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Selective atomic sieving across metal/oxide interface for super-oxidation resistance

Author

Listed:
  • Shuang Li

    (Pacific Northwest National Laboratory)

  • Li Yang

    (Department of Nuclear Engineering, University of Tennessee)

  • Jijo Christudasjustus

    (Pacific Northwest National Laboratory)

  • Nicole R. Overman

    (Pacific Northwest National Laboratory)

  • Brian D. Wirth

    (Department of Nuclear Engineering, University of Tennessee)

  • Maria L. Sushko

    (Pacific Northwest National Laboratory)

  • Pauline Simonnin

    (Pacific Northwest National Laboratory)

  • Daniel K. Schreiber

    (Pacific Northwest National Laboratory)

  • Fei Gao

    (University of Michigan)

  • Chongmin Wang

    (Pacific Northwest National Laboratory)

Abstract

Surface passivation, a desirable natural consequence during initial oxidation of alloys, is the foundation for functioning of corrosion and oxidation resistant alloys ranging from industrial stainless steel to kitchen utensils. This initial oxidation has been long perceived to vary with crystal facet, however, the underlying mechanism remains elusive. Here, using in situ environmental transmission electron microscopy, we gain atomic details on crystal facet dependent initial oxidation behavior in a model Ni-5Cr alloy. We find the (001) surface shows higher initial oxidation resistance as compared to the (111) surface. We reveal the crystal facet dependent oxidation is related to an interfacial atomic sieving effect, wherein the oxide/metal interface selectively promotes diffusion of certain atomic species. Density functional theory calculations rationalize the oxygen diffusion across Ni(111)/NiO(111) interface, as contrasted with Ni(001)/NiO(111), is enhanced. We unveil that crystal facet with initial fast oxidation rate could conversely switch to a slow steady state oxidation.

Suggested Citation

  • Shuang Li & Li Yang & Jijo Christudasjustus & Nicole R. Overman & Brian D. Wirth & Maria L. Sushko & Pauline Simonnin & Daniel K. Schreiber & Fei Gao & Chongmin Wang, 2024. "Selective atomic sieving across metal/oxide interface for super-oxidation resistance," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50576-7
    DOI: 10.1038/s41467-024-50576-7
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    References listed on IDEAS

    as
    1. Qi Zhu & Zhiliang Pan & Zhiyu Zhao & Guang Cao & Langli Luo & Chaolun Ni & Hua Wei & Ze Zhang & Frederic Sansoz & Jiangwei Wang, 2021. "Defect-driven selective metal oxidation at atomic scale," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    2. Xianhu Sun & Dongxiang Wu & Lianfeng Zou & Stephen D. House & Xiaobo Chen & Meng Li & Dmitri N. Zakharov & Judith C. Yang & Guangwen Zhou, 2022. "Dislocation-induced stop-and-go kinetics of interfacial transformations," Nature, Nature, vol. 607(7920), pages 708-713, July.
    3. Lianfeng Zou & Jonathan Li & Dmitri Zakharov & Eric A. Stach & Guangwen Zhou, 2017. "In situ atomic-scale imaging of the metal/oxide interfacial transformation," Nature Communications, Nature, vol. 8(1), pages 1-8, December.
    4. X. X. Wei & B. Zhang & B. Wu & Y. J. Wang & X. H. Tian & L. X. Yang & E. E. Oguzie & X. L. Ma, 2022. "Enhanced corrosion resistance by engineering crystallography on metals," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
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