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High entropy oxides for reversible energy storage

Author

Listed:
  • Abhishek Sarkar

    (Karlsruhe Institute of Technology)

  • Leonardo Velasco

    (Karlsruhe Institute of Technology)

  • Di Wang

    (Karlsruhe Institute of Technology
    Karlsruhe Institute of Technology)

  • Qingsong Wang

    (Karlsruhe Institute of Technology)

  • Gopichand Talasila

    (Karlsruhe Institute of Technology)

  • Lea de Biasi

    (Karlsruhe Institute of Technology)

  • Christian Kübel

    (Karlsruhe Institute of Technology
    Karlsruhe Institute of Technology
    Helmholtz Institute Ulm for Electrochemical Energy Storage)

  • Torsten Brezesinski

    (Karlsruhe Institute of Technology)

  • Subramshu S. Bhattacharya

    (Indian Institute of Technology Madras)

  • Horst Hahn

    (Karlsruhe Institute of Technology
    Helmholtz Institute Ulm for Electrochemical Energy Storage)

  • Ben Breitung

    (Karlsruhe Institute of Technology
    Karlsruhe Institute of Technology)

Abstract

In recent years, the concept of entropy stabilization of crystal structures in oxide systems has led to an increased research activity in the field of “high entropy oxides”. These compounds comprise the incorporation of multiple metal cations into single-phase crystal structures and interactions among the various metal cations leading to interesting novel and unexpected properties. Here, we report on the reversible lithium storage properties of the high entropy oxides, the underlying mechanisms governing these properties, and the influence of entropy stabilization on the electrochemical behavior. It is found that the stabilization effect of entropy brings significant benefits for the storage capacity retention of high entropy oxides and greatly improves the cycling stability. Additionally, it is observed that the electrochemical behavior of the high entropy oxides depends on each of the metal cations present, thus providing the opportunity to tailor the electrochemical properties by simply changing the elemental composition.

Suggested Citation

  • Abhishek Sarkar & Leonardo Velasco & Di Wang & Qingsong Wang & Gopichand Talasila & Lea de Biasi & Christian Kübel & Torsten Brezesinski & Subramshu S. Bhattacharya & Horst Hahn & Ben Breitung, 2018. "High entropy oxides for reversible energy storage," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:9:y:2018:i:1:d:10.1038_s41467-018-05774-5
    DOI: 10.1038/s41467-018-05774-5
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    Cited by:

    1. Sishuang Tang & Minghao Xie & Saerom Yu & Xun Zhan & Ruilin Wei & Maoyu Wang & Weixin Guan & Bowen Zhang & Yuyang Wang & Hua Zhou & Gengfeng Zheng & Yuanyue Liu & Jamie H. Warner & Guihua Yu, 2024. "General synthesis of high-entropy single-atom nanocages for electrosynthesis of ammonia from nitrate," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Adánez-Rubio, Iñaki & Izquierdo, María T. & Brorsson, Joakim & Mei, Daofeng & Mattisson, Tobias & Adánez, Juan, 2024. "Use of a high-entropy oxide as an oxygen carrier for chemical looping," Energy, Elsevier, vol. 298(C).
    3. Kai Wang & Weibo Hua & Xiaohui Huang & David Stenzel & Junbo Wang & Ziming Ding & Yanyan Cui & Qingsong Wang & Helmut Ehrenberg & Ben Breitung & Christian Kübel & Xiaoke Mu, 2023. "Synergy of cations in high entropy oxide lithium ion battery anode," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Jose Antonio Garrido Torres & Vahe Gharakhanyan & Nongnuch Artrith & Tobias Hoffmann Eegholm & Alexander Urban, 2021. "Augmenting zero-Kelvin quantum mechanics with machine learning for the prediction of chemical reactions at high temperatures," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    5. Yi Han & Xiangyang Liu & Qiqi Zhang & Muzhang Huang & Yi Li & Wei Pan & Peng-an Zong & Lieyang Li & Zesheng Yang & Yingjie Feng & Peng Zhang & Chunlei Wan, 2022. "Ultra-dense dislocations stabilized in high entropy oxide ceramics," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    6. Siyang Nie & Liang Wu & Qinghua Zhang & Yunwei Huang & Qingda Liu & Xun Wang, 2024. "High-entropy-perovskite subnanowires for photoelectrocatalytic coupling of methane to acetic acid," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    7. Yanzhi Wang & Hangjuan He & Hao Lv & Fengrui Jia & Ben Liu, 2024. "Two-dimensional single-crystalline mesoporous high-entropy oxide nanoplates for efficient electrochemical biomass upgrading," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    8. Lei Su & Huaixun Huyan & Abhishek Sarkar & Wenpei Gao & Xingxu Yan & Christopher Addiego & Robert Kruk & Horst Hahn & Xiaoqing Pan, 2022. "Direct observation of elemental fluctuation and oxygen octahedral distortion-dependent charge distribution in high entropy oxides," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    9. Mengyuan Zhang & Ying Gao & Chengmin Xie & Xiaolan Duan & Xiaoyan Lu & Kongliang Luo & Jian Ye & Xiaopeng Wang & Xinhua Gao & Qiang Niu & Pengfei Zhang & Sheng Dai, 2024. "Designing water resistant high entropy oxide materials," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    10. Bin Ouyang & Yan Zeng, 2024. "The rise of high-entropy battery materials," Nature Communications, Nature, vol. 15(1), pages 1-5, December.
    11. Jihyun Baek & Md Delowar Hossain & Pinaki Mukherjee & Junghwa Lee & Kirsten T. Winther & Juyoung Leem & Yue Jiang & William C. Chueh & Michal Bajdich & Xiaolin Zheng, 2023. "Synergistic effects of mixing and strain in high entropy spinel oxides for oxygen evolution reaction," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    12. Wei Chen & Antoine Hilhorst & Georgios Bokas & Stéphane Gorsse & Pascal J. Jacques & Geoffroy Hautier, 2023. "A map of single-phase high-entropy alloys," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    13. Yixiu Luo & Luchao Sun & Jiemin Wang & Tiefeng Du & Cui Zhou & Jie Zhang & Jingyang Wang, 2023. "Phase formation capability and compositional design of β-phase multiple rare-earth principal component disilicates," Nature Communications, Nature, vol. 14(1), pages 1-13, December.

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