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In-situ and wavelength-dependent photocatalytic strain evolution of a single Au nanoparticle on a TiO2 film

Author

Listed:
  • Sung Hyun Park

    (Hanyang University)

  • Sukyoung Kim

    (Hanyang University
    Hanyang University)

  • Jae Whan Park

    (Institute for Basic Science)

  • Seunghee Kim

    (Hanyang University
    Hanyang University)

  • Wonsuk Cha

    (Argonne National Laboratory)

  • Joonseok Lee

    (Hanyang University
    Hanyang University
    Hanyang University)

Abstract

Photocatalysis is a promising technique due to its capacity to efficiently harvest solar energy and its potential to address the global energy crisis. However, the structure–activity relationships of photocatalyst during wavelength-dependent photocatalytic reactions remains largely unexplored because it is difficult to measure under operating conditions. Here we show the photocatalytic strain evolution of a single Au nanoparticle (AuNP) supported on a TiO2 film by combining three-dimensional (3D) Bragg coherent X-ray diffraction imaging with an external light source. The wavelength-dependent generation of reactive oxygen species (ROS) has significant effects on the structural deformation of the AuNP, leading to its strain evolution. Density functional theory (DFT) calculations are employed to rationalize the induced strain caused by the adsorption of ROS on the AuNP surface. These observations provide insights of how the photocatalytic activity impacts on the structural deformation of AuNP, contributing to the general understanding of the atomic-level catalytic adsorption process.

Suggested Citation

  • Sung Hyun Park & Sukyoung Kim & Jae Whan Park & Seunghee Kim & Wonsuk Cha & Joonseok Lee, 2024. "In-situ and wavelength-dependent photocatalytic strain evolution of a single Au nanoparticle on a TiO2 film," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49862-1
    DOI: 10.1038/s41467-024-49862-1
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    References listed on IDEAS

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