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Confining platinum clusters in indium-modified ZSM-5 zeolite to promote propane dehydrogenation

Author

Listed:
  • Yong Yuan

    (Brookhaven National Laboratory)

  • Erwei Huang

    (Brookhaven National Laboratory)

  • Sooyeon Hwang

    (Brookhaven National Laboratory)

  • Ping Liu

    (Brookhaven National Laboratory)

  • Jingguang G. Chen

    (Brookhaven National Laboratory
    Columbia University)

Abstract

Designing highly active and stable catalytic sites is often challenging due to the complex synthesis procedure and the agglomeration of active sites during high-temperature reactions. Here, we report a facile two-step method to synthesize Pt clusters confined by In-modified ZSM-5 zeolite. In-situ characterization confirms that In is located at the extra-framework position of ZSM-5 as In+, and the Pt clusters are stabilized by the In-ZSM-5 zeolite. The resulting Pt clusters confined in In-ZSM-5 show excellent propane conversion, propylene selectivity, and catalytic stability, outperforming monometallic Pt, In, and bimetallic PtIn alloys. The incorporation of In+ in ZSM-5 neutralizes Brønsted acid sites to inhibit side reactions, as well as tunes the electronic properties of Pt clusters to facilitate propane activation and propylene desorption. The strategy of combining precious metal clusters with metal cation-exchanged zeolites opens the avenue to develop stable heterogeneous catalysts for other reaction systems.

Suggested Citation

  • Yong Yuan & Erwei Huang & Sooyeon Hwang & Ping Liu & Jingguang G. Chen, 2024. "Confining platinum clusters in indium-modified ZSM-5 zeolite to promote propane dehydrogenation," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50709-y
    DOI: 10.1038/s41467-024-50709-y
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    References listed on IDEAS

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    1. Yuki Nakaya & Jun Hirayama & Seiji Yamazoe & Ken-ichi Shimizu & Shinya Furukawa, 2020. "Single-atom Pt in intermetallics as an ultrastable and selective catalyst for propane dehydrogenation," Nature Communications, Nature, vol. 11(1), pages 1-7, December.
    2. Guodong Sun & Zhi-Jian Zhao & Rentao Mu & Shenjun Zha & Lulu Li & Sai Chen & Ketao Zang & Jun Luo & Zhenglong Li & Stephen C. Purdy & A. Jeremy Kropf & Jeffrey T. Miller & Liang Zeng & Jinlong Gong, 2018. "Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    3. Yaoyuan Zhang & Yun Zhao & Tatiana Otroshchenko & Henrik Lund & Marga-Martina Pohl & Uwe Rodemerck & David Linke & Haijun Jiao & Guiyuan Jiang & Evgenii V. Kondratenko, 2018. "Control of coordinatively unsaturated Zr sites in ZrO2 for efficient C–H bond activation," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    4. Ryong Ryoo & Jaeheon Kim & Changbum Jo & Seung Won Han & Jeong-Chul Kim & Hongjun Park & Jongho Han & Hye Sun Shin & Jae Won Shin, 2020. "Rare-earth–platinum alloy nanoparticles in mesoporous zeolite for catalysis," Nature, Nature, vol. 585(7824), pages 221-224, September.
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