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A mathematical model to study the performance of a proton exchange membrane fuel cell in a dead-ended anode mode

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  • Yang, Chih-Wei
  • Chen, Yong-Song

Abstract

When a proton exchange membrane fuel cell (PEMFC) system is operated in the dead-ended anode mode, nitrogen will gradually permeate from the cathode to the anode. The accumulation of nitrogen in the anode causes a performance drop, which can be recovered by purging. The purge strategy depends on operating conditions of the PEMFC. To investigate the effect of operating conditions on the performance of a PEMFC with a dead-ended anode, a mathematical model is developed to estimate the nitrogen crossover and accumulation in the anode of the PEMFC, especially for varying-load operations. The effect of operating current density on nitrogen crossover is coupled in the model. Parameters in the model are calibrated according to experimental data. The experiments are designed to measure the voltage variations of the single cell with dead-ended anode at different operating current densities. The effect of current density on purge frequency and voltage variation is shown. Simulation results by this calibrated model agree well with experimental data. The transient of hydrogen concentration in the anode is investigated by the model. A purge strategy is suggested at the end of this study.

Suggested Citation

  • Yang, Chih-Wei & Chen, Yong-Song, 2014. "A mathematical model to study the performance of a proton exchange membrane fuel cell in a dead-ended anode mode," Applied Energy, Elsevier, vol. 130(C), pages 113-121.
    • Handle: RePEc:eee:appene:v:130:y:2014:i:c:p:113-121
    DOI: 10.1016/j.apenergy.2014.05.010
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    1. Chen, Yong-Song & Yang, Chih-Wei & Lee, Jiunn-Yih, 2014. "Implementation and evaluation for anode purging of a fuel cell based on nitrogen concentration," Applied Energy, Elsevier, vol. 113(C), pages 1519-1524.
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    1. Ettihir, K. & Boulon, L. & Agbossou, K., 2016. "Optimization-based energy management strategy for a fuel cell/battery hybrid power system," Applied Energy, Elsevier, vol. 163(C), pages 142-153.
    2. Wang, Bowen & Deng, Hao & Jiao, Kui, 2018. "Purge strategy optimization of proton exchange membrane fuel cell with anode recirculation," Applied Energy, Elsevier, vol. 225(C), pages 1-13.
    3. Dashti, Isar & Asghari, Saeed & Goudarzi, Mohammad & Meyer, Quentin & Mehrabani-Zeinabad, Arjomand & Brett, Dan J.L., 2019. "Optimization of the performance, operation conditions and purge rate for a dead-ended anode proton exchange membrane fuel cell using an analytical model," Energy, Elsevier, vol. 179(C), pages 173-185.
    4. Jang, Jer-Huan & Yan, Wei-Mon & Chiu, Han-Chieh & Lui, Jun-Yi, 2015. "Dynamic cell performance of kW-grade proton exchange membrane fuel cell stack with dead-ended anode," Applied Energy, Elsevier, vol. 142(C), pages 108-114.
    5. Barzegari, Mohammad M. & Dardel, Morteza & Alizadeh, Ebrahim & Ramiar, Abas, 2016. "Dynamic modeling and validation studies of dead-end cascade H2/O2 PEM fuel cell stack with integrated humidifier and separator," Applied Energy, Elsevier, vol. 177(C), pages 298-308.
    6. Teresa Donateo, 2023. "Semi-Empirical Models for Stack and Balance of Plant in Closed-Cathode Fuel Cell Systems for Aviation," Energies, MDPI, vol. 16(22), pages 1-40, November.
    7. Xu, Liangfei & Fang, Chuan & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2018. "Nonlinear dynamic mechanism modeling of a polymer electrolyte membrane fuel cell with dead-ended anode considering mass transport and actuator properties," Applied Energy, Elsevier, vol. 230(C), pages 106-121.
    8. Tsai, Shang-Wen & Chen, Yong-Song, 2017. "A mathematical model to study the energy efficiency of a proton exchange membrane fuel cell with a dead-ended anode," Applied Energy, Elsevier, vol. 188(C), pages 151-159.
    9. Chen, Ben & Ke, Wandi & Luo, Maji & Wang, Jun & Tu, Zhengkai & Pan, Mu & Zhang, Haining & Liu, Xiaowei & Liu, Wei, 2015. "Operation characteristics and carbon corrosion of PEMFC (Proton exchange membrane fuel cell) with dead-ended anode for high hydrogen utilization," Energy, Elsevier, vol. 91(C), pages 799-806.
    10. Teresa Donateo, 2024. "Simulation Approaches and Validation Issues for Open-Cathode Fuel Cell Systems in Manned and Unmanned Aerial Vehicles," Energies, MDPI, vol. 17(4), pages 1-38, February.
    11. Liu, Shihua & Chen, Tao & Zhang, Cheng & Xie, Yi, 2020. "Study on the performance of proton exchange membrane fuel cell (PEMFC) with dead-ended anode in gravity environment," Applied Energy, Elsevier, vol. 261(C).
    12. Myo-Eun Kim & Young-Jun Sohn, 2020. "Study on Polymer Electrolyte Fuel Cells with Nonhumidification Using Metal Foam in Dead-Ended Operation," Energies, MDPI, vol. 13(5), pages 1-12, March.

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