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Synthesis and performances of novel solid–solid phase change materials with hexahydroxy compounds for thermal energy storage

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  • Chen, Changzhong
  • Liu, Wenmin
  • Wang, Hongwei
  • Peng, Kelin

Abstract

Three kinds of new polymeric SSPCMs with different crosslinking structures were synthesized and characterized for thermal energy storage. In the SSPCMs, three hexahydroxy compounds (sorbitol, dipentaerythritol and inositol) were individually employed as the molecular skeleton and polyethylene glycol (PEG) was used as the phase change functional chain. The molecular structure, crystalline properties, phase change behaviors, thermal reliability and stability of the synthesized SSPCMs were investigated by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), differential scanning calorimetry (DSC) and thermogravimetry (TG), respectively. The results show that the prepared SSPCMs possess high thermal energy storage density and an applicable temperature range of 30–70°C, and the maximum phase change enthalpy in the heating and cooling process for the SSPCMs is 107.5kJ/kg and 102.9kJ/kg, respectively. The prepared SSPCMs have good reusability, excellent thermal reliability and stability from the heating-cooling thermal cycle test and TG curves. The resultant SSPCMs could be potentially applied in the areas of thermal energy storage and temperature-control.

Suggested Citation

  • Chen, Changzhong & Liu, Wenmin & Wang, Hongwei & Peng, Kelin, 2015. "Synthesis and performances of novel solid–solid phase change materials with hexahydroxy compounds for thermal energy storage," Applied Energy, Elsevier, vol. 152(C), pages 198-206.
    • Handle: RePEc:eee:appene:v:152:y:2015:i:c:p:198-206
    DOI: 10.1016/j.apenergy.2014.12.004
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    References listed on IDEAS

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    Cited by:

    1. Zhu, F.Q. & Jiang, L. & Wang, L.W. & Wang, R.Z., 2016. "Experimental investigation on a MnCl2CaCl2NH3 resorption system for heat and refrigeration cogeneration," Applied Energy, Elsevier, vol. 181(C), pages 29-37.
    2. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    3. Fu, Xiaowei & Lei, Yuan & Xiao, Yao & Wang, Jiliang & Zhou, Shiyi & Lei, Jingxin, 2021. "Graft poly(ethylene glycol)-based thermosetting phase change materials networks with ultrahigh encapsulation fraction and latent heat efficiency," Renewable Energy, Elsevier, vol. 179(C), pages 1076-1084.
    4. Nejad, Alireza Mahdavi, 2021. "A new drying approach deploying solid-solid phase change material: A numerical study," Energy, Elsevier, vol. 232(C).

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