IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v263y2023ipes0360544222028778.html
   My bibliography  Save this article

Direct conversion of syngas to alpha olefins via Fischer–Tropsch synthesis: Process development and comparative techno-economic-environmental analysis

Author

Listed:
  • Wang, Danfeng
  • Gu, Yu
  • Chen, Qianqian
  • Tang, Zhiyong

Abstract

Under the pressure of carbon peak and carbon neutrality, coal chemical industry urgently needs to transform to high energy efficiency, low carbon emissions, and high-added value. A coal-based Fischer-Tropsch to olefins route using a new cobalt carbide nanoprisms catalyst for directly converting syngas into olefins was proposed in this study. To evaluate the feasibility and competitiveness of this route, we designed an products separation process and conducted a process simulation via Aspen plus based on laboratory data. On top of that, the energy consumption, energy efficiency, carbon emission, and economic performance of the coal-based Fischer–Tropsch to olefins route were analyzed, in comparison with coal-based methanol to olefins route. The energy consumption of the proposed route is 10.1% lower than that of coal-based methanol to olefins, and its carbon emissions factor is 14.8% lower than that of coal-based methanol to olefins. When the mass weighted product price is 1504 US $/ton, the project's financial internal rate of return of 17.39% is significantly greater than the industry's benchmark internal rate of return of 12%, indicating that the proposed route has strong economic competitiveness. Finally, several suggestions are proposed to improve the comprehensive performance of the proposed route for its sustainable development.

Suggested Citation

  • Wang, Danfeng & Gu, Yu & Chen, Qianqian & Tang, Zhiyong, 2023. "Direct conversion of syngas to alpha olefins via Fischer–Tropsch synthesis: Process development and comparative techno-economic-environmental analysis," Energy, Elsevier, vol. 263(PE).
  • Handle: RePEc:eee:energy:v:263:y:2023:i:pe:s0360544222028778
    DOI: 10.1016/j.energy.2022.125991
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222028778
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2022.125991?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yin, Changfang & Sun, Huifeng & Lv, Donghui & Liu, Guilian, 2022. "Integrated design and optimization of reactor-distillation sequence-recycle-heat exchanger network," Energy, Elsevier, vol. 238(PA).
    2. Junjie Su & Haibo Zhou & Su Liu & Chuanming Wang & Wenqian Jiao & Yangdong Wang & Chang Liu & Yingchun Ye & Lin Zhang & Yu Zhao & Hongxing Liu & Dong Wang & Weimin Yang & Zaiku Xie & Mingyuan He, 2019. "Syngas to light olefins conversion with high olefin/paraffin ratio using ZnCrOx/AlPO-18 bifunctional catalysts," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    3. Shi, Pengyuan & Zhang, Qingjun & Zeng, Aiwu & Ma, Youguang & Yuan, Xigang, 2020. "Eco-efficient vapor recompression-assisted pressure-swing distillation process for the separation of a maximum-boiling azeotrope," Energy, Elsevier, vol. 196(C).
    4. Dongliang, Wang & Wenliang, Meng & Huairong, Zhou & Guixian, Li & Yong, Yang & Hongwei, Li, 2021. "Green hydrogen coupling with CO2 utilization of coal-to-methanol for high methanol productivity and low CO2 emission," Energy, Elsevier, vol. 231(C).
    5. Garcia, Humberto E. & Chen, Jun & Kim, Jong S. & Vilim, Richard B. & Binder, William R. & Bragg Sitton, Shannon M. & Boardman, Richard D. & McKellar, Michael G. & Paredis, Christiaan J.J., 2016. "Dynamic performance analysis of two regional Nuclear Hybrid Energy Systems," Energy, Elsevier, vol. 107(C), pages 234-258.
    6. Liangshu Zhong & Fei Yu & Yunlei An & Yonghui Zhao & Yuhan Sun & Zhengjia Li & Tiejun Lin & Yanjun Lin & Xingzhen Qi & Yuanyuan Dai & Lin Gu & Jinsong Hu & Shifeng Jin & Qun Shen & Hui Wang, 2016. "Cobalt carbide nanoprisms for direct production of lower olefins from syngas," Nature, Nature, vol. 538(7623), pages 84-87, October.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen, Xiangxiang & Sun, Zhuang & Kuo, Po-Chih & Aziz, Muhammad, 2024. "Carbon-negative olefins production from biomass and solar energy via direct chemical looping," Energy, Elsevier, vol. 289(C).
    2. Teimouri, Zahra & Abatzoglou, Nicolas & Dalai, Ajay K., 2024. "A novel machine learning framework for designing high-performance catalysts for production of clean liquid fuels through Fischer-Tropsch synthesis," Energy, Elsevier, vol. 289(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Athanasios Ioannis Arvanitidis & Vivek Agarwal & Miltiadis Alamaniotis, 2023. "Nuclear-Driven Integrated Energy Systems: A State-of-the-Art Review," Energies, MDPI, vol. 16(11), pages 1-23, May.
    2. Popov, Dimityr & Borissova, Ana, 2017. "Innovative configuration of a hybrid nuclear-solar tower power plant," Energy, Elsevier, vol. 125(C), pages 736-746.
    3. Na Li & Yifeng Zhu & Feng Jiao & Xiulian Pan & Qike Jiang & Jun Cai & Yifan Li & Wei Tong & Changqi Xu & Shengcheng Qu & Bing Bai & Dengyun Miao & Zhi Liu & Xinhe Bao, 2022. "Steering the reaction pathway of syngas-to-light olefins with coordination unsaturated sites of ZnGaOx spinel," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    4. Chen, Jun & Garcia, Humberto E., 2016. "Economic optimization of operations for hybrid energy systems under variable markets," Applied Energy, Elsevier, vol. 177(C), pages 11-24.
    5. Fei Qian & Jiawei Bai & Yi Cai & Hui Yang & Xue-Min Cao & Xingchen Liu & Xing-Wu Liu & Yong Yang & Yong-Wang Li & Ding Ma & Xiao-Dong Wen, 2024. "Stabilized ε-Fe2C catalyst with Mn tuning to suppress C1 byproduct selectivity for high-temperature olefin synthesis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Wang, Gang & Zhang, Zhen & Lin, Jianqing, 2024. "Multi-energy complementary power systems based on solar energy: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    7. Hou, Rui & Zhang, Nachuan & Yang, Chengsheng & Zhao, Jing & Li, Peng & Sun, Bo, 2023. "A novel structure of natural gas, electricity, and methanol production using a combined reforming cycle: Integration of biogas upgrading, liquefied natural gas re-gasification, power plant, and methan," Energy, Elsevier, vol. 270(C).
    8. Chen, Jun & Rabiti, Cristian, 2017. "Synthetic wind speed scenarios generation for probabilistic analysis of hybrid energy systems," Energy, Elsevier, vol. 120(C), pages 507-517.
    9. Galusnyak, Stefan Cristian & Petrescu, Letitia & Chisalita, Dora Andreea & Cormos, Calin-Cristian, 2022. "Life cycle assessment of methanol production and conversion into various chemical intermediates and products," Energy, Elsevier, vol. 259(C).
    10. Kim, Jong Suk & Boardman, Richard D. & Bragg-Sitton, Shannon M., 2018. "Dynamic performance analysis of a high-temperature steam electrolysis plant integrated within nuclear-renewable hybrid energy systems," Applied Energy, Elsevier, vol. 228(C), pages 2090-2110.
    11. Epiney, A. & Rabiti, C. & Talbot, P. & Alfonsi, A., 2020. "Economic analysis of a nuclear hybrid energy system in a stochastic environment including wind turbines in an electricity grid," Applied Energy, Elsevier, vol. 260(C).
    12. Zhao, Yang & Noori, Mehdi & Tatari, Omer, 2017. "Boosting the adoption and the reliability of renewable energy sources: Mitigating the large-scale wind power intermittency through vehicle to grid technology," Energy, Elsevier, vol. 120(C), pages 608-618.
    13. Huang, Yue & Zhu, Lin & He, Yangdong & Wang, Yuan & Hao, Qiang & Zhu, Yifei, 2023. "Carbon dioxide utilization based on exergoenvironmental sustainability assessment: A case study of CO2 hydrogenation to methanol," Energy, Elsevier, vol. 273(C).
    14. Safder, Usman & Loy-Benitez, Jorge & Yoo, ChangKyoo, 2024. "Techno-economic assessment of a novel integrated multigeneration system to synthesize e-methanol and green hydrogen in a carbon-neutral context," Energy, Elsevier, vol. 290(C).
    15. Wan, Zhanghao & Yang, Shiliang & Hu, Jianhang & Wang, Hua, 2023. "Catalyst-scale investigation of polydispersity effect on thermophysical properties in a commercial-scale catalytic MTO fluidized bed reactor," Energy, Elsevier, vol. 262(PA).
    16. Yanfei Xu & Zhenxuan Zhang & Ke Wu & Jungang Wang & Bo Hou & Ruoting Shan & Ling Li & Mingyue Ding, 2024. "Effects of surface hydrophobization on the phase evolution behavior of iron-based catalyst during Fischer–Tropsch synthesis," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    17. Ferchichi, Mariem & Hegely, Laszlo & Lang, Peter, 2022. "Economic and environmental evaluation of heat pump-assisted pressure-swing distillation of maximum-boiling azeotropic mixture water-ethylenediamine," Energy, Elsevier, vol. 239(PE).
    18. Cui, Chengtian & Qi, Meng & Zhang, Xiaodong & Sun, Jinsheng & Li, Qing & Kiss, Anton A. & Wong, David Shan-Hill & Masuku, Cornelius M. & Lee, Moonyong, 2024. "Electrification of distillation for decarbonization: An overview and perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    19. Hailing Yu & Caiqi Wang & Xin Xin & Yao Wei & Shenggang Li & Yunlei An & Fanfei Sun & Tiejun Lin & Liangshu Zhong, 2024. "Engineering ZrO2–Ru interface to boost Fischer-Tropsch synthesis to olefins," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    20. Anetjärvi, Eemeli & Vakkilainen, Esa & Melin, Kristian, 2023. "Benefits of hybrid production of e-methanol in connection with biomass gasification," Energy, Elsevier, vol. 276(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:263:y:2023:i:pe:s0360544222028778. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.