IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i12p3596-d576353.html
   My bibliography  Save this article

Branched Electron-Donor Core Effect in D-π-A Star-Shaped Small Molecules on Their Properties and Performance in Single-Component and Bulk-Heterojunction Organic Solar Cells †

Author

Listed:
  • Alexander N. Solodukhin

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia
    Alexander N. Solodukhin and Yuriy N. Luponosov contributed equally to this work.)

  • Yuriy N. Luponosov

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia
    Alexander N. Solodukhin and Yuriy N. Luponosov contributed equally to this work.)

  • Artur L. Mannanov

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia
    Faculty of Physics, Lomonosov Moscow State University, Leninskie Gory 1/62, 119991 Moscow, Russia)

  • Petr S. Savchenko

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia)

  • Artem V. Bakirov

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia
    National Research Centre Kurchatov Institute, 1 ak. Kurchatov Square, 123098 Moscow, Russia)

  • Maxim A. Shcherbina

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia
    Moscow Institute of Physics and Technology, 9 Institutsky Line, Dolgoprudny, 141700 Moscow, Russia)

  • Sergei N. Chvalun

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia
    National Research Centre Kurchatov Institute, 1 ak. Kurchatov Square, 123098 Moscow, Russia)

  • Dmitry Yu. Paraschuk

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia
    Faculty of Physics, Lomonosov Moscow State University, Leninskie Gory 1/62, 119991 Moscow, Russia)

  • Sergey A. Ponomarenko

    (Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya St. 70, 117393 Moscow, Russia)

Abstract

Star-shaped donor-acceptor molecules are full of promise for organic photovoltaics and electronics. However, the effect of the branching core on physicochemical properties, charge transport and photovoltaic performance of such donor-acceptor materials in single-component (SC) and bulk heterojunction (BHJ) organic solar cells has not been thoroughly addressed. This work shows the comprehensive investigation of six star-shaped donor-acceptor molecules with terminal hexyldicyanovinyl blocks linked through 2,2′-bithiophene π-conjugated bridge to different electron-donating cores such as the pristine and fused triphenylamine, tris (2-methoxyphenyl)amine, carbazole- and benzotriindole-based units. Variation of the branching core strongly impacts on such important properties as the solubility, highest occupied molecular orbital energy, optical absorption, phase behavior, molecular packing and also on the charge-carrier mobility. The performance of SC or BHJ organic solar cells are comprehensively studied and compared. The results obtained provide insight on how to predict and fine-tune photovoltaic performance as well as properties of donor-acceptor star-shaped molecules for organic solar cells.

Suggested Citation

  • Alexander N. Solodukhin & Yuriy N. Luponosov & Artur L. Mannanov & Petr S. Savchenko & Artem V. Bakirov & Maxim A. Shcherbina & Sergei N. Chvalun & Dmitry Yu. Paraschuk & Sergey A. Ponomarenko, 2021. "Branched Electron-Donor Core Effect in D-π-A Star-Shaped Small Molecules on Their Properties and Performance in Single-Component and Bulk-Heterojunction Organic Solar Cells †," Energies, MDPI, vol. 14(12), pages 1-14, June.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:12:p:3596-:d:576353
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/12/3596/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/12/3596/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Hai-Tao Feng & Jiajie Zeng & Ping-An Yin & Xue-Dong Wang & Qian Peng & Zujin Zhao & Jacky W. Y. Lam & Ben Zhong Tang, 2020. "Tuning molecular emission of organic emitters from fluorescence to phosphorescence through push-pull electronic effects," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    2. Yifan Dong & Vasileios C. Nikolis & Felix Talnack & Yi-Chun Chin & Johannes Benduhn & Giacomo Londi & Jonas Kublitski & Xijia Zheng & Stefan C. B. Mannsfeld & Donato Spoltore & Luca Muccioli & Jing Li, 2020. "Orientation dependent molecular electrostatics drives efficient charge generation in homojunction organic solar cells," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    3. Yong Cui & Huifeng Yao & Jianqi Zhang & Tao Zhang & Yuming Wang & Ling Hong & Kaihu Xian & Bowei Xu & Shaoqing Zhang & Jing Peng & Zhixiang Wei & Feng Gao & Jianhui Hou, 2019. "Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Xinlei Wu & Yuanpeng Zhang & Kaihang Shi & Xiaoling Ma & Fujun Zhang, 2023. "Advanced Progress of Organic Photovoltaics," Energies, MDPI, vol. 16(3), pages 1-3, January.
    2. Yu Jiang & Youjun Bai & Shenghao Wang, 2023. "Organic Solar Cells: From Fundamental to Application," Energies, MDPI, vol. 16(5), pages 1-3, February.
    3. Qiuju Liang & Haodong Lu & Yinxia Chang & Zemin He & Yuzhen Zhao & Jiangang Liu, 2022. "Morphology Control in Organic Solar Cells," Energies, MDPI, vol. 15(15), pages 1-3, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yuang Fu & Tack Ho Lee & Yi-Chun Chin & Richard A. Pacalaj & Chiara Labanti & Song Yi Park & Yifan Dong & Hye Won Cho & Jin Young Kim & Daiki Minami & James R. Durrant & Ji-Seon Kim, 2023. "Molecular orientation-dependent energetic shifts in solution-processed non-fullerene acceptors and their impact on organic photovoltaic performance," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Xuelin Wang & Qianqian Sun & Jinhua Gao & Jian Wang & Chunyu Xu & Xiaoling Ma & Fujun Zhang, 2021. "Recent Progress of Organic Photovoltaics with Efficiency over 17%," Energies, MDPI, vol. 14(14), pages 1-27, July.
    3. Aniket Rana & Song Yi Park & Chiara Labanti & Feifei Fang & Sungyoung Yun & Yifan Dong & Emily J. Yang & Davide Nodari & Nicola Gasparini & Jeong–Il Park & Jisoo Shin & Daiki Minami & Kyung-Bae Park &, 2024. "Octupole moment driven free charge generation in partially chlorinated subphthalocyanine for planar heterojunction organic photodetectors," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Caixuan Wang & Xiaoming Ma & Dan Deng & Hao Zhang & Rui Sun & Jianqi Zhang & Lili Zhang & Mengying Wu & Jie Min & Zhi-Guo Zhang & Zhixiang Wei, 2024. "Giant dimeric donors for all-giant-oligomer organic solar cells with efficiency over 16% and superior photostability," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Michael B. Price & Paul A. Hume & Aleksandra Ilina & Isabella Wagner & Ronnie R. Tamming & Karen E. Thorn & Wanting Jiao & Alison Goldingay & Patrick J. Conaghan & Girish Lakhwani & Nathaniel J. L. K., 2022. "Free charge photogeneration in a single component high photovoltaic efficiency organic semiconductor," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    6. Madasamy Periyanayagam & Suresh Kumar V & Bharatiraja Chokkalingam & Sanjeevikumar Padmanaban & Lucian Mihet-Popa & Yusuff Adedayo, 2020. "A Modified High Voltage Gain Quasi-Impedance Source Coupled Inductor Multilevel Inverter for Photovoltaic Application," Energies, MDPI, vol. 13(4), pages 1-31, February.
    7. Guilong Cai & Yuhao Li & Yuang Fu & Hua Yang & Le Mei & Zhaoyang Nie & Tengfei Li & Heng Liu & Yubin Ke & Xun-Li Wang & Jean-Luc Brédas & Man-Chung Tang & Xiankai Chen & Xiaowei Zhan & Xinhui Lu, 2024. "Deuteration-enhanced neutron contrasts to probe amorphous domain sizes in organic photovoltaic bulk heterojunction films," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    8. Marios Maimaris & Allan J. Pettipher & Mohammed Azzouzi & Daniel J. Walke & Xijia Zheng & Andrei Gorodetsky & Yifan Dong & Pabitra Shakya Tuladhar & Helder Crespo & Jenny Nelson & John W. G. Tisch & A, 2022. "Sub-10-fs observation of bound exciton formation in organic optoelectronic devices," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Miron Krassas & Christos Polyzoidis & Pavlos Tzourmpakis & Dimitriοs M. Kosmidis & George Viskadouros & Nikolaos Kornilios & George Charalambidis & Vasilis Nikolaou & Athanassios G. Coutsolelos & Kons, 2020. "Benzothiadiazole Based Cascade Material to Boost the Performance of Inverted Ternary Organic Solar Cells," Energies, MDPI, vol. 13(2), pages 1-12, January.
    10. Samuele Giannini & Wei-Tao Peng & Lorenzo Cupellini & Daniele Padula & Antoine Carof & Jochen Blumberger, 2022. "Exciton transport in molecular organic semiconductors boosted by transient quantum delocalization," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    11. He Wang & Huili Ma & Nan Gan & Kai Qin & Zhicheng Song & Anqi Lv & Kai Wang & Wenpeng Ye & Xiaokang Yao & Chifeng Zhou & Xiao Wang & Zixing Zhou & Shilin Yang & Lirong Yang & Cuimei Bo & Huifang Shi &, 2024. "Abnormal thermally-stimulated dynamic organic phosphorescence," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    12. Jing Wang & Xudong Jiang & Hongbo Wu & Guitao Feng & Hanyu Wu & Junyu Li & Yuanping Yi & Xunda Feng & Zaifei Ma & Weiwei Li & Koen Vandewal & Zheng Tang, 2021. "Increasing donor-acceptor spacing for reduced voltage loss in organic solar cells," Nature Communications, Nature, vol. 12(1), pages 1-9, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:12:p:3596-:d:576353. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.