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Near-infrared-featured broadband CO2 reduction with water to hydrocarbons by surface plasmon

Author

Listed:
  • Canyu Hu

    (University of Science and Technology of China
    Institute of Energy, Hefei Comprehensive National Science Center)

  • Xing Chen

    (Tianjin University)

  • Jingxiang Low

    (University of Science and Technology of China)

  • Yaw-Wen Yang

    (National Synchrotron Radiation Research Center)

  • Hao Li

    (Anhui Normal University)

  • Di Wu

    (University of Science and Technology of China
    Institute of Energy, Hefei Comprehensive National Science Center)

  • Shuangming Chen

    (University of Science and Technology of China)

  • Jianbo Jin

    (University of Science and Technology of China)

  • He Li

    (University of Science and Technology of China)

  • Huanxin Ju

    (University of Science and Technology of China)

  • Chia-Hsin Wang

    (National Synchrotron Radiation Research Center)

  • Zhou Lu

    (Anhui Normal University)

  • Ran Long

    (University of Science and Technology of China)

  • Li Song

    (University of Science and Technology of China)

  • Yujie Xiong

    (University of Science and Technology of China
    Institute of Energy, Hefei Comprehensive National Science Center
    Anhui Normal University)

Abstract

Imitating the natural photosynthesis to synthesize hydrocarbon fuels represents a viable strategy for solar-to-chemical energy conversion, where utilizing low-energy photons, especially near-infrared photons, has been the ultimate yet challenging aim to further improving conversion efficiency. Plasmonic metals have proven their ability in absorbing low-energy photons, however, it remains an obstacle in effectively coupling this energy into reactant molecules. Here we report the broadband plasmon-induced CO2 reduction reaction with water, which achieves a CH4 production rate of 0.55 mmol g−1 h−1 with 100% selectivity to hydrocarbon products under 400 mW cm−2 full-spectrum light illumination and an apparent quantum efficiency of 0.38% at 800 nm illumination. We find that the enhanced local electric field plays an irreplaceable role in efficient multiphoton absorption and selective energy transfer for such an excellent light-driven catalytic performance. This work paves the way to the technique for low-energy photon utilization.

Suggested Citation

  • Canyu Hu & Xing Chen & Jingxiang Low & Yaw-Wen Yang & Hao Li & Di Wu & Shuangming Chen & Jianbo Jin & He Li & Huanxin Ju & Chia-Hsin Wang & Zhou Lu & Ran Long & Li Song & Yujie Xiong, 2023. "Near-infrared-featured broadband CO2 reduction with water to hydrocarbons by surface plasmon," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-35860-2
    DOI: 10.1038/s41467-023-35860-2
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    References listed on IDEAS

    as
    1. Calvin Boerigter & Robert Campana & Matthew Morabito & Suljo Linic, 2016. "Evidence and implications of direct charge excitation as the dominant mechanism in plasmon-mediated photocatalysis," Nature Communications, Nature, vol. 7(1), pages 1-9, April.
    2. Xiao Zhang & Xueqian Li & Du Zhang & Neil Qiang Su & Weitao Yang & Henry O. Everitt & Jie Liu, 2017. "Product selectivity in plasmonic photocatalysis for carbon dioxide hydrogenation," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
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    Cited by:

    1. Rishi Verma & Gunjan Sharma & Vivek Polshettiwar, 2024. "The paradox of thermal vs. non-thermal effects in plasmonic photocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-45, December.
    2. Gunjan Sharma & Rishi Verma & Shinya Masuda & Khaled Mohamed Badawy & Nirpendra Singh & Tatsuya Tsukuda & Vivek Polshettiwar, 2024. "Pt-doped Ru nanoparticles loaded on ‘black gold’ plasmonic nanoreactors as air stable reduction catalysts," Nature Communications, Nature, vol. 15(1), pages 1-16, December.
    3. Xianyu Deng & Jianjun Zhang & Kezhen Qi & Guijie Liang & Feiyan Xu & Jiaguo Yu, 2024. "Ultrafast electron transfer at the In2O3/Nb2O5 S-scheme interface for CO2 photoreduction," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Xueying Wan & Yifan Li & Yihong Chen & Jun Ma & Ying-Ao Liu & En-Dian Zhao & Yadi Gu & Yilin Zhao & Yi Cui & Rongtan Li & Dong Liu & Ran Long & Kim Meow Liew & Yujie Xiong, 2024. "A nonmetallic plasmonic catalyst for photothermal CO2 flow conversion with high activity, selectivity and durability," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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