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Adsorption and regeneration study of polyethylenimine-impregnated millimeter-sized mesoporous carbon spheres for post-combustion CO2 capture

Author

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  • Wang, Mei
  • Yao, Liwen
  • Wang, Jitong
  • Zhang, Zixiao
  • Qiao, Wenming
  • Long, Donghui
  • Ling, Licheng

Abstract

The feasibility of polyethylenimine (PEI)-impregnated millimeter-sized mesoporous carbon spheres (MCSs) for post-combustion CO2 capture is systematically studied over a wide range of adsorption and regeneration conditions. MCSs with developed mesoporous structure and good electrical conductivity are used as supports, while high-molecular-weight PEI (Mn∼10,000) is screened to be the optimal amine due to its thermal stability. At the optimal polyethylene glycol (PEG) loading of 20wt.%, the mass/volume-based adsorption capacity is efficiently improved by 25.7% and 109.5%, respectively. The optimized adsorbent exhibits high equilibrium adsorption capacity of 163.4mg/g for 15% CO2 at 75°C under dry condition, and it could be further enhanced to 187.5mg/g at the relative humidity of 60%. The presence of O2, SO2, NO and NO2 would lead to the decreased adsorption capacity after consecutive adsorption–desorption cycles, due to the irreversible chemical reaction. Moisture could inhibit the negative effect of O2 but deteriorate the detrimental effects of SO2, NO and NO2. Depending on the good sphericity, uniform particle size, excellent thermal/electrical conductivity and good mechanical properties of MCS, PEI-impregnated MCS adsorbents could be directly used in fixed bed system and be applicable for thermal swing adsorption (TSA), vacuum swing adsorption (VSA) and novel electric swing adsorption (ESA) processes. The adsorbents could maintain fairly stable cyclic performance during the rapid VSA process, making rapid VSA of great potential for technical–economical post-combustion CO2 capture.

Suggested Citation

  • Wang, Mei & Yao, Liwen & Wang, Jitong & Zhang, Zixiao & Qiao, Wenming & Long, Donghui & Ling, Licheng, 2016. "Adsorption and regeneration study of polyethylenimine-impregnated millimeter-sized mesoporous carbon spheres for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 168(C), pages 282-290.
    • Handle: RePEc:eee:appene:v:168:y:2016:i:c:p:282-290
    DOI: 10.1016/j.apenergy.2016.01.085
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    References listed on IDEAS

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    1. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    2. Hedin, Niklas & Andersson, Linnéa & Bergström, Lennart & Yan, Jinyue, 2013. "Adsorbents for the post-combustion capture of CO2 using rapid temperature swing or vacuum swing adsorption," Applied Energy, Elsevier, vol. 104(C), pages 418-433.
    3. Wang, Weilong & Li, Jiang & Wei, Xiaolan & Ding, Jing & Feng, Haijun & Yan, Jinyue & Yang, Jianping, 2015. "Carbon dioxide adsorption thermodynamics and mechanisms on MCM-41 supported polyethylenimine prepared by wet impregnation method," Applied Energy, Elsevier, vol. 142(C), pages 221-228.
    4. Li, Kaimin & Jiang, Jianguo & Yan, Feng & Tian, Sicong & Chen, Xuejing, 2014. "The influence of polyethyleneimine type and molecular weight on the CO2 capture performance of PEI-nano silica adsorbents," Applied Energy, Elsevier, vol. 136(C), pages 750-755.
    5. Ben-Mansour, R. & Habib, M.A. & Bamidele, O.E. & Basha, M. & Qasem, N.A.A. & Peedikakkal, A. & Laoui, T. & Ali, M., 2016. "Carbon capture by physical adsorption: Materials, experimental investigations and numerical modeling and simulations – A review," Applied Energy, Elsevier, vol. 161(C), pages 225-255.
    6. Cheung, Ocean & Bacsik, Zoltán & Liu, Qingling & Mace, Amber & Hedin, Niklas, 2013. "Adsorption kinetics for CO2 on highly selective zeolites NaKA and nano-NaKA," Applied Energy, Elsevier, vol. 112(C), pages 1326-1336.
    7. Li, Bao-Hong & Zhang, Nan & Smith, Robin, 2016. "Simulation and analysis of CO2 capture process with aqueous monoethanolamine solution," Applied Energy, Elsevier, vol. 161(C), pages 707-717.
    8. Barelli, L. & Bidini, G. & Gallorini, F., 2016. "CO2 capture with solid sorbent: CFD model of an innovative reactor concept," Applied Energy, Elsevier, vol. 162(C), pages 58-67.
    9. Guo, Yafei & Zhao, Chuanwen & Li, Changhai & Lu, Shouxiang, 2014. "Application of PEI–K2CO3/AC for capturing CO2 from flue gas after combustion," Applied Energy, Elsevier, vol. 129(C), pages 17-24.
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    5. Qasem, Naef A.A. & Ben-Mansour, Rached, 2018. "Energy and productivity efficient vacuum pressure swing adsorption process to separate CO2 from CO2/N2 mixture using Mg-MOF-74: A CFD simulation," Applied Energy, Elsevier, vol. 209(C), pages 190-202.
    6. Qasem, Naef A.A. & Ben-Mansour, Rached & Habib, Mohamed A., 2018. "An efficient CO2 adsorptive storage using MOF-5 and MOF-177," Applied Energy, Elsevier, vol. 210(C), pages 317-326.
    7. Chen, S.J. & Zhu, M. & Fu, Y. & Huang, Y.X. & Tao, Z.C. & Li, W.L., 2017. "Using 13X, LiX, and LiPdAgX zeolites for CO2 capture from post-combustion flue gas," Applied Energy, Elsevier, vol. 191(C), pages 87-98.
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    9. Yang, Chuanruo & Du, Zhilin & Jin, Junsu & Chen, Jian & Mi, Jianguo, 2020. "Epoxide-functionalized tetraethylenepentamine encapsulated into porous copolymer spheres for CO2 capture with superior stability," Applied Energy, Elsevier, vol. 260(C).
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    11. Lee, Jae Won & Torres Pineda, Israel & Lee, Jung Hun & Kang, Yong Tae, 2016. "Combined CO2 absorption/regeneration performance enhancement by using nanoabsorbents," Applied Energy, Elsevier, vol. 178(C), pages 164-176.
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