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Giant dimeric donors for all-giant-oligomer organic solar cells with efficiency over 16% and superior photostability

Author

Listed:
  • Caixuan Wang

    (National Center for Nanoscience and Technology
    University of Chinese Academy of Sciences)

  • Xiaoming Ma

    (National Center for Nanoscience and Technology
    Beijing)

  • Dan Deng

    (National Center for Nanoscience and Technology)

  • Hao Zhang

    (National Center for Nanoscience and Technology
    University of Chinese Academy of Sciences)

  • Rui Sun

    (Wuhan University)

  • Jianqi Zhang

    (National Center for Nanoscience and Technology)

  • Lili Zhang

    (National Center for Nanoscience and Technology
    University of Chinese Academy of Sciences)

  • Mengying Wu

    (National Center for Nanoscience and Technology
    Zhengzhou University)

  • Jie Min

    (Wuhan University)

  • Zhi-Guo Zhang

    (Beijing University of Chemical Technology)

  • Zhixiang Wei

    (National Center for Nanoscience and Technology
    University of Chinese Academy of Sciences)

Abstract

Increasing the molecular weight while maintaining mono-dispersity has been proved crucial in innovating high-performance photovoltaic materials in giant oligomeric acceptors. However, developing efficient giant oligomeric donors to replace the batch-varied polymers remains challenging due to a lack of design principles. Here, by designing two unique isomeric rhodanine-based linkers, we successfully regulate the assembly behaviors of giant dimeric donors (G-Dimer-Ds) and fabricate the first all-giant-oligomer OSCs pairing with giant dimeric acceptor DY. Multiple characterizations demonstrate the small homo-molecular interaction with strong thermal-driven assembly capability in G-Dimer-D2 simultaneously facilitates reducing energetic disorder, improving charge transport and obtaining stable morphology, resulting in a satisfactory efficiency of 15.70% and long-term photostability with an extrapolated T80 of ca.10,000 hours, and further enhancing thermal-driven assembly promotes efficiency of 16.05%. Our results provide construction approaches on efficient giant donors, and propose a promising type of OSC with completely definite structures, high efficiency and superior stability.

Suggested Citation

  • Caixuan Wang & Xiaoming Ma & Dan Deng & Hao Zhang & Rui Sun & Jianqi Zhang & Lili Zhang & Mengying Wu & Jie Min & Zhi-Guo Zhang & Zhixiang Wei, 2024. "Giant dimeric donors for all-giant-oligomer organic solar cells with efficiency over 16% and superior photostability," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52821-5
    DOI: 10.1038/s41467-024-52821-5
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    References listed on IDEAS

    as
    1. Ture F. Hinrichsen & Christopher C. S. Chan & Chao Ma & David Paleček & Alexander Gillett & Shangshang Chen & Xinhui Zou & Guichuan Zhang & Hin-Lap Yip & Kam Sing Wong & Richard H. Friend & He Yan & A, 2020. "Long-lived and disorder-free charge transfer states enable endothermic charge separation in efficient non-fullerene organic solar cells," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    2. Youcai Liang & Difei Zhang & Zerun Wu & Tao Jia & Larry Lüer & Haoran Tang & Ling Hong & Jiabin Zhang & Kai Zhang & Christoph J. Brabec & Ning Li & Fei Huang, 2022. "Organic solar cells using oligomer acceptors for improved stability and efficiency," Nature Energy, Nature, vol. 7(12), pages 1180-1190, December.
    3. Kang An & Wenkai Zhong & Feng Peng & Wanyuan Deng & Ying Shang & Huilei Quan & Hong Qiu & Cheng Wang & Feng Liu & Hongbin Wu & Ning Li & Fei Huang & Lei Ying, 2023. "Mastering morphology of non-fullerene acceptors towards long-term stable organic solar cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
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