IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-50519-2.html
   My bibliography  Save this article

Aqueous alternating electrolysis prolongs electrode lifespans under harsh operation conditions

Author

Listed:
  • Jie Liang

    (Shandong Normal University
    University of Electronic Science and Technology of China)

  • Jun Li

    (University of Electronic Science and Technology of China)

  • Hongliang Dong

    (Center for High Pressure Science and Technology Advanced Research)

  • Zixiaozi Li

    (University of Electronic Science and Technology of China)

  • Xun He

    (University of Electronic Science and Technology of China)

  • Yan Wang

    (University of Electronic Science and Technology of China)

  • Yongchao Yao

    (University of Electronic Science and Technology of China)

  • Yuchun Ren

    (University of Electronic Science and Technology of China)

  • Shengjun Sun

    (Shandong Normal University)

  • Yongsong Luo

    (Shandong Normal University)

  • Dongdong Zheng

    (Shandong Normal University)

  • Jiong Li

    (Chinese Academy of Sciences)

  • Qian Liu

    (Chengdu University)

  • Fengming Luo

    (Sichuan University)

  • Tongwei Wu

    (University of Electronic Science and Technology of China)

  • Guang Chen

    (Shaanxi University of Science & Technology)

  • Xuping Sun

    (Shandong Normal University
    University of Electronic Science and Technology of China
    Sichuan University)

  • Bo Tang

    (Shandong Normal University
    Laoshan Laboratory)

Abstract

It is vital to explore effective ways for prolonging electrode lifespans under harsh electrolysis conditions, such as high current densities, acid environment, and impure water source. Here we report alternating electrolysis approaches that realize promptly and regularly repair/maintenance and concurrent bubble evolution. Electrode lifespans are improved by co-action of Fe group elemental ions and alkali metal cations, especially a unique Co2+-Na+ combo. A commercial Ni foam sustains ampere-level current densities alternatingly during continuous electrolysis for 93.8 h in an acidic solution, whereas such a Ni foam is completely dissolved in ~2 h for conventional electrolysis conditions. The work not only explores an alternating electrolysis-based system, alkali metal cation-based catalytic systems, and alkali metal cation-based electrodeposition techniques, and beyond, but demonstrates the possibility of prolonged electrolysis by repeated deposition-dissolution processes. With enough adjustable experimental variables, the upper improvement limit in the electrode lifespan would be high.

Suggested Citation

  • Jie Liang & Jun Li & Hongliang Dong & Zixiaozi Li & Xun He & Yan Wang & Yongchao Yao & Yuchun Ren & Shengjun Sun & Yongsong Luo & Dongdong Zheng & Jiong Li & Qian Liu & Fengming Luo & Tongwei Wu & Gua, 2024. "Aqueous alternating electrolysis prolongs electrode lifespans under harsh operation conditions," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50519-2
    DOI: 10.1038/s41467-024-50519-2
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-50519-2
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-50519-2?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Stanford R. Ovshinsky, 2000. "The road to decarbonized energy," Nature, Nature, vol. 406(6795), pages 457-458, August.
    2. Christiana Figueres & Corinne Le Quéré & Anand Mahindra & Oliver Bäte & Gail Whiteman & Glen Peters & Dabo Guan, 2018. "Emissions are still rising: ramp up the cuts," Nature, Nature, vol. 564(7734), pages 27-30, December.
    3. Davis, Steven J & Lewis, Nathan S. & Shaner, Matthew & Aggarwal, Sonia & Arent, Doug & Azevedo, Inês & Benson, Sally & Bradley, Thomas & Brouwer, Jack & Chiang, Yet-Ming & Clack, Christopher T.M. & Co, 2018. "Net-Zero Emissions Energy Systems," Institute of Transportation Studies, Working Paper Series qt7qv6q35r, Institute of Transportation Studies, UC Davis.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xi Yang & Chris P. Nielsen & Shaojie Song & Michael B. McElroy, 2022. "Breaking the hard-to-abate bottleneck in China’s path to carbon neutrality with clean hydrogen," Nature Energy, Nature, vol. 7(10), pages 955-965, October.
    2. Johnsson, Filip & Karlsson, Ida & Rootzén, Johan & Ahlbäck, Anders & Gustavsson, Mathias, 2020. "The framing of a sustainable development goals assessment in decarbonizing the construction industry – Avoiding “Greenwashing”," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    3. de Chalendar, Jacques A. & Benson, Sally M., 2021. "A physics-informed data reconciliation framework for real-time electricity and emissions tracking," Applied Energy, Elsevier, vol. 304(C).
    4. Kazuki Shun & Kohsuke Mori & Takumi Kidawara & Satoshi Ichikawa & Hiromi Yamashita, 2024. "Heteroatom doping enables hydrogen spillover via H+/e− diffusion pathways on a non-reducible metal oxide," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Grace D. Kroeger & Matthew G. Burgess, 2024. "Electric utility plans are consistent with Renewable Portfolio Standards and Clean Energy Standards in most US states," Climatic Change, Springer, vol. 177(1), pages 1-18, January.
    6. Stede, Jan & Pauliuk, Stefan & Hardadi, Gilang & Neuhoff, Karsten, 2021. "Carbon pricing of basic materials: Incentives and risks for the value chain and consumers," EconStor Open Access Articles and Book Chapters, ZBW - Leibniz Information Centre for Economics, vol. 189.
    7. Xie, Shiwei & Hu, Zhijian & Wang, Jueying & Chen, Yuwei, 2020. "The optimal planning of smart multi-energy systems incorporating transportation, natural gas and active distribution networks," Applied Energy, Elsevier, vol. 269(C).
    8. Jin, Taeyoung, 2022. "Impact of heat and electricity consumption on energy intensity: A panel data analysis," Energy, Elsevier, vol. 239(PA).
    9. Josefine A. Olsson & Sabbie A. Miller & Mark G. Alexander, 2023. "Near-term pathways for decarbonizing global concrete production," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    10. Isaac Holmes-Gentle & Saurabh Tembhurne & Clemens Suter & Sophia Haussener, 2023. "Kilowatt-scale solar hydrogen production system using a concentrated integrated photoelectrochemical device," Nature Energy, Nature, vol. 8(6), pages 586-596, June.
    11. Ren, Lei & Zhou, Sheng & Peng, Tianduo & Ou, Xunmin, 2022. "Greenhouse gas life cycle analysis of China's fuel cell medium- and heavy-duty trucks under segmented usage scenarios and vehicle types," Energy, Elsevier, vol. 249(C).
    12. Ángel Galán-Martín & Daniel Vázquez & Selene Cobo & Niall Dowell & José Antonio Caballero & Gonzalo Guillén-Gosálbez, 2021. "Delaying carbon dioxide removal in the European Union puts climate targets at risk," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    13. Shao, Tianming & Pan, Xunzhang & Li, Xiang & Zhou, Sheng & Zhang, Shu & Chen, Wenying, 2022. "China's industrial decarbonization in the context of carbon neutrality: A sub-sectoral analysis based on integrated modelling," Renewable and Sustainable Energy Reviews, Elsevier, vol. 170(C).
    14. Sovacool, Benjamin K. & Martiskainen, Mari & Furszyfer Del Rio, Dylan D., 2021. "Knowledge, energy sustainability, and vulnerability in the demographics of smart home technology diffusion," Energy Policy, Elsevier, vol. 153(C).
    15. Jannik Giesekam & Jonathan Norman & Alice Garvey & Sam Betts-Davies, 2021. "Science-Based Targets: On Target?," Sustainability, MDPI, vol. 13(4), pages 1-20, February.
    16. Furszyfer Del Rio, Dylan D. & Sovacool, Benjamin K. & Foley, Aoife M. & Griffiths, Steve & Bazilian, Morgan & Kim, Jinsoo & Rooney, David, 2022. "Decarbonizing the ceramics industry: A systematic and critical review of policy options, developments and sociotechnical systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    17. Zhao, Shihao & Li, Kang & Yang, Zhile & Xu, Xinzhi & Zhang, Ning, 2022. "A new power system active rescheduling method considering the dispatchable plug-in electric vehicles and intermittent renewable energies," Applied Energy, Elsevier, vol. 314(C).
    18. Yang Ou & Christopher Roney & Jameel Alsalam & Katherine Calvin & Jared Creason & Jae Edmonds & Allen A. Fawcett & Page Kyle & Kanishka Narayan & Patrick O’Rourke & Pralit Patel & Shaun Ragnauth & Ste, 2021. "Deep mitigation of CO2 and non-CO2 greenhouse gases toward 1.5 °C and 2 °C futures," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    19. Dan Tong & David J. Farnham & Lei Duan & Qiang Zhang & Nathan S. Lewis & Ken Caldeira & Steven J. Davis, 2021. "Geophysical constraints on the reliability of solar and wind power worldwide," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    20. Patange, Omkar S. & Garg, Amit & Jayaswal, Sachin, 2022. "An integrated bottom-up optimization to investigate the role of BECCS in transitioning towards a net-zero energy system: A case study from Gujarat, India," Energy, Elsevier, vol. 255(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50519-2. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.