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Graft poly(ethylene glycol)-based thermosetting phase change materials networks with ultrahigh encapsulation fraction and latent heat efficiency

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  • Fu, Xiaowei
  • Lei, Yuan
  • Xiao, Yao
  • Wang, Jiliang
  • Zhou, Shiyi
  • Lei, Jingxin

Abstract

Graft phase change materials (GPCMs) networks with pendent side chains of phase change component trend to simultaneously enhance the encapsulation fraction and latent heat efficiency, leading to ultrahigh latent heat, compared to backbone phase change materials (BPCMs) networks with skeleton chains of phase change component. Herein, the GPCMs networks containing graft polyethylene glycol (PEG)-based side chains were synthesized via a facile high efficiency esterification approach between hydroxyl and anhydride as well as between resulting carboxyl and aziridine ring. The GPCMs had much higher normalized latent heat (from 122.6 kJ/g to 157.6 kJ/g) and latent heat efficiency (from 0.76 to 0.93) than BPCMs (from 79.3 kJ/g to 130.6 kJ/g and from 0.49 to 0.77) networks counterparts with various molecular weight (from 2 kDa to 20 kDa) of used PEGs. Also, GPCMs could reach experimental latent heat of 155 J/g with ultrahigh PEG weight fraction of 98.8% and high latent heat efficiency of 0.93 resulting from the promoted crystallization, while GPCMs showed good solid-solid phase change behavior, high thermal reliability and stability, which could not be realized in conventional BPCMs. The synergetic enhancement of PEG weight fraction and latent heat efficiency in GPCMs is due to the decreased non-PEG components and the existence of free molecular end of PEGs in GPCMs. The efficient strategy of constructing graft side chains of PEGs can enable an obvious increase in both PEG weight fraction and latent heat efficiency in solid-solid PCMs network, further leading to a significant increase in latent heat.

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  • Fu, Xiaowei & Lei, Yuan & Xiao, Yao & Wang, Jiliang & Zhou, Shiyi & Lei, Jingxin, 2021. "Graft poly(ethylene glycol)-based thermosetting phase change materials networks with ultrahigh encapsulation fraction and latent heat efficiency," Renewable Energy, Elsevier, vol. 179(C), pages 1076-1084.
  • Handle: RePEc:eee:renene:v:179:y:2021:i:c:p:1076-1084
    DOI: 10.1016/j.renene.2021.07.102
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    1. Du, Xiaosheng & Qiu, Jinghong & Deng, Sha & Du, Zongliang & Cheng, Xu & Wang, Haibo, 2021. "Flame-retardant and solid-solid phase change composites based on dopamine-decorated BP nanosheets/Polyurethane for efficient solar-to-thermal energy storage," Renewable Energy, Elsevier, vol. 164(C), pages 1-10.
    2. Jiang, Liang & Lei, Yuan & Liu, Qinfeng & Lei, Jingxin, 2020. "Polyethylene glycol based self-luminous phase change materials for both thermal and light energy storage," Energy, Elsevier, vol. 193(C).
    3. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    4. Chen, Changzhong & Liu, Wenmin & Wang, Hongwei & Peng, Kelin, 2015. "Synthesis and performances of novel solid–solid phase change materials with hexahydroxy compounds for thermal energy storage," Applied Energy, Elsevier, vol. 152(C), pages 198-206.
    5. Chen, Xiaofei & Xiao, Jinmei & Yuan, Jiaqi & Xiao, Ziwei & Gang, Wenjie, 2021. "Application and performance analysis of 100% renewable energy systems serving low-density communities," Renewable Energy, Elsevier, vol. 176(C), pages 433-446.
    6. Dai, Jiasheng & Ma, Feng & Fu, Zhen & Li, Chen & Jia, Meng & Shi, Ke & Wen, Yalu & Wang, Wentong, 2021. "Applicability assessment of stearic acid/palmitic acid binary eutectic phase change material in cooling pavement," Renewable Energy, Elsevier, vol. 175(C), pages 748-759.
    7. Emam, Mohamed & Ookawara, Shinichi & Ahmed, Mahmoud, 2019. "Thermal management of electronic devices and concentrator photovoltaic systems using phase change material heat sinks: Experimental investigations," Renewable Energy, Elsevier, vol. 141(C), pages 322-339.
    8. Hansen, Kenneth & Breyer, Christian & Lund, Henrik, 2019. "Status and perspectives on 100% renewable energy systems," Energy, Elsevier, vol. 175(C), pages 471-480.
    9. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
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