IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i2p450-d309787.html
   My bibliography  Save this article

Benzothiadiazole Based Cascade Material to Boost the Performance of Inverted Ternary Organic Solar Cells

Author

Listed:
  • Miron Krassas

    (Department of Electrical & Computer Engineering, Hellenic Mediterranean University, 71410 Heraklion, Crete, Greece
    Department of Materials Science and Technology, University of Crete, 71003 Heraklion, Crete, Greece
    These authors contributed equally to this work.)

  • Christos Polyzoidis

    (Department of Electrical & Computer Engineering, Hellenic Mediterranean University, 71410 Heraklion, Crete, Greece
    These authors contributed equally to this work.)

  • Pavlos Tzourmpakis

    (Department of Electrical & Computer Engineering, Hellenic Mediterranean University, 71410 Heraklion, Crete, Greece)

  • Dimitriοs M. Kosmidis

    (Department of Electrical & Computer Engineering, Hellenic Mediterranean University, 71410 Heraklion, Crete, Greece)

  • George Viskadouros

    (Department of Electrical & Computer Engineering, Hellenic Mediterranean University, 71410 Heraklion, Crete, Greece
    Department of Mineral Resources Engineering, Technical University of Crete, 73100 Chania, Crete, Greece)

  • Nikolaos Kornilios

    (Department of Electrical & Computer Engineering, Hellenic Mediterranean University, 71410 Heraklion, Crete, Greece)

  • George Charalambidis

    (Laboratory of Bioinorganic Chemistry, Chemistry Department, University of Crete, Voutes Campus, 71003 Heraklion, Crete, Greece)

  • Vasilis Nikolaou

    (Laboratory of Bioinorganic Chemistry, Chemistry Department, University of Crete, Voutes Campus, 71003 Heraklion, Crete, Greece)

  • Athanassios G. Coutsolelos

    (Laboratory of Bioinorganic Chemistry, Chemistry Department, University of Crete, Voutes Campus, 71003 Heraklion, Crete, Greece)

  • Konstantinos Petridis

    (Department of Electronic Engineering, Hellenic Mediterranean University, 73132 Chania, Crete, Greece)

  • Minas M. Stylianakis

    (Department of Electrical & Computer Engineering, Hellenic Mediterranean University, 71410 Heraklion, Crete, Greece)

  • Emmanuel Kymakis

    (Department of Electrical & Computer Engineering, Hellenic Mediterranean University, 71410 Heraklion, Crete, Greece)

Abstract

A conjugated, ladder-type multi-fused ring 4,7-dithienbenzothiadiazole:thiophene derivative, named as compound ‘T’, was for the first time incorporated, within the PTB7:PC 71 BM photoactive layer for inverted ternary organic solar cells (TOSCs) realization. The effective energy level offset caused by compound T between the polymeric donor and fullerene acceptor materials, as well as its resulting potential as electron cascade material contribute to an enhanced exciton dissociation, electron transfer facilitator and thus improved overall photovoltaic performance. The engineering optimization of the inverted TOSC, ITO/PFN/PTB7:Compound T(5% v/v):PC 71 BM/MoO 3 /Al, resulted in an overall power conversion efficiency (PCE) of 8.34%, with a short-circuit current density ( J sc ) of 16.75 mA cm −2 , open-circuit voltage ( V oc ) of 0.74 V and a fill factor (FF) of 68.1%, under AM1.5G illumination. This photovoltaic performance was improved by approximately 12% with respect to the control binary device.

Suggested Citation

  • Miron Krassas & Christos Polyzoidis & Pavlos Tzourmpakis & Dimitriοs M. Kosmidis & George Viskadouros & Nikolaos Kornilios & George Charalambidis & Vasilis Nikolaou & Athanassios G. Coutsolelos & Kons, 2020. "Benzothiadiazole Based Cascade Material to Boost the Performance of Inverted Ternary Organic Solar Cells," Energies, MDPI, vol. 13(2), pages 1-12, January.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:2:p:450-:d:309787
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/2/450/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/13/2/450/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Luyao Lu & Wei Chen & Tao Xu & Luping Yu, 2015. "High-performance ternary blend polymer solar cells involving both energy transfer and hole relay processes," Nature Communications, Nature, vol. 6(1), pages 1-7, November.
    2. Yong Cui & Huifeng Yao & Jianqi Zhang & Tao Zhang & Yuming Wang & Ling Hong & Kaihu Xian & Bowei Xu & Shaoqing Zhang & Jing Peng & Zhixiang Wei & Feng Gao & Jianhui Hou, 2019. "Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    3. Katerina Anagnostou & Minas M. Stylianakis & Konstantinos Petridis & Emmanuel Kymakis, 2019. "Building an Organic Solar Cell: Fundamental Procedures for Device Fabrication," Energies, MDPI, vol. 12(11), pages 1-23, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xinlei Wu & Yuanpeng Zhang & Kaihang Shi & Xiaoling Ma & Fujun Zhang, 2023. "Advanced Progress of Organic Photovoltaics," Energies, MDPI, vol. 16(3), pages 1-3, January.
    2. Qiuju Liang & Haodong Lu & Yinxia Chang & Zemin He & Yuzhen Zhao & Jiangang Liu, 2022. "Morphology Control in Organic Solar Cells," Energies, MDPI, vol. 15(15), pages 1-3, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xuelin Wang & Qianqian Sun & Jinhua Gao & Jian Wang & Chunyu Xu & Xiaoling Ma & Fujun Zhang, 2021. "Recent Progress of Organic Photovoltaics with Efficiency over 17%," Energies, MDPI, vol. 14(14), pages 1-27, July.
    2. Fabian Schoden & Anna Katharina Schnatmann & Tomasz Blachowicz & Hildegard Manz-Schumacher & Eva Schwenzfeier-Hellkamp, 2022. "Circular Design Principles Applied on Dye-Sensitized Solar Cells," Sustainability, MDPI, vol. 14(22), pages 1-32, November.
    3. Madasamy Periyanayagam & Suresh Kumar V & Bharatiraja Chokkalingam & Sanjeevikumar Padmanaban & Lucian Mihet-Popa & Yusuff Adedayo, 2020. "A Modified High Voltage Gain Quasi-Impedance Source Coupled Inductor Multilevel Inverter for Photovoltaic Application," Energies, MDPI, vol. 13(4), pages 1-31, February.
    4. Hong, Kai Jeat & Tan, Sin Tee & Chong, Kok-Keong & Yap, Chi Chin & Hj Jumali, Mohammad Hafizuddin & Loo, Yueh-Lin, 2019. "Numerical analysis with experimental verification to predict outdoor power conversion efficiency of inverted organic solar devices," Renewable Energy, Elsevier, vol. 135(C), pages 589-596.
    5. Alexander N. Solodukhin & Yuriy N. Luponosov & Artur L. Mannanov & Petr S. Savchenko & Artem V. Bakirov & Maxim A. Shcherbina & Sergei N. Chvalun & Dmitry Yu. Paraschuk & Sergey A. Ponomarenko, 2021. "Branched Electron-Donor Core Effect in D-π-A Star-Shaped Small Molecules on Their Properties and Performance in Single-Component and Bulk-Heterojunction Organic Solar Cells †," Energies, MDPI, vol. 14(12), pages 1-14, June.
    6. Guilong Cai & Yuhao Li & Yuang Fu & Hua Yang & Le Mei & Zhaoyang Nie & Tengfei Li & Heng Liu & Yubin Ke & Xun-Li Wang & Jean-Luc Brédas & Man-Chung Tang & Xiankai Chen & Xiaowei Zhan & Xinhui Lu, 2024. "Deuteration-enhanced neutron contrasts to probe amorphous domain sizes in organic photovoltaic bulk heterojunction films," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    7. Yuang Fu & Tack Ho Lee & Yi-Chun Chin & Richard A. Pacalaj & Chiara Labanti & Song Yi Park & Yifan Dong & Hye Won Cho & Jin Young Kim & Daiki Minami & James R. Durrant & Ji-Seon Kim, 2023. "Molecular orientation-dependent energetic shifts in solution-processed non-fullerene acceptors and their impact on organic photovoltaic performance," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    8. Zhi Zhang & Yao Wang & Qun Chen & Zhipan Zeng, 2022. "Performance Enhancement of Interdigitated Heterojunction Solar Cells with Discotic Molecule," Energies, MDPI, vol. 15(15), pages 1-12, August.
    9. Jing Wang & Xudong Jiang & Hongbo Wu & Guitao Feng & Hanyu Wu & Junyu Li & Yuanping Yi & Xunda Feng & Zaifei Ma & Weiwei Li & Koen Vandewal & Zheng Tang, 2021. "Increasing donor-acceptor spacing for reduced voltage loss in organic solar cells," Nature Communications, Nature, vol. 12(1), pages 1-9, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:2:p:450-:d:309787. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.