exchange membrane direct formate fuel cell," Applied Energy, Elsevier, vol. 115(C), pages 405-410.
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    Cited by:

    1. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    2. Ali Saleh Bairq, Zain & Gao, Hongxia & Huang, Yufei & Zhang, Haiyan & Liang, Zhiwu, 2019. "Enhancing CO2 desorption performance in rich MEA solution by addition of SO42−/ZrO2/SiO2 bifunctional catalyst," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    3. Ba Hung, Nguyen & Jaewon, Sung & Lim, Ocktaeck, 2017. "A study of the effects of input parameters on the dynamics and required power of an electric bicycle," Applied Energy, Elsevier, vol. 204(C), pages 1347-1362.
    4. Chen, S.J. & Zhu, M. & Fu, Y. & Huang, Y.X. & Tao, Z.C. & Li, W.L., 2017. "Using 13X, LiX, and LiPdAgX zeolites for CO2 capture from post-combustion flue gas," Applied Energy, Elsevier, vol. 191(C), pages 87-98.
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    6. Muneeb, Omar & Do, Emily & Boyd, Desiree & Perez, Josh & Haan, John L., 2019. "PdCu/C anode catalysts for the alkaline ascorbate fuel cell," Applied Energy, Elsevier, vol. 235(C), pages 473-479.

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