IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v132y2014icp236-247.html
   My bibliography  Save this article

Mixture of glycerol ethers as diesel bio-derivable oxy-fuel: Impact on combustion and emissions of an automotive engine combustion system

Author

Listed:
  • Beatrice, Carlo
  • Di Blasio, Gabriele
  • Guido, Chiara
  • Cannilla, Catia
  • Bonura, Giuseppe
  • Frusteri, Francesco

Abstract

The effects on combustion and emissions of a bio-derivable glycerol-based ethers mixture (GEM) usable in a compression ignition engine have been investigated. The tests were performed on a single cylinder research engine derived from a Euro5 compliant four cylinder engine for passenger car application. The experimental methodology has considered the comparison among three fuels: (1) a reference diesel; (2) a mixture consisting of 90vol.% diesel and 10vol.% of GEM; (3) a blend consisting of 80vol.% diesel and 20vol.% of GEM. The tests were carried out in some characteristic key points of the New European Driving Cycle (NEDC) emission homologation cycle. These points allowed an estimation of the blend impact on the performance of a real four-cylinder engine (one cylinder of which is represented by the research engine) over the NEDC. Both regulated and unregulated pollutant emissions have been measured during the test campaign. In particular, apart from the regulated emissions, the concentration of aldehydes and carbonaceous particles at the engine exhaust has been determined in some test points. The results have shown the possibility to burn the diesel/GEM blends without any significant impact on combustion characteristics and efficiencies, while, due to the oxygen content of the GEM, important benefits were obtained in terms of NOx-PM trade-off and emissions of particles at the exhaust. At medium–high load conditions, there was a maximum decrease of about 70% in terms of PM emissions compared to a slight increase of NOx. At low load conditions, a maximum increase of HC and CO of about 50% has been detected. Regarding the emissions of aldehydes, the results showed that the GEM addition favoured the increasing of carbonyl compounds at low engine loads, while at higher loads no significant variation has been detected by burning GEM.

Suggested Citation

  • Beatrice, Carlo & Di Blasio, Gabriele & Guido, Chiara & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco, 2014. "Mixture of glycerol ethers as diesel bio-derivable oxy-fuel: Impact on combustion and emissions of an automotive engine combustion system," Applied Energy, Elsevier, vol. 132(C), pages 236-247.
    • Handle: RePEc:eee:appene:v:132:y:2014:i:c:p:236-247
    DOI: 10.1016/j.apenergy.2014.07.006
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261914006734
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2014.07.006?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Rahmat, Norhasyimi & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2010. "Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 987-1000, April.
    2. Beatrice, Carlo & Di Blasio, Gabriele & Lazzaro, Maurizio & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco & Asdrubali, Francesco & Baldinelli, Giorgio & Presciutti, Andrea & Fantozzi, Franc, 2013. "Technologies for energetic exploitation of biodiesel chain derived glycerol: Oxy-fuels production by catalytic conversion," Applied Energy, Elsevier, vol. 102(C), pages 63-71.
    3. Hamelinck, Carlo N & Faaij, Andre P.C., 2006. "Outlook for advanced biofuels," Energy Policy, Elsevier, vol. 34(17), pages 3268-3283, November.
    4. Aleklett, Kjell & Höök, Mikael & Jakobsson, Kristofer & Lardelli, Michael & Snowden, Simon & Söderbergh, Bengt, 2010. "The Peak of the Oil Age - Analyzing the world oil production Reference Scenario in World Energy Outlook 2008," Energy Policy, Elsevier, vol. 38(3), pages 1398-1414, March.
    5. Vlysidis, Anestis & Binns, Michael & Webb, Colin & Theodoropoulos, Constantinos, 2011. "A techno-economic analysis of biodiesel biorefineries: Assessment of integrated designs for the co-production of fuels and chemicals," Energy, Elsevier, vol. 36(8), pages 4671-4683.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Stanislaw Szwaja & Michal Gruca & Michal Pyrc & Romualdas Juknelevičius, 2021. "Performance and Exhaust Emissions of a Spark Ignition Internal Combustion Engine Fed with Butanol–Glycerol Blend," Energies, MDPI, vol. 14(20), pages 1-15, October.
    2. Sidhu, Manpreet Singh & Roy, Murari Mohon & Wang, Wilson, 2018. "Glycerine emulsions of diesel-biodiesel blends and their performance and emissions in a diesel engine," Applied Energy, Elsevier, vol. 230(C), pages 148-159.
    3. Francesco Asdrubali & Franco Cotana & Federico Rossi & Andrea Presciutti & Antonella Rotili & Claudia Guattari, 2015. "Life Cycle Assessment of New Oxy-Fuels from Biodiesel-Derived Glycerol," Energies, MDPI, vol. 8(3), pages 1-16, February.
    4. Singh, Paramvir & Varun, & Chauhan, S.R., 2016. "Carbonyl and aromatic hydrocarbon emissions from diesel engine exhaust using different feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 269-291.
    5. Kumbhar, Vishal & Pandey, Anand & Sonawane, Chandrakant R. & Panchal, Hitesh & Ağbulut, Ümit, 2023. "Numerical and experimental investigation of the influence of various metal-oxide-based nanoparticles on performance, combustion, and emissions of CI engine fuelled with tamarind seed oil methyl ester," Energy, Elsevier, vol. 265(C).
    6. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    7. Fantozzi, F. & Frassoldati, A. & Bartocci, P. & Cinti, G. & Quagliarini, F. & Bidini, G. & Ranzi, E.M., 2016. "An experimental and kinetic modeling study of glycerol pyrolysis," Applied Energy, Elsevier, vol. 184(C), pages 68-76.
    8. Mwangi, John Kennedy & Lee, Wen-Jhy & Chang, Yu-Cheng & Chen, Chia-Yang & Wang, Lin-Chi, 2015. "An overview: Energy saving and pollution reduction by using green fuel blends in diesel engines," Applied Energy, Elsevier, vol. 159(C), pages 214-236.
    9. Jia, Guangxin & He, Beibei & Ma, Wenlin & Sun, Yifan, 2019. "Thermodynamic analysis based on simultaneous chemical and phase equilibrium for dehydration of glycerol with methanol," Energy, Elsevier, vol. 188(C).
    10. Michal Gruca & Michal Pyrc & Magdalena Szwaja & Stanislaw Szwaja, 2020. "Effective Combustion of Glycerol in a Compression Ignition Engine Equipped with Double Direct Fuel Injection," Energies, MDPI, vol. 13(23), pages 1-14, December.
    11. Lapuerta, Magín & Rodríguez-Fernández, José & García-Contreras, Reyes, 2015. "Effect of a glycerol-derived advanced biofuel –FAGE (fatty acid formal glycerol ester)– on the emissions of a diesel engine tested under the New European Driving Cycle," Energy, Elsevier, vol. 93(P1), pages 568-579.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Francesco Asdrubali & Franco Cotana & Federico Rossi & Andrea Presciutti & Antonella Rotili & Claudia Guattari, 2015. "Life Cycle Assessment of New Oxy-Fuels from Biodiesel-Derived Glycerol," Energies, MDPI, vol. 8(3), pages 1-16, February.
    2. Rafael Estevez & Laura Aguado-Deblas & Diego Luna & Felipa M. Bautista, 2019. "An Overview of the Production of Oxygenated Fuel Additives by Glycerol Etherification, Either with Isobutene or tert -Butyl Alcohol, over Heterogeneous Catalysts," Energies, MDPI, vol. 12(12), pages 1-20, June.
    3. Hunsom, Mali & Saila, Payia, 2015. "Electrochemical conversion of enriched crude glycerol: Effect of operating parameters," Renewable Energy, Elsevier, vol. 74(C), pages 227-236.
    4. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    5. Hoefnagels, Ric & Banse, Martin & Dornburg, Veronika & Faaij, André, 2013. "Macro-economic impact of large-scale deployment of biomass resources for energy and materials on a national level—A combined approach for the Netherlands," Energy Policy, Elsevier, vol. 59(C), pages 727-744.
    6. Bogdanov, Dmitrii & Breyer, Christian, 2024. "Role of smart charging of electric vehicles and vehicle-to-grid in integrated renewables-based energy systems on country level," Energy, Elsevier, vol. 301(C).
    7. Beatrice, Carlo & Di Blasio, Gabriele & Lazzaro, Maurizio & Cannilla, Catia & Bonura, Giuseppe & Frusteri, Francesco & Asdrubali, Francesco & Baldinelli, Giorgio & Presciutti, Andrea & Fantozzi, Franc, 2013. "Technologies for energetic exploitation of biodiesel chain derived glycerol: Oxy-fuels production by catalytic conversion," Applied Energy, Elsevier, vol. 102(C), pages 63-71.
    8. Yee, Kian Fei & Mohamed, Abdul Rahman & Tan, Soon Huat, 2013. "A review on the evolution of ethyl tert-butyl ether (ETBE) and its future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 604-620.
    9. Geraili, A. & Sharma, P. & Romagnoli, J.A., 2014. "Technology analysis of integrated biorefineries through process simulation and hybrid optimization," Energy, Elsevier, vol. 73(C), pages 145-159.
    10. Amela Ajanovic & Gerfried Jungmeier & Martin Beermann & Reinhard Haas, 2012. "The Long-Term Prospects of Biofuels in the EU-15 Countries," Energies, MDPI, vol. 5(8), pages 1-16, August.
    11. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    12. Bauer, Fredric & Hulteberg, Christian, 2014. "Isobutanol from glycerine – A techno-economic evaluation of a new biofuel production process," Applied Energy, Elsevier, vol. 122(C), pages 261-268.
    13. van Vliet, Oscar & van den Broek, Machteld & Turkenburg, Wim & Faaij, André, 2011. "Combining hybrid cars and synthetic fuels with electricity generation and carbon capture and storage," Energy Policy, Elsevier, vol. 39(1), pages 248-268, January.
    14. Antonakakis, Nikolaos & Chatziantoniou, Ioannis & Filis, George, 2017. "Oil shocks and stock markets: Dynamic connectedness under the prism of recent geopolitical and economic unrest," International Review of Financial Analysis, Elsevier, vol. 50(C), pages 1-26.
    15. Chang, Yue & Jia, Yulong & Hong, Tan, 2023. "Comprehensive analysis and multi-objective optimization of an innovative power generation system using biomass gasification and LNG regasification processes," Energy, Elsevier, vol. 283(C).
    16. Navas-Anguita, Zaira & García-Gusano, Diego & Iribarren, Diego, 2019. "A review of techno-economic data for road transportation fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 11-26.
    17. Sathre, Roger & Gustavsson, Leif, 2009. "Process-based analysis of added value in forest product industries," Forest Policy and Economics, Elsevier, vol. 11(1), pages 65-75, January.
    18. Kovacevic, Vujadin & Wesseler, Justus, 2010. "Cost-effectiveness analysis of algae energy production in the EU," Energy Policy, Elsevier, vol. 38(10), pages 5749-5757, October.
    19. Kim, Tae-Hyoung & Lee, Kyungho & Oh, Baek-Rock & Lee, Mi-Eun & Seo, Minji & Li, Sheng & Kim, Jae-Kon & Choi, Minkee & Chang, Yong Keun, 2021. "A novel process for the coproduction of biojet fuel and high-value polyunsaturated fatty acid esters from heterotrophic microalgae Schizochytrium sp. ABC101," Renewable Energy, Elsevier, vol. 165(P1), pages 481-490.
    20. Hellsmark, Hans & Jacobsson, Staffan, 2012. "Realising the potential of gasified biomass in the European Union—Policy challenges in moving from demonstration plants to a larger scale diffusion," Energy Policy, Elsevier, vol. 41(C), pages 507-518.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:132:y:2014:i:c:p:236-247. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.