IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-50576-7.html
   My bibliography  Save this article

Selective atomic sieving across metal/oxide interface for super-oxidation resistance

Author

Listed:
  • Shuang Li

    (Pacific Northwest National Laboratory)

  • Li Yang

    (Department of Nuclear Engineering, University of Tennessee)

  • Jijo Christudasjustus

    (Pacific Northwest National Laboratory)

  • Nicole R. Overman

    (Pacific Northwest National Laboratory)

  • Brian D. Wirth

    (Department of Nuclear Engineering, University of Tennessee)

  • Maria L. Sushko

    (Pacific Northwest National Laboratory)

  • Pauline Simonnin

    (Pacific Northwest National Laboratory)

  • Daniel K. Schreiber

    (Pacific Northwest National Laboratory)

  • Fei Gao

    (University of Michigan)

  • Chongmin Wang

    (Pacific Northwest National Laboratory)

Abstract

Surface passivation, a desirable natural consequence during initial oxidation of alloys, is the foundation for functioning of corrosion and oxidation resistant alloys ranging from industrial stainless steel to kitchen utensils. This initial oxidation has been long perceived to vary with crystal facet, however, the underlying mechanism remains elusive. Here, using in situ environmental transmission electron microscopy, we gain atomic details on crystal facet dependent initial oxidation behavior in a model Ni-5Cr alloy. We find the (001) surface shows higher initial oxidation resistance as compared to the (111) surface. We reveal the crystal facet dependent oxidation is related to an interfacial atomic sieving effect, wherein the oxide/metal interface selectively promotes diffusion of certain atomic species. Density functional theory calculations rationalize the oxygen diffusion across Ni(111)/NiO(111) interface, as contrasted with Ni(001)/NiO(111), is enhanced. We unveil that crystal facet with initial fast oxidation rate could conversely switch to a slow steady state oxidation.

Suggested Citation

  • Shuang Li & Li Yang & Jijo Christudasjustus & Nicole R. Overman & Brian D. Wirth & Maria L. Sushko & Pauline Simonnin & Daniel K. Schreiber & Fei Gao & Chongmin Wang, 2024. "Selective atomic sieving across metal/oxide interface for super-oxidation resistance," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50576-7
    DOI: 10.1038/s41467-024-50576-7
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-50576-7
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-50576-7?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Lianfeng Zou & Jonathan Li & Dmitri Zakharov & Eric A. Stach & Guangwen Zhou, 2017. "In situ atomic-scale imaging of the metal/oxide interfacial transformation," Nature Communications, Nature, vol. 8(1), pages 1-8, December.
    2. X. X. Wei & B. Zhang & B. Wu & Y. J. Wang & X. H. Tian & L. X. Yang & E. E. Oguzie & X. L. Ma, 2022. "Enhanced corrosion resistance by engineering crystallography on metals," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    3. Qi Zhu & Zhiliang Pan & Zhiyu Zhao & Guang Cao & Langli Luo & Chaolun Ni & Hua Wei & Ze Zhang & Frederic Sansoz & Jiangwei Wang, 2021. "Defect-driven selective metal oxidation at atomic scale," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    4. Xianhu Sun & Dongxiang Wu & Lianfeng Zou & Stephen D. House & Xiaobo Chen & Meng Li & Dmitri N. Zakharov & Judith C. Yang & Guangwen Zhou, 2022. "Dislocation-induced stop-and-go kinetics of interfacial transformations," Nature, Nature, vol. 607(7920), pages 708-713, July.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yao Zhang & Zezhou Li & Xing Tong & Zhiheng Xie & Siwei Huang & Yue-E Zhang & Hai-Bo Ke & Wei-Hua Wang & Jihan Zhou, 2024. "Three-dimensional atomic insights into the metal-oxide interface in Zr-ZrO2 nanoparticles," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Gang Wu & Chen Qian & Wen-Li Lv & Xiaona Zhao & Xian-Wei Liu, 2023. "Dynamic imaging of interfacial electrochemistry on single Ag nanowires by azimuth-modulated plasmonic scattering interferometry," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Shucai Zhang & Hao Feng & Huabing Li & Zhouhua Jiang & Tao Zhang & Hongchun Zhu & Yue Lin & Wei Zhang & Guoping Li, 2023. "Design for improving corrosion resistance of duplex stainless steels by wrapping inclusions with niobium armour," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Yangyang Zhang & Yanxu Chen & Xiaowen Wang & Yafei Feng & Zechuan Dai & Mingyu Cheng & Genqiang Zhang, 2024. "Low-coordinated copper facilitates the *CH2CO affinity at enhanced rectifying interface of Cu/Cu2O for efficient CO2-to-multicarbon alcohols conversion," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Shuo Sun & Zhen Han & Wei Liu & Qiuying Xia & Liang Xue & Xincheng Lei & Teng Zhai & Dong Su & Hui Xia, 2023. "Lattice pinning in MoO3 via coherent interface with stabilized Li+ intercalation," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    6. Wenjun Cui & Weixiao Lin & Weichao Lu & Chengshan Liu & Zhixiao Gao & Hao Ma & Wen Zhao & Gustaaf Tendeloo & Wenyu Zhao & Qingjie Zhang & Xiahan Sang, 2023. "Direct observation of cation diffusion driven surface reconstruction at van der Waals gaps," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50576-7. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.