IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-39866-8.html
   My bibliography  Save this article

Dynamic imaging of interfacial electrochemistry on single Ag nanowires by azimuth-modulated plasmonic scattering interferometry

Author

Listed:
  • Gang Wu

    (University of Science and Technology of China)

  • Chen Qian

    (University of Science and Technology of China)

  • Wen-Li Lv

    (University of Science and Technology of China)

  • Xiaona Zhao

    (University of Science and Technology of China)

  • Xian-Wei Liu

    (University of Science and Technology of China
    University of Science and Technology of China)

Abstract

Direct visualization of surface chemical dynamics in solution is essential for understanding the mechanisms involved in nanocatalysis and electrochemistry; however, it is challenging to achieve high spatial and temporal resolution. Here, we present an azimuth-modulated plasmonic imaging technique capable of imaging dynamic interfacial changes. The method avoids strong interference from reflected light and consequently eliminates the parabolic-like interferometric patterns in the images, allowing for a 67-fold increase in the spatial resolution of plasmonic imaging. We demonstrate that this optical imaging approach enables comprehensive analyses of surface chemical dynamics and identification of previously unknown surface reaction heterogeneity by investigating electrochemical redox reactions over single silver nanowires as an example. This work provides a general strategy for high-resolution plasmonic imaging of surface electrochemical dynamics and other interfacial chemical reactions, complementing existing surface characterization methods.

Suggested Citation

  • Gang Wu & Chen Qian & Wen-Li Lv & Xiaona Zhao & Xian-Wei Liu, 2023. "Dynamic imaging of interfacial electrochemistry on single Ag nanowires by azimuth-modulated plasmonic scattering interferometry," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39866-8
    DOI: 10.1038/s41467-023-39866-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-39866-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-39866-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Chung-Yeh Wu & William J. Wolf & Yehonatan Levartovsky & Hans A. Bechtel & Michael C. Martin & F. Dean Toste & Elad Gross, 2017. "High-spatial-resolution mapping of catalytic reactions on single particles," Nature, Nature, vol. 541(7638), pages 511-515, January.
    2. Jian Peng & Bili Chen & Zhichang Wang & Jing Guo & Binghui Wu & Shuqiang Hao & Qinghua Zhang & Lin Gu & Qin Zhou & Zhi Liu & Shuqin Hong & Sifan You & Ang Fu & Zaifa Shi & Hao Xie & Duanyun Cao & Chan, 2020. "Surface coordination layer passivates oxidation of copper," Nature, Nature, vol. 586(7829), pages 390-394, October.
    3. Qi Zhu & Zhiliang Pan & Zhiyu Zhao & Guang Cao & Langli Luo & Chaolun Ni & Hua Wei & Ze Zhang & Frederic Sansoz & Jiangwei Wang, 2021. "Defect-driven selective metal oxidation at atomic scale," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    4. Fariah Hayee & Tarun C. Narayan & Neel Nadkarni & Andrea Baldi & Ai Leen Koh & Martin Z. Bazant & Robert Sinclair & Jennifer A. Dionne, 2018. "In-situ visualization of solute-driven phase coexistence within individual nanorods," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    5. Manjesh Kumar & Madhuresh K. Choudhary & Jeffrey D. Rimer, 2018. "Transient modes of zeolite surface growth from 3D gel-like islands to 2D single layers," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    6. Justin B. Sambur & Tai-Yen Chen & Eric Choudhary & Guanqun Chen & Erin J. Nissen & Elayne M. Thomas & Ningmu Zou & Peng Chen, 2016. "Sub-particle reaction and photocurrent mapping to optimize catalyst-modified photoanodes," Nature, Nature, vol. 530(7588), pages 77-80, February.
    7. Hui Ma & Jian-Fu Chen & Hai-Feng Wang & Pei-Jun Hu & Wei Ma & Yi-Tao Long, 2020. "Exploring dynamic interactions of single nanoparticles at interfaces for surface-confined electrochemical behavior and size measurement," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    8. F. U. Renner & A. Stierle & H. Dosch & D. M. Kolb & T.-L. Lee & J. Zegenhagen, 2006. "Initial corrosion observed on the atomic scale," Nature, Nature, vol. 439(7077), pages 707-710, February.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Guusje Delen & Matteo Monai & Katarina Stančiaková & Bettina Baumgartner & Florian Meirer & Bert M. Weckhuysen, 2023. "Structure sensitivity in gas sorption and conversion on metal-organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Mengze Zhao & Zhibin Zhang & Wujun Shi & Yiwei Li & Chaowu Xue & Yuxiong Hu & Mingchao Ding & Zhiqun Zhang & Zhi Liu & Ying Fu & Can Liu & Muhong Wu & Zhongkai Liu & Xin-Zheng Li & Zhu-Jun Wang & Kaih, 2023. "Enhanced copper anticorrosion from Janus-doped bilayer graphene," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    3. Yao Zhang & Zezhou Li & Xing Tong & Zhiheng Xie & Siwei Huang & Yue-E Zhang & Hai-Bo Ke & Wei-Hua Wang & Jihan Zhou, 2024. "Three-dimensional atomic insights into the metal-oxide interface in Zr-ZrO2 nanoparticles," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    4. Xin He & Jonathan M. Larson & Hans A. Bechtel & Robert Kostecki, 2022. "In situ infrared nanospectroscopy of the local processes at the Li/polymer electrolyte interface," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Changjiang Hu & Zhiwen Jiang & Qunyan Wu & Shuiyan Cao & Qiuhao Li & Chong Chen & Liyong Yuan & Yunlong Wang & Wenyun Yang & Jinbo Yang & Jing Peng & Weiqun Shi & Maolin Zhai & Mehran Mostafavi & Jun , 2023. "Selective CO2 reduction to CH3OH over atomic dual-metal sites embedded in a metal-organic framework with high-energy radiation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Xuezhi Ma & Qiushi Liu & Ning Yu & Da Xu & Sanggon Kim & Zebin Liu & Kaili Jiang & Bryan M. Wong & Ruoxue Yan & Ming Liu, 2021. "6 nm super-resolution optical transmission and scattering spectroscopic imaging of carbon nanotubes using a nanometer-scale white light source," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    7. Shuang Li & Li Yang & Jijo Christudasjustus & Nicole R. Overman & Brian D. Wirth & Maria L. Sushko & Pauline Simonnin & Daniel K. Schreiber & Fei Gao & Chongmin Wang, 2024. "Selective atomic sieving across metal/oxide interface for super-oxidation resistance," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39866-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.