IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v130y2014icp350-356.html
   My bibliography  Save this article

Combustion of propane with Pt and Rh catalysts in a meso-scale heat recirculating combustor

Author

Listed:
  • Wierzbicki, Teresa A.
  • Lee, Ivan C.
  • Gupta, Ashwani K.

Abstract

The results obtained from the combustion behavior of propane over platinum and rhodium catalysts in a meso-scale heat recirculating combustor are presented. The extinction limits, conversion, product selectivity/yield, and activation energy using the two catalysts were compared in an effort to predict their performance using a liquid fuel. The extinction limits were also compared to those of non-catalytic combustion in the same combustor. The results showed that the use of a catalyst greatly expanded the range of stable operating conditions, in terms of both extinction limits and flow rates supported. The Rh catalyst was found to exhibit a higher propane conversion rate, reaching a maximum of 90.4% at stoichiometric conditions (as compared to only 61.4% offered by the Pt catalyst under lean conditions), but the Pt catalyst had superior CO2 selectivity for most of the examined conditions, indicating more of the heat released being used for product formation as opposed to being lost to the environment. However, despite having a higher rate of heat loss, the combustion with the Rh catalyst produced an overall higher amount of enthalpy than the Pt due to its superior fuel conversion. The Pt catalyst also had a significantly smaller activation energy (13.8kJ/mol) than the Rh catalyst (74.7kJ/mol), except at equivalence ratios richer than Φ=1.75 (corresponding to catalyst temperatures below 500°C), where it abruptly changed to 211.4kJ/mol, signifying a transition from diffusion-limited reactions to kinetically limited reactions at this point. The results reveal that Rh would be a more suitable catalyst for use in liquid-fueled meso-scale combustors, as fuel conversion has been found to be a limiting factor for combustion stability in these systems, and as its higher output energy allows for greater flexibility of use.

Suggested Citation

  • Wierzbicki, Teresa A. & Lee, Ivan C. & Gupta, Ashwani K., 2014. "Combustion of propane with Pt and Rh catalysts in a meso-scale heat recirculating combustor," Applied Energy, Elsevier, vol. 130(C), pages 350-356.
    • Handle: RePEc:eee:appene:v:130:y:2014:i:c:p:350-356
    DOI: 10.1016/j.apenergy.2014.05.069
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261914005741
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2014.05.069?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Shirsat, V. & Gupta, A.K., 2011. "Performance characteristics of methanol and kerosene fuelled meso-scale heat-recirculating combustors," Applied Energy, Elsevier, vol. 88(12), pages 5069-5082.
    2. Vijayan, V. & Gupta, A.K., 2010. "Combustion and heat transfer at meso-scale with thermal recuperation," Applied Energy, Elsevier, vol. 87(8), pages 2628-2639, August.
    3. Wierzbicki, Teresa A. & Lee, Ivan C. & Gupta, Ashwani K., 2014. "Performance of synthetic jet fuels in a meso-scale heat recirculating combustor," Applied Energy, Elsevier, vol. 118(C), pages 41-47.
    4. Vijayan, V. & Gupta, A.K., 2011. "Thermal performance of a meso-scale liquid-fuel combustor," Applied Energy, Elsevier, vol. 88(7), pages 2335-2343, July.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Baigmohammadi, Mohammadreza & Tabejamaat, Sadegh & Faghani-Lamraski, Morteza, 2017. "Experimental study on the effects of mixture flow rate, equivalence ratio, oxygen enhancement, and geometrical parameters on propane-air premixed flame dynamics in non-adiabatic meso-scale reactors," Energy, Elsevier, vol. 121(C), pages 657-675.
    2. Merotto, L. & Fanciulli, C. & Dondè, R. & De Iuliis, S., 2016. "Study of a thermoelectric generator based on a catalytic premixed meso-scale combustor," Applied Energy, Elsevier, vol. 162(C), pages 346-353.
    3. Yan, Yunfei & Liu, Ying & Li, Lixian & Cui, Yu & Zhang, Li & Yang, Zhongqing & Zhang, Zhien, 2019. "Numerical comparison of H2/air catalytic combustion characteristic of micro–combustors with a conventional, slotted or controllable slotted bluff body," Energy, Elsevier, vol. 189(C).
    4. Tang, Aikun & Cai, Tao & Deng, Jiang & Zhao, Dan & Huang, Qiuhan & Zhou, Chen, 2019. "Experimental study on flame structure transitions of premixed propane/air in micro-scale planar combustors," Energy, Elsevier, vol. 179(C), pages 558-570.
    5. Fanciulli, C. & Abedi, H. & Merotto, L. & Dondè, R. & De Iuliis, S. & Passaretti, F., 2018. "Portable thermoelectric power generation based on catalytic combustor for low power electronic equipment," Applied Energy, Elsevier, vol. 215(C), pages 300-308.
    6. Peng, Qingguo & Wu, Yifeng & E, Jiaqiang & Yang, Wenming & Xu, Hongpeng & Li, Zhenwei, 2019. "Combustion characteristics and thermal performance of premixed hydrogen-air in a two-rearward-step micro tube," Applied Energy, Elsevier, vol. 242(C), pages 424-438.
    7. Zhang, Xiaolei & Hu, Longhua & Delichatsios, Michael A. & Zhang, Jianping, 2019. "Experimental study on flame morphologic characteristics of wall attached non-premixed buoyancy driven turbulent flames," Applied Energy, Elsevier, vol. 254(C).
    8. Deng, Daxiang & Xie, Yanlin & Chen, Liang & Pi, Guang & Huang, Yue, 2019. "Experimental investigation on thermal and combustion performance of a combustor with microchannel cooling," Energy, Elsevier, vol. 181(C), pages 954-963.
    9. Wierzbicki, Teresa A. & Lee, Ivan C. & Gupta, Ashwani K., 2015. "Rh assisted catalytic oxidation of jet fuel surrogates in a meso-scale combustor," Applied Energy, Elsevier, vol. 145(C), pages 1-7.
    10. Tang, Aikun & Deng, Jiang & Cai, Tao & Xu, Yiming & Pan, Jianfeng, 2017. "Combustion characteristics of premixed propane/hydrogen/air in the micro-planar combustor with different channel-heights," Applied Energy, Elsevier, vol. 203(C), pages 635-642.
    11. Seyed Ehsan Hosseini & Evan Owens & John Krohn & James Leylek, 2018. "Experimental Investigation into the Effects of Thermal Recuperation on the Combustion Characteristics of a Non-Premixed Meso-Scale Vortex Combustor," Energies, MDPI, vol. 11(12), pages 1-16, December.
    12. Jiaqiang, E. & Zuo, Wei & Liu, Xueling & Peng, Qingguo & Deng, Yuanwang & Zhu, Hao, 2016. "Effects of inlet pressure on wall temperature and exergy efficiency of the micro-cylindrical combustor with a step," Applied Energy, Elsevier, vol. 175(C), pages 337-345.
    13. Yi Ma & Wenhua Yuan & Shaomin Zhao & Hongru Fang, 2024. "Premixed Combustion Characteristics of Hydrogen/Air in a Micro-Cylindrical Combustor with Double Ribs," Energies, MDPI, vol. 17(20), pages 1-21, October.
    14. Tan, Yan & E, Jiaqiang & Chen, Jingwei & Liao, Gaoliang & Zhang, Feng & Li, Jintao, 2022. "Investigation on combustion characteristics and thermal performance of a three rearward-step structure micro combustor fueled by premixed hydrogen/air," Renewable Energy, Elsevier, vol. 186(C), pages 486-504.
    15. Aravind, B. & Khandelwal, Bhupendra & Kumar, Sudarshan, 2018. "Experimental investigations on a new high intensity dual microcombustor based thermoelectric micropower generator," Applied Energy, Elsevier, vol. 228(C), pages 1173-1181.
    16. Li, Yanxia & Luo, Chaoming & Liu, Zhongliang & Sang, Lixia, 2015. "Catalytic oxidation characteristics of CH4–air mixtures over metal foam monoliths," Applied Energy, Elsevier, vol. 156(C), pages 756-761.
    17. Zuo, Wei & E, Jiaqiang & Liu, Haili & Peng, Qingguo & Zhao, Xiaohuan & Zhang, Zhiqing, 2016. "Numerical investigations on an improved micro-cylindrical combustor with rectangular rib for enhancing heat transfer," Applied Energy, Elsevier, vol. 184(C), pages 77-87.
    18. Aravind, B. & Khandelwal, Bhupendra & Ramakrishna, P.A. & Kumar, Sudarshan, 2020. "Towards the development of a high power density, high efficiency, micro power generator," Applied Energy, Elsevier, vol. 261(C).
    19. Zuo, Wei & E, Jiaqiang & Peng, Qingguo & Zhao, Xiaohuan & Zhang, Zhiqing, 2017. "Numerical investigations on a comparison between counterflow and coflow double-channel micro combustors for micro-thermophotovoltaic system," Energy, Elsevier, vol. 122(C), pages 408-419.
    20. Cai, Tao & Tang, Aikun & Zhao, Dan & Zhou, Chen & Huang, Qiuhan, 2020. "Flame dynamics and stability of premixed methane/air in micro-planar quartz combustors," Energy, Elsevier, vol. 193(C).
    21. Akhtar, Saad & Khan, Mohammed N. & Kurnia, Jundika C. & Shamim, Tariq, 2017. "Investigation of energy conversion and flame stability in a curved micro-combustor for thermo-photovoltaic (TPV) applications," Applied Energy, Elsevier, vol. 192(C), pages 134-145.
    22. Zuo, Wei & E, Jiaqiang & Hu, Wenyu & Jin, Yu & Han, Dandan, 2017. "Numerical investigations on combustion characteristics of H2/air premixed combustion in a micro elliptical tube combustor," Energy, Elsevier, vol. 126(C), pages 1-12.
    23. Jinshen Tong & Tao Cai, 2022. "Enhancing Thermal Performance, Exergy and Thermodynamics Efficiency of Premixed Methane/Air Micro-Planar Combustor in Micro-Thermophotovoltaic Systems," Energies, MDPI, vol. 16(1), pages 1-21, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jiaqiang, E. & Zuo, Wei & Liu, Xueling & Peng, Qingguo & Deng, Yuanwang & Zhu, Hao, 2016. "Effects of inlet pressure on wall temperature and exergy efficiency of the micro-cylindrical combustor with a step," Applied Energy, Elsevier, vol. 175(C), pages 337-345.
    2. Zuo, Wei & E, Jiaqiang & Hu, Wenyu & Jin, Yu & Han, Dandan, 2017. "Numerical investigations on combustion characteristics of H2/air premixed combustion in a micro elliptical tube combustor," Energy, Elsevier, vol. 126(C), pages 1-12.
    3. Akhtar, Saad & Khan, Mohammed N. & Kurnia, Jundika C. & Shamim, Tariq, 2017. "Investigation of energy conversion and flame stability in a curved micro-combustor for thermo-photovoltaic (TPV) applications," Applied Energy, Elsevier, vol. 192(C), pages 134-145.
    4. Wierzbicki, Teresa A. & Lee, Ivan C. & Gupta, Ashwani K., 2015. "Rh assisted catalytic oxidation of jet fuel surrogates in a meso-scale combustor," Applied Energy, Elsevier, vol. 145(C), pages 1-7.
    5. Tang, Aikun & Deng, Jiang & Cai, Tao & Xu, Yiming & Pan, Jianfeng, 2017. "Combustion characteristics of premixed propane/hydrogen/air in the micro-planar combustor with different channel-heights," Applied Energy, Elsevier, vol. 203(C), pages 635-642.
    6. Zuo, Wei & E, Jiaqiang & Liu, Haili & Peng, Qingguo & Zhao, Xiaohuan & Zhang, Zhiqing, 2016. "Numerical investigations on an improved micro-cylindrical combustor with rectangular rib for enhancing heat transfer," Applied Energy, Elsevier, vol. 184(C), pages 77-87.
    7. Wierzbicki, Teresa A. & Lee, Ivan C. & Gupta, Ashwani K., 2014. "Performance of synthetic jet fuels in a meso-scale heat recirculating combustor," Applied Energy, Elsevier, vol. 118(C), pages 41-47.
    8. Zuo, Wei & E, Jiaqiang & Peng, Qingguo & Zhao, Xiaohuan & Zhang, Zhiqing, 2017. "Numerical investigations on a comparison between counterflow and coflow double-channel micro combustors for micro-thermophotovoltaic system," Energy, Elsevier, vol. 122(C), pages 408-419.
    9. Merotto, L. & Fanciulli, C. & Dondè, R. & De Iuliis, S., 2016. "Study of a thermoelectric generator based on a catalytic premixed meso-scale combustor," Applied Energy, Elsevier, vol. 162(C), pages 346-353.
    10. Shirsat, V. & Gupta, A.K., 2011. "A review of progress in heat recirculating meso-scale combustors," Applied Energy, Elsevier, vol. 88(12), pages 4294-4309.
    11. Peng, Qingguo & Yang, Wenming & E, Jiaqiang & Li, Shaobo & Li, Zhenwei & Xu, Hongpeng & Fu, Guang, 2021. "Effects of propane addition and burner scale on the combustion characteristics and working performance," Applied Energy, Elsevier, vol. 285(C).
    12. Akhtar, Saad & Kurnia, Jundika C. & Shamim, Tariq, 2015. "A three-dimensional computational model of H2–air premixed combustion in non-circular micro-channels for a thermo-photovoltaic (TPV) application," Applied Energy, Elsevier, vol. 152(C), pages 47-57.
    13. Peng, Qingguo & Yang, Wenming & E, Jiaqiang & Xu, Hongpeng & Li, Zhenwei & Tay, Kunlin & Zeng, Guang & Yu, Wenbin, 2020. "Investigation on premixed H2/C3H8/air combustion in porous medium combustor for the micro thermophotovoltaic application," Applied Energy, Elsevier, vol. 260(C).
    14. Zhao, Zhengyang & Wang, Wei & Zuo, Zhengxing & Kuang, Nianling, 2022. "Investigation on the flame characteristics of premixed propane/air in a micro opposed flow porous combustor," Energy, Elsevier, vol. 238(PA).
    15. Shirsat, V. & Gupta, A.K., 2013. "Extinction, discharge, and thrust characteristics of methanol fueled meso-scale thrust chamber," Applied Energy, Elsevier, vol. 103(C), pages 375-392.
    16. Wang, Wei & Zuo, Zhengxing & Liu, Jinxiang, 2019. "Numerical study of the premixed propane/air flame characteristics in a partially filled micro porous combustor," Energy, Elsevier, vol. 167(C), pages 902-911.
    17. Aravind, B. & Khandelwal, Bhupendra & Kumar, Sudarshan, 2018. "Experimental investigations on a new high intensity dual microcombustor based thermoelectric micropower generator," Applied Energy, Elsevier, vol. 228(C), pages 1173-1181.
    18. Vinay Sankar & Sreejith Sudarsanan & Sudipto Mukhopadhyay & Prabhu Selvaraj & Aravind Balakrishnan & Ratna Kishore Velamati, 2023. "Towards the Development of Miniature Scale Liquid Fuel Combustors for Power Generation Application—A Review," Energies, MDPI, vol. 16(10), pages 1-41, May.
    19. Sun, Yuze & Rao, Zhuming & Zhao, Dan & Wang, Bing & Sun, Dakun & Sun, Xiaofeng, 2020. "Characterizing nonlinear dynamic features of self-sustained thermoacoustic oscillations in a premixed swirling combustor," Applied Energy, Elsevier, vol. 264(C).
    20. Aravind, B. & Khandelwal, Bhupendra & Ramakrishna, P.A. & Kumar, Sudarshan, 2020. "Towards the development of a high power density, high efficiency, micro power generator," Applied Energy, Elsevier, vol. 261(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:130:y:2014:i:c:p:350-356. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.