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Oxy-fuel combustion as an alternative for increasing lime production in rotary kilns

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  • Granados, D.A.
  • Chejne, F.
  • Mejía, J.M.

Abstract

The effect of Flue Gas Recirculation (FGR) on the decarbonation process during oxy-fuel combustion in a lime (and cement) rotary kiln is analyzed using an unsteady one-dimensional Eulerian–Lagrangian mathematical model. The model considers gas and limestone as continuous phases and the coal particles as the discrete phase. The model predicts limestone decarbonation, temperature and species distribution of gas and solid phases along the kiln. Simulation results of an air-combustion case are successfully validated with reported experimental data. This model is used to study and to compare the conventional air combustion process with oxy-fuel combustion with FGR ratios between 30% and 80% as controller parameter in this process. Changes in decarbonation process due to energy fluxes by convection and radiation with different FGRs were simulated and analyzed. Simulation results indicate a temperature increase of 20% in the gas and solid phases and a higher decarbonation rate of 40% in relation to the air-combustion case, for a given constant fuel consumption rate. However, for a given temperature, the increase of the CO2 partial pressure in the oxy-fuel case promotes a reduction of the decarbonation rate. Therefore, there is a compromise between FGR and decarbonation rate, which is analyzed in the present study. Simulation results of the decarbonation step in low FGR cases, compared to air-combustion case, shows that conversion takes place in shorter distances in the kiln, suggesting that the production rate can be increased for existing kilns in oxy-fuel kilns or, equivalently, shorter kilns can be designed for an equivalent production rate.

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  • Granados, D.A. & Chejne, F. & Mejía, J.M., 2015. "Oxy-fuel combustion as an alternative for increasing lime production in rotary kilns," Applied Energy, Elsevier, vol. 158(C), pages 107-117.
  • Handle: RePEc:eee:appene:v:158:y:2015:i:c:p:107-117
    DOI: 10.1016/j.apenergy.2015.07.075
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    References listed on IDEAS

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    7. Xu, Mingxin & Li, Shiyuan & Wu, Yinghai & Jia, Lufei & Lu, Qinggang, 2017. "The characteristics of recycled NO reduction over char during oxy-fuel fluidized bed combustion," Applied Energy, Elsevier, vol. 190(C), pages 553-562.
    8. Nhuchhen, Daya R. & Sit, Song P. & Layzell, David B., 2022. "Decarbonization of cement production in a hydrogen economy," Applied Energy, Elsevier, vol. 317(C).
    9. Promdee, Kittiphop & Chanvidhwatanakit, Jirawat & Satitkune, Somruedee & Boonmee, Chakkrich & Kawichai, Thitipong & Jarernprasert, Sittipong & Vitidsant, Tharapong, 2017. "Characterization of carbon materials and differences from activated carbon particle (ACP) and coal briquettes product (CBP) derived from coconut shell via rotary kiln," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 1175-1186.
    10. Simoni, Marco & Wilkes, Mathew D. & Brown, Solomon & Provis, John L. & Kinoshita, Hajime & Hanein, Theodore, 2022. "Decarbonising the lime industry: State-of-the-art," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).

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