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A hot syngas purification system integrated with downdraft gasification of municipal solid waste

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  • Chan, Wei Ping
  • Veksha, Andrei
  • Lei, Junxi
  • Oh, Wen-Da
  • Dou, Xiaomin
  • Giannis, Apostolos
  • Lisak, Grzegorz
  • Lim, Teik-Thye

Abstract

Gasification of municipal solid waste (MSW) with subsequent utilization of syngas in gas engines/turbines and solid oxide fuel cells can substantially increase the power generation of waste-to-energy facilities and optimize the utilization of wastes as a sustainable energy resources. However, purification of syngas to remove multiple impurities such as particulates, tar, HCl, alkali chlorides and sulfur species is required. This study investigates the feasibility of high temperature purification of syngas from MSW gasification with the focus on catalytic tar reforming and desulfurization. Syngas produced from a downdraft fixed-bed gasifier is purified by a multi-stage system. The system comprises of a fluidized-bed catalytic tar reformer, a filter for particulates and a fixed-bed reactor for dechlorination and then desulfurization with overall downward cascading of the operating temperatures throughout the system. Novel nano-structured nickel catalyst supported on alumina and regenerable Ni-Zn desulfurization sorbent loaded on honeycomb are synthesized. Complementary sampling and analysis methods are applied to quantify the impurities and determine their distribution at different stages. Experimental and thermodynamic modeling results are compared to determine the kinetic constraints in the integrated system. The hot purification system demonstrates up to 90% of tar and sulfur removal efficiency, increased total syngas yield (14%) and improved cold gas efficiency (12%). The treated syngas is potentially applicable in gas engines/turbines and solid oxide fuel cells based on the dew points and concentration limits of the remaining tar compounds. Reforming of raw syngas by nickel catalyst for over 20 h on stream shows strong resistance to deactivation. Desulfurization of syngas from MSW gasification containing significantly higher proportion of carbonyl sulfide than hydrogen sulfide, traces of tar and hydrogen chloride demonstrates high performance of Ni-Zn sorbents.

Suggested Citation

  • Chan, Wei Ping & Veksha, Andrei & Lei, Junxi & Oh, Wen-Da & Dou, Xiaomin & Giannis, Apostolos & Lisak, Grzegorz & Lim, Teik-Thye, 2019. "A hot syngas purification system integrated with downdraft gasification of municipal solid waste," Applied Energy, Elsevier, vol. 237(C), pages 227-240.
    • Handle: RePEc:eee:appene:v:237:y:2019:i:c:p:227-240
    DOI: 10.1016/j.apenergy.2019.01.031
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    1. Shen, Yafei, 2015. "Chars as carbonaceous adsorbents/catalysts for tar elimination during biomass pyrolysis or gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 281-295.
    2. Zhang, Zhikun & Liu, Lina & Shen, Boxiong & Wu, Chunfei, 2018. "Preparation, modification and development of Ni-based catalysts for catalytic reforming of tar produced from biomass gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 1086-1109.
    3. Azizi, Mohammad Ali & Brouwer, Jacob, 2018. "Progress in solid oxide fuel cell-gas turbine hybrid power systems: System design and analysis, transient operation, controls and optimization," Applied Energy, Elsevier, vol. 215(C), pages 237-289.
    4. Shen, Yafei & Yoshikawa, Kunio, 2013. "Recent progresses in catalytic tar elimination during biomass gasification or pyrolysis—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 371-392.
    5. Giuffrida, A. & Bonalumi, D. & Lozza, G., 2013. "Amine-based post-combustion CO2 capture in air-blown IGCC systems with cold and hot gas clean-up," Applied Energy, Elsevier, vol. 110(C), pages 44-54.
    6. Shen, Yafei & Zhao, Peitao & Shao, Qinfu & Takahashi, Fumitake & Yoshikawa, Kunio, 2015. "In situ catalytic conversion of tar using rice husk char/ash supported nickel–iron catalysts for biomass pyrolytic gasification combined with the mixing-simulation in fluidized-bed gasifier," Applied Energy, Elsevier, vol. 160(C), pages 808-819.
    7. Dragos Neagu & Tae-Sik Oh & David N. Miller & Hervé Ménard & Syed M. Bukhari & Stephen R. Gamble & Raymond J. Gorte & John M. Vohs & John T.S. Irvine, 2015. "Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    8. Rakesh N, & Dasappa, S., 2018. "A critical assessment of tar generated during biomass gasification - Formation, evaluation, issues and mitigation strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1045-1064.
    9. Baskoro Lokahita, & Muhammad Aziz, & Yoshikawa, Kunio & Takahashi, Fumitake, 2017. "Energy and resource recovery from Tetra Pak waste using hydrothermal treatment," Applied Energy, Elsevier, vol. 207(C), pages 107-113.
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    2. Li, Sarengaowa & Chen, Heng & Yuan, Xin & Pan, Peiyuan & Xu, Gang & Wang, Xiuyan & Wu, Lining, 2024. "Energy, exergy and economic analysis of a poly-generation system combining sludge pyrolysis and medical waste plasma gasification," Energy, Elsevier, vol. 295(C).
    3. Wang, Haiming & Dou, Xiaomin & Veksha, Andrei & Liu, Wen & Giannis, Apostolos & Ge, Liya & Thye Lim, Teik & Lisak, Grzegorz, 2020. "Barium aluminate improved iron ore for the chemical looping combustion of syngas," Applied Energy, Elsevier, vol. 272(C).
    4. Jančauskas, Adolfas & Striūgas, Nerijus & Zakarauskas, Kęstutis & Skvorčinskienė, Raminta & Eimontas, Justinas & Buinevičius, Kęstutis, 2024. "Experimental investigation of sorted municipal solid wastes producer gas composition in an updraft fixed bed gasifier," Energy, Elsevier, vol. 289(C).
    5. Johannes Full & Steffen Merseburg & Robert Miehe & Alexander Sauer, 2021. "A New Perspective for Climate Change Mitigation—Introducing Carbon-Negative Hydrogen Production from Biomass with Carbon Capture and Storage (HyBECCS)," Sustainability, MDPI, vol. 13(7), pages 1-22, April.
    6. Wang, Haiming & Liu, Guicai & Veksha, Andrei & Giannis, Apostolos & Lim, Teik-Thye & Lisak, Grzegorz, 2021. "Effective H2S control during chemical looping combustion by iron ore modified with alkaline earth metal oxides," Energy, Elsevier, vol. 218(C).
    7. Adnan, Muflih A. & Hossain, Mohammad M. & Golam Kibria, Md, 2022. "Converting waste into fuel via integrated thermal and electrochemical routes: An analysis of thermodynamic approach on thermal conversion," Applied Energy, Elsevier, vol. 311(C).

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