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Co-adsorbed self-assembled monolayer enables high-performance perovskite and organic solar cells

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  • Dongyang Li

    (Southern University of Science and Technology
    The Hong Kong Polytechnic University, Hung Hom)

  • Qing Lian

    (Southern University of Science and Technology)

  • Tao Du

    (The Hong Kong Polytechnic University)

  • Ruijie Ma

    (The Hong Kong Polytechnic University, Hung Hom)

  • Heng Liu

    (The Chinese University of Hong Kong)

  • Qiong Liang

    (The Hong Kong Polytechnic University, Hung Hom)

  • Yu Han

    (The Hong Kong Polytechnic University, Hung Hom)

  • Guojun Mi

    (Southern University of Science and Technology)

  • Ouwen Peng

    (Southern University of Science and Technology)

  • Guihua Zhang

    (Southern University of Science and Technology)

  • Wenbo Peng

    (Southern University of Science and Technology)

  • Baomin Xu

    (Southern University of Science and Technology)

  • Xinhui Lu

    (The Chinese University of Hong Kong)

  • Kuan Liu

    (The Hong Kong Polytechnic University, Hung Hom)

  • Jun Yin

    (The Hong Kong Polytechnic University)

  • Zhiwei Ren

    (The Hong Kong Polytechnic University, Hung Hom)

  • Gang Li

    (The Hong Kong Polytechnic University, Hung Hom
    The Hong Kong Polytechnic University Shenzhen Research Institute)

  • Chun Cheng

    (Southern University of Science and Technology
    Southern University of Science and Technology
    Southern University of Science and Technology)

Abstract

Self-assembled monolayers (SAMs) have become pivotal in achieving high-performance perovskite solar cells (PSCs) and organic solar cells (OSCs) by significantly minimizing interfacial energy losses. In this study, we propose a co-adsorb (CA) strategy employing a novel small molecule, 2-chloro-5-(trifluoromethyl)isonicotinic acid (PyCA-3F), introducing at the buried interface between 2PACz and the perovskite/organic layers. This approach effectively diminishes 2PACz’s aggregation, enhancing surface smoothness and increasing work function for the modified SAM layer, thereby providing a flattened buried interface with a favorable heterointerface for perovskite. The resultant improvements in crystallinity, minimized trap states, and augmented hole extraction and transfer capabilities have propelled power conversion efficiencies (PCEs) beyond 25% in PSCs with a p-i-n structure (certified at 24.68%). OSCs employing the CA strategy achieve remarkable PCEs of 19.51% based on PM1:PTQ10:m-BTP-PhC6 photoactive system. Notably, universal improvements have also been achieved for the other two popular OSC systems. After a 1000-hour maximal power point tracking, the encapsulated PSCs and OSCs retain approximately 90% and 80% of their initial PCEs, respectively. This work introduces a facile, rational, and effective method to enhance the performance of SAMs, realizing efficiency breakthroughs in both PSCs and OSCs with a favorable p-i-n device structure, along with improved operational stability.

Suggested Citation

  • Dongyang Li & Qing Lian & Tao Du & Ruijie Ma & Heng Liu & Qiong Liang & Yu Han & Guojun Mi & Ouwen Peng & Guihua Zhang & Wenbo Peng & Baomin Xu & Xinhui Lu & Kuan Liu & Jun Yin & Zhiwei Ren & Gang Li , 2024. "Co-adsorbed self-assembled monolayer enables high-performance perovskite and organic solar cells," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-51760-5
    DOI: 10.1038/s41467-024-51760-5
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