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Structural color three-dimensional printing by shrinking photonic crystals

Author

Listed:
  • Yejing Liu

    (Singapore University of Technology and Design)

  • Hao Wang

    (Singapore University of Technology and Design)

  • Jinfa Ho

    (Institute of Materials Research and Engineering)

  • Ryan C. Ng

    (California Institute of Technology)

  • Ray J. H. Ng

    (Singapore University of Technology and Design
    Institute of Materials Research and Engineering)

  • Valerian H. Hall-Chen

    (University of Oxford)

  • Eleen H. H. Koay

    (Institute of Materials Research and Engineering)

  • Zhaogang Dong

    (Institute of Materials Research and Engineering)

  • Hailong Liu

    (Singapore University of Technology and Design)

  • Cheng-Wei Qiu

    (National University of Singapore)

  • Julia R. Greer

    (California Institute of Technology)

  • Joel K. W. Yang

    (Singapore University of Technology and Design
    Institute of Materials Research and Engineering)

Abstract

The coloration of some butterflies, Pachyrhynchus weevils, and many chameleons are notable examples of natural organisms employing photonic crystals to produce colorful patterns. Despite advances in nanotechnology, we still lack the ability to print arbitrary colors and shapes in all three dimensions at this microscopic length scale. Here, we introduce a heat-shrinking method to produce 3D-printed photonic crystals with a 5x reduction in lattice constants, achieving sub-100-nm features with a full range of colors. With these lattice structures as 3D color volumetric elements, we printed 3D microscopic scale objects, including the first multi-color microscopic model of the Eiffel Tower measuring only 39 µm tall with a color pixel size of 1.45 µm. The technology to print 3D structures in color at the microscopic scale promises the direct patterning and integration of spectrally selective devices, such as photonic crystal-based color filters, onto free-form optical elements and curved surfaces.

Suggested Citation

  • Yejing Liu & Hao Wang & Jinfa Ho & Ryan C. Ng & Ray J. H. Ng & Valerian H. Hall-Chen & Eleen H. H. Koay & Zhaogang Dong & Hailong Liu & Cheng-Wei Qiu & Julia R. Greer & Joel K. W. Yang, 2019. "Structural color three-dimensional printing by shrinking photonic crystals," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:10:y:2019:i:1:d:10.1038_s41467-019-12360-w
    DOI: 10.1038/s41467-019-12360-w
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    Cited by:

    1. Keliang Liu & Haibo Ding & Sen Li & Yanfang Niu & Yi Zeng & Junning Zhang & Xin Du & Zhongze Gu, 2022. "3D printing colloidal crystal microstructures via sacrificial-scaffold-mediated two-photon lithography," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    2. Feng Jin & Jie Liu & Yuan-Yuan Zhao & Xian-Zi Dong & Mei-Ling Zheng & Xuan-Ming Duan, 2022. "λ/30 inorganic features achieved by multi-photon 3D lithography," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Tomohiro Mori & Hao Wang & Wang Zhang & Chern Chia Ser & Deepshikha Arora & Cheng-Feng Pan & Hao Li & Jiabin Niu & M. A. Rahman & Takeshi Mori & Hideyuki Koishi & Joel K. W. Yang, 2023. "Pick and place process for uniform shrinking of 3D printed micro- and nano-architected materials," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Lingling Guan & Chun Cao & Xi Liu & Qiulan Liu & Yiwei Qiu & Xiaobing Wang & Zhenyao Yang & Huiying Lai & Qiuyuan Sun & Chenliang Ding & Dazhao Zhu & Cuifang Kuang & Xu Liu, 2024. "Light and matter co-confined multi-photon lithography," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Zhi-Yong Hu & Yong-Lai Zhang & Chong Pan & Jian-Yu Dou & Zhen-Ze Li & Zhen-Nan Tian & Jiang-Wei Mao & Qi-Dai Chen & Hong-Bo Sun, 2022. "Miniature optoelectronic compound eye camera," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    6. Xianglong Lyu & Zhiqiang Zheng & Anitha Shiva & Mertcan Han & Cem Balda Dayan & Mingchao Zhang & Metin Sitti, 2024. "Capillary trapping of various nanomaterials on additively manufactured scaffolds for 3D micro-/nanofabrication," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    7. Yu Zhang & Lidian Zhang & Chengqi Zhang & Jingxia Wang & Junchao Liu & Changqing Ye & Zhichao Dong & Lei Wu & Yanlin Song, 2022. "Continuous resin refilling and hydrogen bond synergistically assisted 3D structural color printing," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    8. Geon Yeong Kim & Shinho Kim & Ki Hyun Park & Hanhwi Jang & Moohyun Kim & Tae Won Nam & Kyeong Min Song & Hongjoo Shin & Yemin Park & Yeongin Cho & Jihyeon Yeom & Min-Jae Choi & Min Seok Jang & Yeon Si, 2024. "Chiral 3D structures through multi-dimensional transfer printing of multilayer quantum dot patterns," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    9. Ahmet F. Demirörs & Erik Poloni & Maddalena Chiesa & Fabio L. Bargardi & Marco R. Binelli & Wilhelm Woigk & Lucas D. C. Castro & Nicole Kleger & Fergal B. Coulter & Alba Sicher & Henning Galinski & Fr, 2022. "Three-dimensional printing of photonic colloidal glasses into objects with isotropic structural color," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    10. Jiao Geng & Liye Xu & Wei Yan & Liping Shi & Min Qiu, 2023. "High-speed laser writing of structural colors for full-color inkless printing," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    11. Wenqi Ouyang & Xiayi Xu & Wanping Lu & Ni Zhao & Fei Han & Shih-Chi Chen, 2023. "Ultrafast 3D nanofabrication via digital holography," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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