IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v168y2016icp193-203.html
   My bibliography  Save this article

Perovskite-type oxides LaFe1−xCoxO3 for chemical looping steam methane reforming to syngas and hydrogen co-production

Author

Listed:
  • Zhao, Kun
  • He, Fang
  • Huang, Zhen
  • Wei, Guoqiang
  • Zheng, Anqing
  • Li, Haibin
  • Zhao, Zengli

Abstract

Chemical looping steam methane reforming is a novel technology for syngas and hydrogen production. It’s very important to find suitable oxygen carriers with good reactivity and high agglomeration resistance for this process. In the present work, the perovskite-type oxides LaFe1−xCoxO3 with x=0.1, 0.3, 0.5, 0.7, 1.0 were used as oxygen carriers. The influence of Co doping on the characteristics and the stabilities of these perovskite-type oxides were investigated by means of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), hydrogen temperature-programmed reduction (H2-TPR), Brunauer–Emmett–Teller (BET) surface area and fixed-bed experiments. All the as-prepared samples with various Co substitutions exhibited crystalline perovskite structure similar to LaFeO3. The surface adsorbed oxygen which is beneficial to the complete oxidation of CH4 increased as the Co substitution increase. From the point of view of the oxygen-donation ability, resistance to carbon formation, as well as hydrogen generation capacity, the optimal degree of Co substitution is x=0.3. Despite slight sintering, the perovskite-type oxide LaFe0.7Co0.3O3 showed very good regenerability during the twenty redox reactions. In the methane reduction stage, syngas with H2/CO molar ratio close to 2:1 was obtained in the twenty cycles with 85% of CH4 conversion, 43% of CO selectivity, and 50% of H2 selectivity. While in the steam oxidation stage, a steadily hydrogen productivity at about 4mmol/g oxygen carriers was generated.

Suggested Citation

  • Zhao, Kun & He, Fang & Huang, Zhen & Wei, Guoqiang & Zheng, Anqing & Li, Haibin & Zhao, Zengli, 2016. "Perovskite-type oxides LaFe1−xCoxO3 for chemical looping steam methane reforming to syngas and hydrogen co-production," Applied Energy, Elsevier, vol. 168(C), pages 193-203.
  • Handle: RePEc:eee:appene:v:168:y:2016:i:c:p:193-203
    DOI: 10.1016/j.apenergy.2016.01.052
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916300320
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2016.01.052?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kodama, T. & Shimizu, T. & Satoh, T. & Shimizu, K.-I., 2003. "Stepwise production of CO-rich syngas and hydrogen via methane reforming by a WO3-redox catalyst," Energy, Elsevier, vol. 28(11), pages 1055-1068.
    2. Forster, Martin, 2004. "Theoretical investigation of the system SnOx/Sn for the thermochemical storage of solar energy," Energy, Elsevier, vol. 29(5), pages 789-799.
    3. Rydén, Magnus & Leion, Henrik & Mattisson, Tobias & Lyngfelt, Anders, 2014. "Combined oxides as oxygen-carrier material for chemical-looping with oxygen uncoupling," Applied Energy, Elsevier, vol. 113(C), pages 1924-1932.
    4. Kodama, T & Ohtake, H & Matsumoto, S & Aoki, A & Shimizu, T & Kitayama, Y, 2000. "Thermochemical methane reforming using a reactive WO3/W redox system," Energy, Elsevier, vol. 25(5), pages 411-425.
    5. Neal, Luke & Shafiefarhood, Arya & Li, Fanxing, 2015. "Effect of core and shell compositions on MeOx@LaySr1−yFeO3 core–shell redox catalysts for chemical looping reforming of methane," Applied Energy, Elsevier, vol. 157(C), pages 391-398.
    6. Tang, Mingchen & Xu, Long & Fan, Maohong, 2015. "Progress in oxygen carrier development of methane-based chemical-looping reforming: A review," Applied Energy, Elsevier, vol. 151(C), pages 143-156.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xiang, Dong & Jin, Tong & Lei, Xinru & Liu, Shuai & Jiang, Yong & Dong, Zhongbing & Tao, Quanbao & Cao, Yan, 2018. "The high efficient synthesis of natural gas from a joint-feedstock of coke-oven gas and pulverized coke via a chemical looping combustion scheme," Applied Energy, Elsevier, vol. 212(C), pages 944-954.
    2. Luo, Ming & Yi, Yang & Wang, Shuzhong & Wang, Zhuliang & Du, Min & Pan, Jianfeng & Wang, Qian, 2018. "Review of hydrogen production using chemical-looping technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 3186-3214.
    3. Zhu, Yanyan & Jin, Nannan & Liu, Ruilin & Sun, Xueyan & Bai, Lei & Tian, Hanjing & Ma, Xiaoxun & Wang, Xiaodong, 2020. "Bimetallic BaFe2MAl9O19 (M = Mn, Ni, and Co) hexaaluminates as oxygen carriers for chemical looping dry reforming of methane," Applied Energy, Elsevier, vol. 258(C).
    4. Jin, Jian & Wei, Xin & Liu, Mingkai & Yu, Yuhang & Li, Wenjia & Kong, Hui & Hao, Yong, 2018. "A solar methane reforming reactor design with enhanced efficiency," Applied Energy, Elsevier, vol. 226(C), pages 797-807.
    5. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Zhao, Xiaotong & Sun, Xiaohang, 2017. "Hydrogen production from ethanol decomposition by pulsed discharge with needle-net configurations," Applied Energy, Elsevier, vol. 206(C), pages 126-133.
    6. Jiang, Qiongqiong & Zhang, Hao & Deng, Ya'nan & Kang, Qilan & Hong, Hui & Jin, Hongguang, 2018. "Properties and reactivity of LaCuxNi1−xO3 perovskites in chemical-looping combustion for mid-temperature solar-thermal energy storage," Applied Energy, Elsevier, vol. 228(C), pages 1506-1514.
    7. Qiu, Yu & Zhang, Shuai & Cui, Dongxu & Li, Min & Zeng, Jimin & Zeng, Dewang & Xiao, Rui, 2019. "Enhanced hydrogen production performance at intermediate temperatures through the synergistic effects of binary oxygen carriers," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    8. Marek, Ewa & Hu, Wenting & Gaultois, Michael & Grey, Clare P. & Scott, Stuart A., 2018. "The use of strontium ferrite in chemical looping systems," Applied Energy, Elsevier, vol. 223(C), pages 369-382.
    9. Gao, Yuan & Zhang, Shuai & Sun, Hao & Wang, Ruixue & Tu, Xin & Shao, Tao, 2018. "Highly efficient conversion of methane using microsecond and nanosecond pulsed spark discharges," Applied Energy, Elsevier, vol. 226(C), pages 534-545.
    10. Zhao, Kun & Li, Luwei & Zheng, Anqing & Huang, Zhen & He, Fang & Shen, Yang & Wei, Guoqiang & Li, Haibin & Zhao, Zengli, 2017. "Synergistic improvements in stability and performance of the double perovskite-type oxides La2−xSrxFeCoO6 for chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 197(C), pages 393-404.
    11. Zhang, Haotian & Sun, Zhuxing & Hu, Yun Hang, 2021. "Steam reforming of methane: Current states of catalyst design and process upgrading," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    12. Huang, Zhen & Deng, Zhengbing & Chen, Dezhen & He, Fang & Liu, Shuai & Zhao, Kun & Wei, Guoqiang & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2017. "Thermodynamic analysis and kinetic investigations on biomass char chemical looping gasification using Fe-Ni bimetallic oxygen carrier," Energy, Elsevier, vol. 141(C), pages 1836-1844.
    13. Akbari-Emadabadi, S. & Rahimpour, M.R. & Hafizi, A. & Keshavarz, P., 2017. "Production of hydrogen-rich syngas using Zr modified Ca-Co bifunctional catalyst-sorbent in chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 206(C), pages 51-62.
    14. Lu, Chunqiang & Li, Kongzhai & Wang, Hua & Zhu, Xing & Wei, Yonggang & Zheng, Min & Zeng, Chunhua, 2018. "Chemical looping reforming of methane using magnetite as oxygen carrier: Structure evolution and reduction kinetics," Applied Energy, Elsevier, vol. 211(C), pages 1-14.
    15. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Luo, Ming & Yi, Yang & Wang, Shuzhong & Wang, Zhuliang & Du, Min & Pan, Jianfeng & Wang, Qian, 2018. "Review of hydrogen production using chemical-looping technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 3186-3214.
    2. Kang, Dohyung & Lim, Hyun Suk & Lee, Minbeom & Lee, Jae W., 2018. "Syngas production on a Ni-enhanced Fe2O3/Al2O3 oxygen carrier via chemical looping partial oxidation with dry reforming of methane," Applied Energy, Elsevier, vol. 211(C), pages 174-186.
    3. Huang, Jijiang & Liu, Wen & Hu, Wenting & Metcalfe, Ian & Yang, Yanhui & Liu, Bin, 2019. "Phase interactions in Ni-Cu-Al2O3 mixed oxide oxygen carriers for chemical looping applications," Applied Energy, Elsevier, vol. 236(C), pages 635-647.
    4. Lu, Chunqiang & Li, Kongzhai & Wang, Hua & Zhu, Xing & Wei, Yonggang & Zheng, Min & Zeng, Chunhua, 2018. "Chemical looping reforming of methane using magnetite as oxygen carrier: Structure evolution and reduction kinetics," Applied Energy, Elsevier, vol. 211(C), pages 1-14.
    5. Zhang, Haotian & Sun, Zhuxing & Hu, Yun Hang, 2021. "Steam reforming of methane: Current states of catalyst design and process upgrading," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    6. Jiang, Qiongqiong & Zhang, Hao & Deng, Ya'nan & Kang, Qilan & Hong, Hui & Jin, Hongguang, 2018. "Properties and reactivity of LaCuxNi1−xO3 perovskites in chemical-looping combustion for mid-temperature solar-thermal energy storage," Applied Energy, Elsevier, vol. 228(C), pages 1506-1514.
    7. Zhao, Kun & Li, Luwei & Zheng, Anqing & Huang, Zhen & He, Fang & Shen, Yang & Wei, Guoqiang & Li, Haibin & Zhao, Zengli, 2017. "Synergistic improvements in stability and performance of the double perovskite-type oxides La2−xSrxFeCoO6 for chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 197(C), pages 393-404.
    8. Liu, Yiyuan & Zhu, Qunzhi & Zhang, Tao & Yan, Xuefeng & Duan, Rui, 2020. "Analysis of chemical-looping hydrogen production and power generation system driven by solar energy," Renewable Energy, Elsevier, vol. 154(C), pages 863-874.
    9. Benincosa, William & Siriwardane, Ranjani & Tian, Hanjing & Riley, Jarrett, 2017. "Unique phase identification of trimetallic copper iron manganese oxygen carrier using simultaneous differential scanning calorimetry/thermogravimetric analysis during chemical looping combustion react," Applied Energy, Elsevier, vol. 203(C), pages 522-534.
    10. Lin, Shen & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Long, Yanhui & Yang, Kun & He, Fang & Wang, Hua & Li, Kongzhai, 2020. "Synergy of red mud oxygen carrier with MgO and NiO for enhanced chemical-looping combustion," Energy, Elsevier, vol. 197(C).
    11. Zhu, Yanyan & Jin, Nannan & Liu, Ruilin & Sun, Xueyan & Bai, Lei & Tian, Hanjing & Ma, Xiaoxun & Wang, Xiaodong, 2020. "Bimetallic BaFe2MAl9O19 (M = Mn, Ni, and Co) hexaaluminates as oxygen carriers for chemical looping dry reforming of methane," Applied Energy, Elsevier, vol. 258(C).
    12. Rajabi, Mahsa & Mehrpooya, Mehdi & Haibo, Zhao & Huang, Zhen, 2019. "Chemical looping technology in CHP (combined heat and power) and CCHP (combined cooling heating and power) systems: A critical review," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    13. Gu, Zhenhua & Zhang, Ling & Lu, Chunqiang & Qing, Shan & Li, Kongzhai, 2020. "Enhanced performance of copper ore oxygen carrier by red mud modification for chemical looping combustion," Applied Energy, Elsevier, vol. 277(C).
    14. Medrano, J.A. & Potdar, I. & Melendez, J. & Spallina, V. & Pacheco-Tanaka, D.A. & van Sint Annaland, M. & Gallucci, F., 2018. "The membrane-assisted chemical looping reforming concept for efficient H2 production with inherent CO2 capture: Experimental demonstration and model validation," Applied Energy, Elsevier, vol. 215(C), pages 75-86.
    15. Fan Li & Dong Liu & Ke Sun & Songheng Yang & Fangzheng Peng & Kexin Zhang & Guodong Guo & Yuan Si, 2024. "Towards a Future Hydrogen Supply Chain: A Review of Technologies and Challenges," Sustainability, MDPI, vol. 16(5), pages 1-36, February.
    16. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.
    17. Zhu, Min & Chen, Shiyi & Soomro, Ahsanullah & Hu, Jun & Sun, Zhao & Ma, Shiwei & Xiang, Wenguo, 2018. "Effects of supports on reduction activity and carbon deposition of iron oxide for methane chemical looping hydrogen generation," Applied Energy, Elsevier, vol. 225(C), pages 912-921.
    18. Li, Fang-zhou & Kang, Jing-xian & Song, Yun-cai & Feng, Jie & Li, Wen-ying, 2020. "Thermodynamic feasibility for molybdenum-based gaseous oxides assisted looping coal gasification and its derived power plant," Energy, Elsevier, vol. 194(C).
    19. Shah, Vedant & Cheng, Zhuo & Baser, Deven S. & Fan, Jonathan A. & Fan, Liang-Shih, 2021. "Highly Selective Production of Syngas from Chemical Looping Reforming of Methane with CO2 Utilization on MgO-supported Calcium Ferrite Redox Materials," Applied Energy, Elsevier, vol. 282(PA).
    20. Habib, Mohamed A. & Salaudeen, Shakirudeen A. & Nemitallah, Medhat A. & Ben-Mansour, R. & Mokheimer, Esmail M.A., 2016. "Numerical investigation of syngas oxy-combustion inside a LSCF-6428 oxygen transport membrane reactor," Energy, Elsevier, vol. 96(C), pages 654-665.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:168:y:2016:i:c:p:193-203. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.