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A Raman spectroscopic approach to investigate the production of biodiesel from soybean oil using 1-alkyl-3-methylimidazolium ionic liquids with intermediate chain length

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  • Abrahamsson, Johanna
  • Andreasson, Emil
  • Hansson, Niklas
  • Sandström, David
  • Wennberg, Ellinor
  • Maréchal, Manuel
  • Martinelli, Anna

Abstract

We present a Raman spectroscopic study of the conversion of soybean oil into biodiesel by methanol using the lipase B enzyme pseudomonas cepacia as the bio-catalyst and 1-alkyl-3-methylimidazolium ionic liquids (CnC1Im) as co-solvents, where the alkyl chain length is varied from ethyl (n=2) to decyl (n=10). We have limited this study to a low reaction temperature, 40°C, and a low enzyme concentration to investigate the possibility of producing biodiesel with low energy and cost demands. We also demonstrate that Raman spectroscopy is a powerful and straightforward method to estimate the yield of the transesterification reaction, by analysis of the characteristic CO stretching mode found in the range ∼1730–1750cm−1. Our results indicate that both reaction yield and reaction rate increase with the chain length, but also that for chains longer than decyl further improvements are marginal. We discuss these results from the viewpoint of local interactions and local structure of the investigated ionic liquids.

Suggested Citation

  • Abrahamsson, Johanna & Andreasson, Emil & Hansson, Niklas & Sandström, David & Wennberg, Ellinor & Maréchal, Manuel & Martinelli, Anna, 2015. "A Raman spectroscopic approach to investigate the production of biodiesel from soybean oil using 1-alkyl-3-methylimidazolium ionic liquids with intermediate chain length," Applied Energy, Elsevier, vol. 154(C), pages 763-770.
    • Handle: RePEc:eee:appene:v:154:y:2015:i:c:p:763-770
    DOI: 10.1016/j.apenergy.2015.04.123
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    1. Mohammad Fauzi, Ahmad Hafiidz & Amin, Nor Aishah Saidina, 2012. "An overview of ionic liquids as solvents in biodiesel synthesis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5770-5786.
    2. Christopher, Lew P. & Hemanathan Kumar, & Zambare, Vasudeo P., 2014. "Enzymatic biodiesel: Challenges and opportunities," Applied Energy, Elsevier, vol. 119(C), pages 497-520.
    3. Li, Ji & Peng, Xiao & Luo, Meng & Zhao, Chun-Jian & Gu, Cheng-Bo & Zu, Yuan-Gang & Fu, Yu-Jie, 2014. "Biodiesel production from Camptotheca acuminata seed oil catalyzed by novel Brönsted–Lewis acidic ionic liquid," Applied Energy, Elsevier, vol. 115(C), pages 438-444.
    4. Liu, Chun-Zhao & Wang, Feng & Stiles, Amanda R. & Guo, Chen, 2012. "Ionic liquids for biofuel production: Opportunities and challenges," Applied Energy, Elsevier, vol. 92(C), pages 406-414.
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    1. Hosseini, Shokoufe & Moradi, G.R. & Bahrami, Kiumars, 2019. "Synthesis of a novel stabilized basic ionic liquid through immobilization on boehmite nanoparticles: A robust nanocatalyst for biodiesel production from soybean oil," Renewable Energy, Elsevier, vol. 138(C), pages 70-78.
    2. Dash, Archana & Banerjee, Rintu, 2021. "Exploring indigenously produced celite-immobilized Rhizopus oryzae NRRL 3562-lipase for biodiesel production," Energy, Elsevier, vol. 222(C).
    3. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    4. Gutiérrez-Arnillas, Esther & Álvarez, María S. & Deive, Francisco J. & Rodríguez, Ana & Sanromán, M. Ángeles, 2016. "New horizons in the enzymatic production of biodiesel using neoteric solvents," Renewable Energy, Elsevier, vol. 98(C), pages 92-100.
    5. Xu, Jun & Tang, Hao & Su, Sheng & Liu, Jiawei & Xu, Kai & Qian, Kun & Wang, Yi & Zhou, Yingbiao & Hu, Song & Zhang, Anchao & Xiang, Jun, 2018. "A study of the relationships between coal structures and combustion characteristics: The insights from micro-Raman spectroscopy based on 32 kinds of Chinese coals," Applied Energy, Elsevier, vol. 212(C), pages 46-56.
    6. Ibrahim, Muna Hassan & Hayyan, Maan & Hashim, Mohd Ali & Hayyan, Adeeb, 2017. "The role of ionic liquids in desulfurization of fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 1534-1549.

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